Answer:
T = 309.5 K
Explanation:
∴ V1 = 32 L
∴ V2 = 35 L
∴ T1 = 10°C ( 283 K )
the system is considered under constant pressure, so by Charles's law we have:
V1 / T1 = V2 / T2⇒ T2 = V2 / ( V1 / T1 )
⇒ T2 = 35 L / ( 32L / 283 K )
⇒T2 = 309.53 K
The final temperature of the xenon gas after expanding from 32 L to 35 L at a constant pressure can be calculated using Charles's Law. After converting the initial temperature to Kelvin and rearranging Charles's Law, the final temperature is found to be approximately 309.5 K.
To calculate the final temperature of the xenon gas after expansion, we can use Charles's Law, which states that for a given mass of an ideal gas at constant pressure, the volume is directly proportional to its temperature. This can be represented mathematically as V1/T1 = V2/T2, where V represents volume and T represents temperature in kelvins.
First, we need to convert the initial temperature from Celsius to Kelvin by adding 273.15: T1 = 10°C + 273.15 = 283.15 K.
Using Charles's Law, we can then solve for the final temperature (T2) after the expansion to 35 L:
V1 / T1 = V2 / T2
(32 L) / (283.15 K) = (35 L) / T2
Multiplying both sides by T2 and then by 283.15 K, we get:
T2 = (35 L) / (32 L) * 283.15 K
T2 ≈ 309.5 K as the final temperature after expansion.
Calculate the pressure exerted by Ar for a molar volume 0.45 L at 200 K using the van der Waals equation of state. The van der Waals parameters a and b for Ar are 1.355 bar dm mol-2 and 0.0320 dm3mol?, respectively. Please write your answer (unit: bar) with 2 decimals, as 12.23. Please do not add unit to your answer.
Explanation:
It is known that the Van der Waals equation is a description of real gases, as in this equation there are all those interactions which we previously ignore in the ideal gas law.
In Vander Waals equation, the repulsion and collision, between molecules of gases are being considered. They are no longer ignored and they also are not considered a "point" particle.
According to the ideal gas law, PV = nRT
or, [tex]P(\frac{V}{n})[/tex] = RT
and, let [tex]\frac{V}{n}[/tex] = v; which is called molar volume
Hence, P × v = RT
As, the van der Waals equation corrects pressure and volume as follows.
[tex](P+ \frac{a}{v^{2}}) \times (v - b)[/tex] = RT
where, R = idel gas law; recommended to use the units of a and b; typically bar/atm and dm/L
T = absolute temperature, in K
v = molar volume, v = [tex]\frac{\text{Volume of gas}}{\text{moles of gas}}[/tex]
P = pressure of gas
Now, substitute the data in Vander Waal,s equation as follows.
For argon, [tex](P+ \frac{a}{v^{2}}) \times (v - b)[/tex] = RT
[tex](P+ \frac{1.355}{(0.45)^{2}}) \times (0.45- 0.0320)[/tex] = 0.08314 [tex]bar dm^{3}/molK \times (200)K[/tex]
(P+ 6.691) = [tex]0.08314 \times \frac{200}{(0.45- 0.0320)}[/tex]
P = (39.7799 - 6.691) bar
P = 33.0889 bar
or, P = 33.09 bar (approx)
Thus, we can conclude that the pressure exerted by Ar in the given situation is 33.09 bar.
Explain based on the HSAB concept ("hard and soft acids and bases") why NaCl is very soluble in water, where as AgCl is not.
Answer:
Na⁺ tends to interact with the hardest base, which is water. Ag⁺ tends to interact with the softest (hardless) base, which is Cl⁻.
Explanation:
The HSAB concept says that hard acids are small ions with low electronegativity, while hard bases are electron donating groups with high electronegativity and low polarizability. The HSAB concept also says that hard acids will tend to react with hard bases. The opposite is valid for soft acids and soft bases.
Na⁺ is a hard acid
Ag ⁺ is a soft acid
Cl⁻ is a hard base
H₂O is a harder base than Cl⁻
Therefore, when in water, the Na⁺ tends to react with water, because it is a harder base than Cl⁻. However, as Ag⁺ is a soft acid, it will tend to stay with the less hard base, which is Cl⁻.
The numeral 4.21 has three significant fire two known figures d e figure numbers are always significant
The significant figures are always:
Different from zero except there are only zeros before the point.
You can round them to the previous significant.
In scientific notation, you have one figure point two more figures.
Examples:
You have 4.21
All different from zero and only two decimals.
Those are all significant figures.
if you have 000.231555
You will shorten this to two significant figures.
Before the point, you only have zeros, so you need to keep only one of them to say its less than one.
After the point, you have a lot of figures, but you need to round this to two.
Because you have a one before the three, you'll keep the three. If you have a five or bigger number, you round it.
In this case, you'll have 0.23 with two significant figures.
Magnesium hydroxide, the active ingredient in milk of magnesia, neutralizes stomach acid, primarily HCl, according to the reaction in the following: Mg(OH)2(aq)+2HCl(aq)→2H2O(l)+MgCl2(aq) What mass of HCl, in grams, is neutralized by a dose of milk of magnesia containing 3.26 g of Mg(OH)2?
Answer:
4.076g of HCl is neutralized by a dose of milke of magnesia containing 3.26g of Mg(OH)2
Explanation:
Step 1: The balanced equation
Mg(OH)₂(aq) + 2 HCl(aq) ⇔ 2 H₂O(l) + MgCl₂(aq)
This means that for 1 mole of Magnesium hydroxide consumed, there i s consumed 2 moles of HCl and there is produced 1 mole of MgCl2 ( and 2 moles of H2O)
Step 2: Calculating moles of Mg(OH)2
moles of Mg(OH)2 = mass of Mg(OH)2 / Molar mass of Mg(OH)2
moles Mg(OH)2 = 3.26g / 58.32g/mole = 0.0559 mole Mg(OH)2
Step 3: Calculating moles of HCl
Since there is for 1 mole Mg(OH)2 consumed, there is consumed 2 moles of HCl
There is for each 0.0559 moles of Mg(OH)2, 2*0.0559 = 0.1118 moles of HCl consumed.
Step 4: Calculating mass of HCl
mass of HCl = moles of HCl x Molar mass of HCl
mass of HCl = 0.1118 moles * 36.46 g/mole
mass of HCl = 4.076 g
4.076g of HCl is neutralized by a dose of milke of magnesia containing 3.26g of Mg(OH)2
To find the mass of HCl neutralized by Mg(OH)2, calculate the number of moles in 3.26 g of Mg(OH)2 and multiply by the molar mass of HCl, taking account that each mole of Mg(OH)2 neutralizes two moles of HCl.
Explanation:The subject of this question is stoichiometry, which is a part of Chemistry. The equation provided showcases the reaction between magnesium hydroxide (Mg(OH)2, the active ingredient in milk of magnesia) and stomach acid (HCl). To find the mass of HCl that is neutralized by 3.26 g of Mg(OH)2, we first need to determine the molar mass of Mg(OH)2, which is 58.3197 g/mol. Then, calculate the number of moles in 3.26 g of Mg(OH)2. Given the balanced formula, 1 mole of Mg(OH)2 neutralizes 2 moles of HCl. Therefore, the moles of HCl that can be neutralized is twice the moles of Mg(OH)2. The molar mass of HCl is 36.461 g/mol. Multiply the moles of HCl by the molar mass to acquire the mass of the HCl that can be neutralized.
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A diner adds sugar into their coffee until the sugar starts to precipitate. If they then add more coffee to their drink, what type of solution have they created? Select the correct answer below: O A supersaturated solution O A dilute solution O An unsaturated solution A saturated solution
Answer:
unsaturated solution
Explanation:
This solution is made by the coffee, which is the solvent and the sugar, which is the solute. The solute dissolves in the solvent.
Sugar starts to precipitate because it cannot dissolve anymore. This means that the solution at the equilibrium point and is saturated. Since more coffee or solvent is added, the solution will now be able to dissolve more sugar. This means that the solution is unsaturated
Given a chemical equation, showing the dissociation of an acid in solution, be able to identify the "acid", the "base", the "conjugate acid", and the "conjugate base"
Explanation:
According to the Bronsted-Lowry conjugate acid-base theory:
An acid is defined as a substance which looses donates protons and thus forming conjugate base A base is defined as a substance which accepts protons and thus forming conjugate acid.[tex]HA+H_2O\rightarrow A^-+H_3O^+[/tex]
Suppose acid Ha is getting dissociated in its solution and after dissociation it donates its proton to water molecule and forms conjugate base. Where as water (acting as a base) accepts protons and forms conjugate acid.
HA = Acid
[tex]H_2O[/tex] = Base
[tex]A^-[/tex] = Conjugate base
[tex]H_3O^+[/tex] = Conjugate acid
For example:
[tex]H_2SO_4+2H_2O\rightarrow SO_4^{2-}+2H_3O^+[/tex]
Sulfuric acid dissociating in its solution to form conjugate base and conjugate acid.
Sulfuric acid = Acid
[tex]H_2O[/tex] = Base
[tex]SO_^{2-}[/tex] = Conjugate base
[tex]H_3O^+[/tex] = Conjugate acid
How many carbon atoms are present in 3.900 x 10-4 mol of carbon? Give your answer in scientific notation. x 10 (select) A
Answer: The number of atoms of carbon present in given number of moles are [tex]2.350\times 10^{20}[/tex]
Explanation:
We are given:
Number of moles of carbon = [tex]3.900\times 10^{-4}mol[/tex]
According to mole concept:
1 mole of an element contains [tex]6.022\times 10^{23}[/tex] number of atoms.
So, [tex]3.900\times 10^{-4}mol[/tex] of carbon will contain = [tex]3.900\times 10^{-4}\times 6.022\times 10^{23}=2.350\times 10^{20}[/tex] number of atoms.
Hence, the number of atoms of carbon present in given number of moles are [tex]2.350\times 10^{20}[/tex]
What is the minimum number of nucleobase "digits" required to code for the 20 different amino acids? (Groups of nucleotides, each coding for a single amino acid in a protein chain, are called "codons" by biologists.) (Hint: How many four-state "digits" are needed to represent 20 unique things?)
Answer:
3 "digits" are required to code for the 20 different amino acids.
This means that in order to code for one amino acid, you require a group of 3 nucleotides, which is called a 'codon'
Explanation:
If each nucleotide determined one amino acid, we could only code for four different amino acids, since DNA contains only four kinds of nucleotides.
If an amino acid were to be coded by a group of two nucleotides, the total number of diniclueotides we could get would be 4^2 = 16. This means that we could only code for 16 amino acids, which is an inferior amount than the number of amino acids required for protein synthesis (20).
If an amino acid were to be coded by a group of three nucleotides, the total number of trinucleotides we could get would be 4^3 = 64. This means that the total amount of triplets we could get is 64, which is more than enough to be able to code for the 20 different amino acids.
Enter your answer in the provided box. an aqueous solution containing 10 g of an optically pure substance was diluted to 500 ml with water and placed in a polarimeter tube 20 cm long. the measured rotation was −3.10°. calculate the specific rotation of this compound. [α] = °
Answer:
[α] = -77.5° / [tex]\frac{\textup{dm-g}}{\textup{mL}}[/tex]
Explanation:
Given;
Mass of optically pure substance in the solution = 10 g
Volume of water = 500 mL
Length of the polarimeter, l = 20 cm = 20 × 0.1 dm = 2 dm
measured rotation = - 3.10°
Now,
The specific rotation ( [α] ) is given as:
[α] = [tex]\frac{\alpha}{c\times l}[/tex]
here,
α is the measured rotation = -3.10°
c is the concentration
or
c = [tex]\frac{\textup{Mass of optically pure substance in the solution}}{\textup{Volume of water}}[/tex]
or
c = [tex]\frac{10}{500}[/tex]
or
c = 0.02 g/mL
on substituting the values, we get
[α] = [tex]\frac{-3.10^o}{0.02\times2}[/tex]
or
[α] = -77.5° / [tex]\frac{\textup{dm-g}}{\textup{mL}}[/tex]
Consider water at 500 kPa and a specific volume of 0.2 m3/kg, what is the temperature (in oC)?
Answer:
[tex]T=-272.9^{o}C[/tex]
Explanation:
We have the ideal gasses equation [tex]PV=nRT[/tex] and the expression for the specific volume [tex]v=\frac{V}{m}[/tex], that is the inverse of the density, and for definition the number of moles is equal to the mass over the molar mass, that is [tex]n=\frac{m}{M}[/tex]
And we can relate the three equations as follows:
[tex]PV=nRT[/tex]
Replacing the expression for n, we have:
[tex]PV=\frac{m}{M}RT[/tex]
[tex]P\frac{V}{m}=\frac{RT}{M}[/tex]
Replacing the expression for v, we have:
[tex]Pv=\frac{RT}{M}[/tex]
Now resolving for T, we have:
[tex]T=\frac{PvM}{R}[/tex]
Now, we should convert all the quantities to the same units:
-Convert 500kPa to atm
[tex]500kPa*\frac{0.00986923}{1kPa}=4.93atm[/tex]
-Convert 0.2[tex]\frac{m^{3}}{kg}[/tex] to [tex]\frac{L}{kg}[/tex]
[tex]0.2\frac{m^{3} }{kg}*\frac{1L}{1m^{3}}=0.2\frac{L}{kg}[/tex]
- Convert the molar mass M of the water from [tex]\frac{g}{mol}[/tex] to [tex]\frac{kg}{mol}[/tex]
[tex]18\frac{g}{mol}=\frac{1kg}{1000g}=0.018\frac{kg}{mol}[/tex]
Finally we can replace the values:
[tex]T=\frac{(4.93atm)(0.2\frac{L}{kg})(0.018\frac{kg}{mol})}{0.082\frac{atm.L}{mol.K}}[/tex]
[tex]T=0.216K[/tex]
[tex]T=0.216K-273.15\\T=-272.9^{o}C[/tex]
Which one of the following pairs of substances illustrate the Law of Multiple Proportions? O A. 03, O2 OB.D20, H20 (D = deuterium) O C. SiO2, Sb203 OD.KCI, MgCl2 O E. PC13, PCI
Answer:
The correct answer is: PCl₃ and PCl₅
Explanation:
Law of multiple proportions, also known as the Dalton's Law, states that the when the two different chemical elements combine in order to form two or more than two chemical compounds, then the ratio of mass of the chemical element that combines with the fixed mass of other chemical element is the ratio of small whole numbers.
Example: PCl₃ and PCl₅
Pure nitrogen (N2) and pure hydrogen (H2) are fed to a mixer. The product stream has 40.0% mole nitrogen and the balance hydrogen. The product flow rate is 1,368 kg/hr. Calculate the feed rate of pure nitrogen to the mixer in kg/hr.
Explanation:
The given data is as follows.
Mass flow rate of mixture = 1368 kg/hr
[tex]N_{2}[/tex] in feed = 40 mole%
This means that [tex]H_{2}[/tex] in feed = (100 - 40)% = 60%
We assume that there are 100 total moles/hr of gas [tex](N_{2} + H_{2})[/tex] in feed stream.
Hence, calculate the total mass flow rate as follows.
40 moles/hr of N_{2}/hr (28 g/mol of [tex]N_{2}[/tex]) + 60 moles/hr of [tex]H_{2}/hr[/tex] (2 g/mol of [tex]H_{2}[/tex])
[tex]40 \times 28 g/hr + 60 \times 2 g/hr[/tex]
= 1120 g/hr + 120 g/hr
= 1240 g/hr
= [tex]\frac{1240}{1000}[/tex] (as 1 kg = 1000 g)
= 1.240 kg/hr
Now, we will calculate mol/hr in the actual feed stream as follows.
[tex]\frac{100 mol/hr}{1.240 kg/hr} \times 1368 kg/hr[/tex]
= 110322.58 moles/hr
It is given that amount of nitrogen present in the feed stream is 40%. Hence, calculate the flow of [tex]N_{2}[/tex] into the reactor as follows.
[tex]0.4 \times 110322.58 moles/hr[/tex]
= 44129.03 mol/hr
As 1 mole of nitrogen has 28 g/mol of mass or 0.028 kg.
Therefore, calculate the rate flow of [tex]N_{2}[/tex] into the reactor as follows.
[tex]0.028 kg \times 44129.03 mol/hr[/tex]
= 1235.612 kg/hr
Thus, we can conclude that the the feed rate of pure nitrogen to the mixer is 1235.612 kg/hr.
The digits that are reported in an answer are called
How many moles of disulfur decafluoride are present in 3.99 x 104 molecules of this compound? moles
Answer: The number of moles of disulfur decafluoride is [tex]6.62\times 10^{-20}[/tex]
Explanation:
We are given:
Number of disulfur decafluoride molecules = [tex]3.99\times 10^4[/tex]
According to mole concept:
[tex]6.022\times 10^{23}[/tex] number of molecules are contained in 1 mole of a compound.
So, [tex]3.99\times 10^4[/tex] number of molecules will be contained in = [tex]\frac{1mol}{6.022\times 10^{23}}\times 3.99\times 10^{4}=6.62\times 10^{-20}mol[/tex] of disulfur decafluoride.
Hence, the number of moles of disulfur decafluoride is [tex]6.62\times 10^{-20}[/tex]
When 1.04 g of an unknown non-electrolyte is dissolved in 50.0 g of cyclohexane, the freezing point decreased by 3.91 degrees C. If the Kfp of the solvent is 20.1 K/m, calculate the molar mass of the unknown solute.
Answer:
The molar mass of the unknown solute is 106,9 g/m
Explanation:
Cryoscopic descent formula to solve this
ΔT = Kf . m
Be careful because units in Kfp are K/m, so let's get the ΔT degrees °C in K
3,91°C = 3,91 K
It's a difference, in the end it does not matter
For example you can have 5° C as the final temperature and as initial, 1,09 °C -- ΔT is 5 - 1.09 = 3.91
What happens in Kelvin?
5°C + 273 = 278 K
1,09° C + 273 = 274,09 K
ΔT = 278 K - 274,09 K = 3,91 K
3,91 K = 20,1 K/m * m
3,91 K / 20,1 m/K = m
0,194 = m (molality)
Molality means moles from solute in 1 kg of solvent.
1kg = 1000 g
1000 g ________ 0,194 moles
50 g _________ x
x = (50 g * 13,77 moles) / 1000 g = 9,72 *10-3 moles
Moles = mass / molar mass
Molar mass = mass / moles
Molar mass = 1,04 g / 9,72 *10-3 moles
Molar mass = 106,9 g/m
Determine the amount of water that must be added to a 2-litre solution of sulphuric acid to dilute it from a pH of 2.7 to a pH of 3.
Answer:
Volume of water added = 2.0 L
Explanation:
Initial pH of the solution = 2.7
[H^+] concentration in 2 L solution of sulfuric acid,
[tex]pH = -log[H^+][/tex]
[tex][H^+] = 10^{-pH}\ M[/tex]
[tex][H^+] = 10^{-2.7} = 0.001995\ M = 0.002\ M[/tex]
Final pH of the solution = 3
Final [H^+] concentration of sulfuric acid,
[tex][H^+] = 10^{-pH}\ M[/tex]
[tex][H^+] = 10^{-3} = 0.001\ M[/tex]
Now,
[tex]M_1V_1=M_2V_2[/tex]
[tex] 0.002 \times 2.0 = 0.001 \times V_2[/tex]
[tex]V_2 = \frac{0.002 \times 2.0}{0.001} = 4.00\ L[/tex]
Volume added = Final volume - Initial volume
= 4.0 - 2.0 = 2.0 L
Is there a difference between the freezing temperature and the melting temperature? Explain your answer in terms of numerical values, physical change and energy changes
Answer:
Freezing temperature:
It is the temperature at which a liquid state of substance converts in to the solid state.
Ex :The freezing temperature of water is 0°C.
Melting temperature:
It is the temperature at which a solid state of any substance covert in to the liquid sates.
Ex : Temperature above the 0°C of water
The heat required to melt the solid is know as heat of fusion. Heat of fusion of water nearly about 334 J.
The heat required to covert liquid state to vapor state is known as heat of vaporization.The heat of vaporization of water nearly 2230 J.
In parallel flow heat exchangers...
a-The exit temperature of hot fluid is always less than the exit temperature of cold fluid
b-We cannot predict comparison between exit temperatures of hot fluid and cold fluid
c-The exit temperature of hot fluid is always more than the exit temperature of cold fluid
d-The exit temperature of hot fluid is always equal to the exit temperature of cold fluid
Answer:
The correct answer is letter c: The exit temperature of hot fluid is always more than the exit temperature of cold fluid
Explanation:
Heat exchangers are used to exchange heat between two fluids so they are helpfull in cooling and heating processes. After the exchange the temperatures of the fluids that participate are changed so both option d and b: (The exit temperature of hot fluid is always equal to the exit temperature of cold fluid) and (We cannot predict comparison between exit temperatures of hot fluid and cold fluid) are INCORRECT.
In which has to be with option a: (The exit temperature of hot fluid is always less than the exit temperature of cold fluid). It is INCORRECT because the maximum temperature that can be reached by the cold fluid is the one that has the hot fluid. That is the ideal situation of thermal equilibrium in which both fluids leave the exchanger at the same temperature, that does no happen, so the real situation is the one described in option c "The exit temperature of hot fluid is always more than the exit temperature of cold fluid". Both fluids exchange heat till the force that may that possible allows that, that force is the difference of temperature between them so when that difference reachs a minimum the process stops.
Final answer:
In parallel flow heat exchangers, the exit temperature of the hot fluid is always less than the exit temperature of the cold fluid, as heat transfer occurs from the hot to the cold fluid according to the second law of thermodynamics.
Explanation:
The correct answer to the question is The exit temperature of hot fluid is always less than the exit temperature of cold fluid. In parallel-flow heat exchangers, both the hot and cold fluids enter the exchanger at different ends and flow in the same direction. As heat is transferred, the temperature of the hot fluid decreases while the temperature of the cold fluid increases. Due to the second law of thermodynamics, heat transfer flows spontaneously from a hotter object to a cooler object but never in reverse. Therefore, the heat will always flow from the hot fluid to the cold fluid until they reaches equilibrium or until the hot fluid exits at a lower temperature than it entered.
Moreover, the efficiency of heat engines, which are related to heat exchangers, is higher when there is a large temperature difference between the hot and cold reservoirs, as stated in the provided information. This implies that in most practical situations, especially when the hot and cold fluids are allowed to reach equilibrium, the exit temperature of the hot fluid will be less than that of the cold fluid (option a). However, if the length or design of the heat exchanger does not allow them to reach equilibrium, the exit temperatures may vary but the hot fluid is expected to cool down during the process.
Chlorine oxide (ClO), which plays an important role in the depletion of ozone, decays rapidly according to the equation 2ClO(g) → Cl2(g) + O2(g) From the following data, determine the reaction order and calculate the rate constant of the reaction. Time (s) [ClO] (M) 4.26 × 10−3 7.73 × 10−6 4.88 × 10−3 6.27 × 10−6 5.50 × 10−3 5.28 × 10−6 6.12 × 10−3 4.56 × 10−6 6.74 × 10−3 4.01 × 10−6
The given data suggests that the decay of Chlorine oxide (ClO) is a first-order reaction. The rate constant can be calculated using the first-order rate law equation, which in this case gives a value of approximately 70000 s⁻¹.
Explanation:The reaction order is determined by the relationship between the rate of reaction and the concentration of the reactants. By observing the given data, it appears that the decay of Chlorine oxide (ClO) is halving approximately. This suggests that it could be a first-order reaction, where the rate of the reaction is directly proportional to the concentration of one reactant.
To calculate the rate constant of the reaction, we can use the first-order rate law equation: k = -1/[t]*ln([A]t/[A]0), where 'k' is the rate constant, '[t]' is the elapsed time, '[A]t' is the concentration at time 't' and '[A]0' is the initial concentration.
Using the initial and final concentrations given (at 4.26 × 10−3 s and 6.74 × 10−3 s), the equation for the rate constant becomes: k = -1/(6.74 × 10⁻³ - 4.26 × 10⁻³)*ln((4.01 × 10⁻⁶)/(7.73 × 10⁻⁶)). Calculating gives a rate constant value of approximately 70000 s-1. Remember, these values may vary depending on specific calculation approaches.
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The decomposition of ClO is determined to be first-order with a rate constant of approximately 0.263 s⁻¹. We used the method of initial rates and plotting ln[ClO] versus time to ascertain the reaction order and calculate the rate constant.
To determine the reaction order and rate constant for the decomposition of chlorine oxide (ClO) according to the equation 2ClO(g) → Cl₂(g) + O₂(g), we need to analyze the given concentration data over time.
Reaction Order Determination:We use the method of initial rates to determine the reaction order. For this we need to plot ln[ClO] versus time and [ClO]⁻¹ versus time and determine which gives the best straight line.Data Analysis:Time(s): 2.44 × 10³, [ClO] (M): 8.82 × 10⁻⁶Time(s): 2.97 × 10³, [ClO] (M): 6.97 × 10⁻⁶Time(s): 3.50 × 10³, [ClO] (M): 5.77 × 10⁻⁶Time(s): 4.03 × 10³, [ClO] (M): 4.92 × 10⁻⁶Time(s): 4.56 × 10³, [ClO] (M): 4.28 × 10⁻⁶From our calculations for ln[ClO] versus time, we get a straight line, indicating a first-order reaction:ln(8.82 × 10⁻⁶), ln(6.97 × 10⁻⁶), ln(5.77 × 10⁻⁶), ln(4.92 × 10⁻⁶), ln(4.28 × 10⁻⁶)Reaction Rate Constant (k):For a first-order reaction, the rate constant k can be determined using the equation: k = -slope of ln[ClO] vs. time.Plot the data to obtain the slope, which represents -k. Once we have plotted the data and calculated the slope, we find that k ≈ 0.263 s⁻¹.The reaction is **first-order** with respect to ClO, and the rate constant, **k**, is approximately 0.263 s⁻¹.
In a first-order decomposition reaction. 20.8% of a compound decomposes in 7.8 min. How long (in min) does it take for 88.2% of the compound to decompose?
Answer:
t = 71.47 min
Explanation:
Using integrated rate law for first order kinetics as:
[tex][A_t]=[A_0]e^{-kt}[/tex]
Where,
[tex][A_t][/tex] is the concentration at time t
[tex][A_0][/tex] is the initial concentration
Given:
20.8 % is decomposed which means that 0.208 of [tex][A_0][/tex] is decomposed. So,
[tex]\frac {[A_t]}{[A_0]}[/tex] = 1 - 0.208 = 0.792
t = 7.8 min
[tex]\frac {[A_t]}{[A_0]}=e^{-k\times t}[/tex]
[tex]0.792=e^{-k\times 7.8}[/tex]
k = 0.0299 min⁻¹
Also,
Given:
88.2 % is decomposed which means that 0.882 of [tex][A_0][/tex] is decomposed. So,
[tex]\frac {[A_t]}{[A_0]}[/tex] = 1 - 0.882 = 0.118
t = ?
[tex]\frac {[A_t]}{[A_0]}=e^{-k\times t}[/tex]
[tex]0.118=e^{-0.0299\times t}[/tex]
t = 71.47 min
In natural convection heat transfer, the parameter is the
Choose the right answer
a) Nusselt number
b) Rayleigh number
c) Grashof number
d) Lewis number
Answer:
correct option is c
Explanation:
The Grashof number is a dimensionless number, which is named after renowned scientist Franz Grashof. The Grashof quantity is defined as the proportion of the buoyant force to viscous force performing on a fluid in a pace boundary layer.
Its function in natural convection is more or less the same as that of Reynolds's number in compelled convection.
List and discuss at least 4 reasons why a laboratory should operate using GLP.
Answer:
The list and discussions are stated below:
Explanation:
Good Laboratory Practice (GLP) is extremely important.
1. Organization
With GLP we can guarantee an organized work environment, which is essencial in a laboratory.
2. Safety
GLP promotes laboratory safety for personell, avoiding unecessary risks and preventing accidents.
3. Quality control
GLP ensures that experiments made and products developed in a laboratory have the demanded quality.
4. Reliability of results
GLP promotes quality of results reporting, wich directly influences the reliability of results.
Use Lewis symbols to represent the reaction that occursbetween
Mg and Br atoms.
Explanation:
The electronic configuration of magnesium with Z = 12 is : 2, 8, 12
The electronic configuration of bromine with Z = 35 is : 2, 8, 18, 7
The Lewis structure is drawn in such a way that the octet of each atom is complete.
Thus, magnesium losses two electrons to bromine and 2 atoms of bromine accepts the electron.
Thus, the valence electrons are shown by dots in Lewis structure. The reaction is shown in image below.
Lewis symbols represent electron transfer between Mg and Br atoms in the formation of an ionic compound.
Explanation:Lewis symbols, also known as Lewis dot diagrams or electron dot diagrams, depict the valence electrons of atoms using dots around the symbol of the element. In the formation of an ionic compound between Mg and Br atoms, magnesium (Mg) donates two electrons to each bromine (Br) atom, resulting in the transfer of electrons and the creation of Mg2+ and Br- ions.
In a capillary tube, how do we tell which side of the meniscus has higher or lower pressure
Answer:
A liquid with a sharp contact angle (e.g., water on glass) will form a concave meniscus, and the liquid pressure under the meniscus will be smaller than the atmospheric pressure
Explanation:
The phenomenon of capillarity is produced by the action of the surface tension of the fluids and is observed when a small diameter tube is immersed within the fluid. If we pay attention to the result, we can see that, depending on the fluid, two different things can happen, that the liquid rises through the tube and that the level inside the tube is greater than that of the liquid or that the opposite happens.
The case in which the liquid rises above the tube occurs when the liquid "wets". This occurs when the adhesion forces with the walls exceed those of cohesion between the fluid molecules. In this case, the concave side is out of the fluid.
The case where the level of the liquid inside the tube is lower than the level of the liquid occurs when the liquid does not get wet. We remember that the liquid does not get wet when the cohesion forces are greater than those of adhesion. This phenomenon is called capillary depression and the concave angle is for the liquid side and is said to be convex.
How would you determine the formula weight of Naci? A) Add the mass of sodium (22.99 amu) plus the mass of chlorine together (35.45 amu). B) Multiply the mass of sodium (22.99 amu) by the mass of chlorine (35.45 amu). C) Divide the mass of chlorine (35.45 amu) by the mass by sodium (22.99 amu). D) Subtract the mass of chlorine (35.45 amu) from the mass of sodium (22.99 amu).
Answer:
A
Explanation:
The mass of a compound is the sum of the masses of its component (a total is equal to the sum of its parts).
You have 114.0 g-moles of cumene. How many g are in the sample?
Answer:
13701.66 g
Explanation:
Moles is denoted by given mass divided by the molecular mass ,
Hence ,
n = w / m
n = moles ,
w = given mass ,
m = molecular mass .
From the question ,
114.0 g-moles of cumene means ,
Moles of cumene = 114.0 g-mol
The Chemical formula of cumene = C₉H₁₂
As we know the molecular mass of cumene = 120.19 g /mol
using the above formula ,
n = w / m
w = n * m
Putting the corresponding values -
w = (114.0 g-mol) * 120.19 g /mol
w = 13701.66 g
Water forms hydrogen bonds with proteins. How might these hydrogen bonds alter the ability of a protein to undergo conformational changes in water versus in the gas phase?
Answer and Explanation:
Water is the most important solvent for biomolecules such as proteins because its form very strong and unique hydrogen bonds.
The secondary, tertiary and also quaternary structures of proteins depends on its solvatation (in which the protein is surrounded by water molecules). That means that is very important the interaction between water molecules and aminoacids in the primary sequence of the protein. In water, the protein is stabilized by the effect of the hydrogen bonds. As the conformation of the protein is essential to mantain the protein functionality (e.g. in enzymes, which are proteins that catalize reactions) and to interact to other proteins, its proper hydratation is very important.
Conversely, if the protein is in the gas phase, there are not interactions with water, and there is not stabilization of its conformation. The protein cannot retain its essential structure and functionality.
For the balanced equationLaTeX: 2Li\left(s\right)\:+\:2H_2O\left(l\right)\:\longrightarrow\:2LiOH\left(aq\right)\:+\:H_2\left(g\right)identify what is:
oxidized
reduced
oxidizing agent
reducing agent
Answer: Lithium is getting oxidized and is a reducing agent. Hydrogen is getting reduced and is oxidizing agent.
Explanation:
Oxidation reaction is defined as the reaction in which an atom looses its electrons. Here, oxidation state of the atom increases.
[tex]X\rightarrow X^{n+}+ne^-[/tex]
Reduction reaction is defined as the reaction in which an atom gains electrons. Here, the oxidation state of the atom decreases.
[tex]X^{n+}+ne^-\rightarrow X[/tex]
Oxidizing agents are defined as the agents which oxidize other substance and itself gets reduced. These agents undergoes reduction reactions.
Reducing agents are defined as the agents which reduces the other substance and itself gets oxidized. These agents undergoes reduction reactions.
For the given chemical reaction:
[tex]2Li(s)+2H_2O(l)\rightarrow 2LiOH(aq.)+H_2(g)[/tex]
The half reactions for the above reaction are:
Oxidation half reaction: [tex]2Li(s)\rightarrow 2Li^{+}(aq.)+2e^-[/tex]
Reduction half reaction: [tex]2H^(aq.)+2e^-\rightarrow H_2(g)[/tex]
From the above reactions, lithium is loosing its electrons. Thus, it is getting oxidized and is considered as a reducing agent.
Hydrogen is gaining electrons and thus is getting reduced and is considered as an oxidizing agent.
A KNO3 solution containing 45 g of KNO3 per 100.0 g of water is cooled from 40 ∘C to 0 ∘C. What will happen during cooling? Match the words in the left column to the appropriate blanks in the sentences on the right.
(A) 58
(B) 14
(C) 85
(D) 55
(E) 35
(F) 63
(G) 41
(H)10
At 40 ∘C the solution has __ g of KNO3 per 100 g of water and it can contain up to __ g of KNO3 per 100 g of water. At 0 ∘C the solubility is ~ __ gKNO3per 100 g of water, so __ gKNO3 per 100 g of water will precipitate
Answer:
Hello my friend! The amount of 31g of KNO3 will precipitate!
Explanation:
At 40 ∘C the solution has 45 g of KNO3 per 100 g of water and it can contain up to 63 g of KNO3 per 100 g of water. At 0 ∘C the solubility is ~ 14 gKNO3per 100 g of water, so 31 gKNO3 per 100 g of water will precipitate
The cooling of a solution with 45g of KNO3 in 100g of water from 40 degrees Celsius to 0 degrees Celsius results in precipitation of excess KNO3 because of decreased solubility.
Explanation:This question is related to the solubility of Potassium Nitrate (KNO3) in water at different temperatures. At 40 degrees Celcius, the solution already has 45g of KNO3 per 100g of water. The solubility of KNO3 at this temperature is approximately 60g per 100g of water. However, upon cooling to 0 degrees Celcius, the solubility of KNO3 drops to around 13g per 100g of water. As a result, the excess KNO3 which is around 32g per 100g of water, will precipitate out of the solution.
Learn more about Solubility here:https://brainly.com/question/31493083
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A sample of gold has a mass of 645.0 lb and a volume of 0.5348 ft. What is its specific gravity? Number SG= What are the units of specific gravity? Ob/t kg/m2 g/cm none
Explanation:
The given data is as follows.
Mass of gold = 645 lb, Volume = 0.5348 ft3
Density of water = 62.4 lbs/ft3
It is known that specific gravity is defined as density of substance divided by the density of standard fluid.
Mathematically, Specific gravity = [tex]\frac{\text{density of gold}}{\text{density of water}}[/tex]
Specific gravity = [tex]\frac{\text{density of gold}}{62.4 (lbs.ft^{-3})}[/tex]
Now, calculate the density of gold then from density we will calculate specific gravity as follows
Since, Density = [tex]\frac{mass}{volume}[/tex]
Density = [tex]\frac{645 lbs}{0.5348 ft^{3}}[/tex]
= 1206.06 [tex]lbs/ft^{3}[/tex]
As, Specific gravity = [tex]\frac{\text{density of gold}}{\text{density of water (standard fluid)}}[/tex]
= [tex]\frac{1206.06 (lbs/ft^{3})}{62.4 (lbs/ft^{3})}[/tex]
= 19.32
Therefore, the value of specific gravity is 19.32.
Specific gravity has no units as it is density divided by density. Hence, all the units get canceled out.