A bomb calorimetric experiment was run to determine the enthalpy of combustion of ethanol. The reaction is The bomb had a heat capacity of 490 J/K, and the calorimeter contained 730 g of water. Burning 4.40 g of ethanol, resulted in a rise in temperature from 16.8 °C to 20.5 °C. Calculate the enthalpy of combustion of ethanol, in kJ/mol. (The specific heat capacity of liquid water is 4.184 J/g ⋅ K.) Enthalpy of combustion = kJ/mol

Answers

Answer 1

The enthalpy of combustion of ethanol is approximately -118.45 kJ/mol.

To determine the enthalpy of combustion (ΔH) of ethanol, we can use the heat transfer equation:

q = mcΔT

where q is the heat absorbed by the water, m is the mass of the water, c is the specific heat capacity of water, and ΔT is the change in temperature.

First, calculate the heat absorbed by the water:

q = (730 g)(4.184 J/g ⋅ K)(20.5 °C - 16.8 °C)

q = 730 × 4.184 × 3.7 J

q = 11,300.984 J

Next, convert the mass of ethanol burned (4.40 g) to moles using the molar mass of ethanol (C2H5OH):

Molar mass of ethanol = 2 × molar mass of C + 6 × molar mass of H + molar mass of O

Molar mass of ethanol = 2 × 12.01 + 6 × 1.01 + 16.00 g/mol

Molar mass of ethanol = 46.07 g/mol

Moles of ethanol = 4.40 g / 46.08 g/mol

Moles of ethanol ≈ 0.0954 mol

Now, calculate ΔH using the formula:

ΔH = -q / moles of ethanol

ΔH = -11,300.984 J / 0.0954 mol

ΔH ≈ -118,458.952 J/mol

Convert to kJ/mol:

ΔH ≈ -118.45 kJ/mol


Related Questions

Between Lab Period 1 and Lab Period 2, design a separation scheme for all 4 cations. Use the results of your preliminary tests and the reasoning illustrated in the introduction and the Week 2 Worksheet. Be sure to include equations for all the reactions which occur at each step in the scheme. Record the scheme in the data section of the lab notebook. The scheme MUST be submitted at the start of Lab Period 2. It will be reviewed by the TA at the start of the lab period, before you begin testing your scheme. Ag+, Fe 3+ Cu2+, Ni2+

Answers

Answer:

                    SEPARATION SCHEME FOR  CATIONS

GIVEN  CATIONS : [tex]Ag^{+} \ , Fe^{3+} , Cu^{2+}, Ni^{2+}[/tex]

     

    Step 1:   Add [tex]6mol/dm^3[/tex] of [tex]HCl[/tex] to the mixture solution

    Result : This would cause a precipitate of [tex]AgCl[/tex] to be formed

    Reaction :  [tex]Ag^{+} _{(aq)} + Cl^{-} _{(aq)} ---------> AgCl(ppt)[/tex]

    Step 2 : Next is to remove the precipitate and add [tex]H_2S[/tex] to the remaining          

                 solution in the presence of [tex]0.2 \ mol/dm^3[/tex] of HCl

     Result : This would cause a precipitate of [tex]CuS[/tex] to be formed

     Reaction :  [tex]Cu^{2+}_{(aq)} + S^{2-}_{(aq)} ------> Cu_2S(ppt)[/tex]

 

     Step 3: Next remove the precipitate then add [tex]6 \ mol/dm^3[/tex] of aqueous      

                 [tex]NH_3 (NH_3 \cdot H_2 O)[/tex] , process the solution in a centrifuge,when the  

                 process  is done then sort out the  precipitate from the  solution

                 Now this precipitate is   [tex]Fe(OH)_3[/tex] and the remaining solution

                contains  [tex](Ni (NH_3)_6)[/tex]

                 Next take out the precipitate to a different beaker and add HCl

                to it   this will dissolve it, then add a drop of [tex]NH_4SCN[/tex] this will

                form  a precipitate  [tex]Fe(SCN)_{6}^{3-}[/tex] which will have the color of

                 blood  indicating the presence of [tex]Fe^{3+}[/tex]

             

   Reaction :   [tex]F^{3+}_{(aq)} + 30H^-_{(aq)} --------->Fe(OH)_3_{(aq)}[/tex]

                        [tex]Fe (OH)_{(s)} _3 + 3H^{+}_{aq} -------> Fe^{3+}_{aq} + 3H_2O_{(l)}[/tex]

                         [tex]Fe^{3+} + 6SCN^{-} -----> Fe(SCN)_6 ^{3-}[/tex]

                      Now the remaining mixture contains [tex]Ni^{2+}[/tex]

     

       

Explanation:

Determine the primary structure of an octapeptide from the following data: acid-catalyzed hydrolysis gives 2 arg, leu, lys, met, phe, ser, and tyr. carboxypeptidase a releases ser. edman's reagent releases leu. treatment with cyanogen bromide forms two peptides with the following amino acid compositions: 1. arg, phe, ser 2. arg, leu, lys, met, tyr trypsin-catalyzed hydrolysis forms the following two amino acids and two peptides: 1. arg 2. ser 3. arg, met, phe 4. leu, lys, tyr

Answers

A Sentence that I Used:

The position of Met seems incorrect. The amino acid sequences of all proteins begin with Met because it is the amino acid that is attached to the anticodon for the AUG start codon. It looks like the student might have worked in a backward direction for transcription.

Sodium hydrogen carbonate (NaHCO3) , also known as sodium bicarbonate or "baking soda", can be used to relieve acid indigestion. Acid indigestion is the burning sensation you get in your stomach when it contains too much hydrochloric acid (HC1) , which the stomach secretes to help digest food. Drinking a glass of water containing dissolved NaHCO3 neutralizes excess HC1 through this reaction:

HC1(aq) + NaHCO3 (aq) → NaC1 (aq) + H2O (I) + CO2 (g)

The CO2 gas produced is what makes you burp after drinking the solution.

Suppose the fluid in the stomach of a man suffering from indigestion can be considered to be 50. mL of a 0.034 M HC1 solution. What mass of NaHCO 3 would he need to ingest to neutralize this much HC1 ?
Be sure your answer has the correct number of significant digits.

Answers

Answer:

Mass of NaHCO₃ required for the neutralization = 0.143 g

Explanation:

The reaction between HCl and NaHCO₃ is given as

HCl + NaHCO₃ → NaCl + H₂O + CO₂

The fluid in the stomach of a man suffering from indigestion is considered to be 50 mL of a 0.034 M HCl solution. The mass of NaHCO₃ he would need to ingest to neutralize this much HCl.

We forst need to calculate the number of moles of HCl in 50.0 mL of 0.034 M HCl

(Number of moles) = (Conc in mol/L) × (Volume in L)

Conc in mol/L = 0.034 M

Volume in L = (50/1000) = 0.05 L

Number of moles of HCl = 0.034 × 0.05 = 0.0017 moles

From the stoichiometric balance of the reaction,

1 mole of HCl requires 1 mole of NaHCO₃

0.0017 moles of HCl will require 0.0017 moles of NaHCO₃.

So, we can then.calculate the mass of NaHCO₃ required for this neutralization.

Mass = (Number of moles) × (Molar mass)

Molar mass of NaHCO₃ = 84.007 g/mol

Mass of NaHCO₃ required for this neutralization = 0.0017 × 84.007 = 0.1428119 g = 0.143 g to 3 s.f because calculated values usually have 1 more significant figure than the given parameters for the calculations.

Hope this Helps!!!

besides the ocean where else is water on Earth? Is it always in liquid form?​

Answers

Answer:

water is everywhere, its in the air and the clouds, in the earth too!

it isnt always liquid form. like when it snows or hails.

Explanation:

Water is everywhere in the world. it’s also in your body and you live as 80% of water

What will be the pH of 1.0 mol dm-3 of NH4OH, which is 1% dissociated

Answers

reaction is NH4OH <-> NH4+ OH- (note this is reversible)

Draw up an ICE table

Let x be equilibrium conc of OH- assume init conc of OH is 0M and init conc of NH4+ is 0M also. Init conc of NH4OH is 0.1M so equilibrium conc will be 0.1-x.

%dissociation = x/0.1-x * 100%

1 = 100x/0.1-x

0.1-x = 100x

101x = 0.1

x = 0.0009901

pOH = -log(0.0009901) = 3.00

The pH of this solution is 12.

We can solve this question knowing that the ammonium hydroxide, NH₄OH, dissociates in water as follows:

NH₄OH(aq) ⇄ NH₄⁺(aq) + OH⁻(aq)

Based on the reaction, 1 mole of NH₄OH produces 1 mole of OH⁻

With this molarity and the 1% dissociated we can find the molarity of OH⁻. With molarity of OH⁻ we can find pOH (pOH = -log[OH⁻]) and pH (pH = 14-pOH) as follows:

Molarity OH⁻:

A solution 1.0mol dm⁻³ = 1M of NH₄OH produce 1% of OH⁻ ions because only 1% is dissociate, that is:

[tex]1M NH_4OH*(\frac{1MOH^-}{100MNH_4OH}) = 0.01M OH^-[/tex]

Now, we can find pOH as follows:

pOH:

pOH = -log [OH⁻] = 2

And pH:

pH:

pH = 14 - pOH

pH = 12

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Can convection occur in both liquids and
gases? Suggest a reason for your answer
using the particle theory.

Answers

Answer:

Yes, Convection can occur in both liquids and gases

Explanation:

  The Particle Theory suggests that Particles are always moving. Convection occurs in the breeze you feel, when the warm particles quickly move upwards resulting in cold air quickly sinking and creating a breeze. Convection also occurs when you boil water, the molecules of warm water quickly move to the top and cold water quickly moves to the bottom resulting in a circle the constantly keeps the water circulating, making it boil.

The decomposition reaction 2 NOCl → 2 NO + Cl_2 has a rate law that is second order with respect to ​[NOCl], where k = 3.2 M^{-1}s^{-1} at a certain temperature. If the initial concentration of NOCl is 0.076 M, how many seconds will it take for ​[NOCl] to decrease to 0.042 M at this temperature? Do not enter units with your numerical answer.

Answers

Final answer:

For the second-order reaction 2 NOCl → 2 NO + Cl2, it will take 3.32 seconds for the concentration of NOCl to decrease from 0.076 M to 0.042 M.

Explanation:

The reaction 2 NOCl → 2 NO + Cl2 is second order with respect to [NOCl], meaning the rate law can be written as rate = k[NOCl]2. Given that k = 3.2 M−1s−1, we can use the integrated rate law for second-order reactions to find the time it takes for the concentration of NOCl to change from 0.076 M to 0.042 M. The integrated rate law for second-order reactions is ¼¾ ϑ¾ = k(t-t0), with t as the time elapsed, t0 as the initial time, and ϑ and ϑ0 as the final and initial concentrations, respectively. Solving for t gives us

t = ¼¾ [ϑ0^{-1} - ϑ^{-1}] / k

Substituting the given values we get:

t = ( ¼¾ [0.076−1 - 0.042−1] ) / 3.2

t = ( ¼¾ [13.16 - 23.81] ) / 3.2

t = ( ¼¾ [-10.65] ) / 3.2

t = 3.32 seconds

Addition of AgNO3 to aqueous solutions of the complex results in a cloudy white precipitate, presumably AgCl. You dissolve 0.1000 g of the complex in H2O and perform a precipitation titration with 0.0500 M AgNO3 as the titrant. Using an electrode that is sensitive to [Ag ], you reach the endpoint after 9.00 mL of titrant is added. How many grams of chloride ion were present in the 0.1000-g sample

Answers

Answer:

0.016 grams of chloride ion were present in the 0.1000 grams of sample.

Explanation:

According to question, 9.00 mL of titrant was added to solution with 0.1000 grams of complex to reach the end point.

Molarity of the silver nitrate solution = 0.0500 M

Volume of the silver nitrate solution = V = 9.00 mL = 0.009 L

1 mL = 1000 L

Moles of silver nitrate = n

[tex]Molarity=\frac{Moles}{Volume (L)}[/tex]

[tex]0.0500 M=\frac{n}{0.009 L}[/tex]

n = 0.00045 mol

[tex]Cl^-+AgNO_3\rightarrow AgCl+NO_3^{-}[/tex]

According to 1 mole of silver nitrate reacts with 1 mol of chloride ion, then 0.00045 moles of silver nitrate will :

[tex]\frac{1}{1}\times 0.00045 mol=0.00045 mol[/tex] of chloride ions

Mass of chloride ions :

0.00045 mol × 35.5 g/mol = 0.016 g

0.016 grams of chloride ion were present in the 0.1000 grams of sample.

Problem 19.24a Using the reagents below, list in order (by letter, no period) those necessary to convert the starting material into the given product: Note: More than 1 mole of the starting material may be used. Not all spaces provided may be needed. Type "na" in any space where you have no reagent. a. heat, -CO2 b. NaOEt c. (CH3CH2)2CuLi d. CH2Cl2, PCC e. C3H7C(O)CH(C2H5)C(O)C2H5 f. CH3CH2Li g. CH3C(O)Cl, AlCl3 h. NBS, ROOR i. H2NC(O)NH2 j. HN(CH3)2 k. OH-, H2O, heat then H3O l. H3O

Answers

Answer:

Step 1: The answer is option (b) NaOEt

Step 2: The answer is option (k) OH-, H2O, heat then H3O

Step 3: The answer is option (a) heat, -CO2

Step 4: na (no reagent)

Explanation:

See the attached file for the explanation.

In the equation KClO3 -> KCl + O2, how many moles of oxygen are produced when 3.0 mol of KClO3 decomposes completely?

Answers

Answer:

4.5

Hope this helps!

In the given chemical equation according to stoichiometry, 4.5 moles  of oxygen are produced when 3.0 mole of KClO₃ decomposes completely.

What is stoichiometry?

Stoichiometry is the determination of proportions of elements or compounds in a chemical reaction. The related relations are based on law of conservation of mass and law of combining weights and volumes.

Stoichiometry is used in quantitative analysis for measuring concentrations of substances present in the sample. It is important while making solutions and balancing chemical equations.In the given balanced chemical equation, 2 moles of  KClO₃  gives 3 moles of oxygen , thus 3 mole of  KClO₃ will give 3×3/2=4.5  moles.

Thus, 4.5 moles  of oxygen are produced when 3.0 mole of KClO₃ decomposes completely.

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You are given 25.00 mL of an acetic acid solution of unknown concentration. You find it requires 35.75 mL of a 0.1950 M NaOH solution to exactly neutralize this sample (phenolphthalein was used as an indicator). What is the molarity of the acetic acid solution? What is the percentage of acetic acid in the solution?

Answers

Answer:

0.2788 M

1.674 %(m/V)

Explanation:

Step 1: Write the balanced equation

NaOH + CH₃COOH → CH₃COONa + H₂O

Step 2: Calculate the reacting moles of NaOH

[tex]0.03575 L \times \frac{0.1950mol}{L} = 6.971 \times 10^{-3} mol[/tex]

Step 3: Calculate the reacting moles of CH₃COOH

The molar ratio of NaOH to CH₃COOH is 1:1.

[tex]6.971 \times 10^{-3} molNaOH \times \frac{1molCH_3COOH}{1molNaOH} = 6.971 \times 10^{-3} molCH_3COOH[/tex]

Step 4: Calculate the molarity of the acetic acid solution

[tex]M = \frac{6.971 \times 10^{-3} mol}{0.02500L} =0.2788 M[/tex]

Step 5: Calculate the mass of acetic acid

The molar mass of acetic acid is 60.05 g/mol.

[tex]6.971 \times 10^{-3} mol \times \frac{60.05g}{mol} =0.4186 g[/tex]

Step 6: Calculate the percentage of acetic acid in the solution

[tex]\frac{0.4186g}{25.00mL} \times 100\% = 1.674 \%(m/V)[/tex]

Answer:

Concentration  acetic acid = ‬0.27885 M

% acetic acid = 0.69%

Explanation:

You are given 25.00 mL of an acetic acid solution of unknown concentration. You find it requires 35.75 mL of a 0.1950 M NaOH solution to exactly neutralize this sample (phenolphthalein was used as an indicator). What is the molarity of the acetic acid solution?

what is the percentage of acetic acid in the solution? Assume the density of the solution is 1 g/ml.

Step 1: Data given

Volume of acetic acid = 25.00 mL = 0.025 L

Volume of NaOH = 35.75 mL = 0.03575 L

Molarity of NaOH = 0.1950 M

Step 2: The balanced equation

CH3COOH + NaOH → CH3COONa + H2O

Step 3: Calculate moles

Moles = molarity * volume

Moles NaOH = 0.1950 M * 0.03575 L

Moles NaOH = 0.00697125‬ moles

Step 4: Calculate concentration of acetic acid

We need 0.00697125‬ moles of acetic acid to neutralize NaOH

Concentration = moles / volume

Concentration = 0.00697125 moles / 0.025 L

Concentration = ‬0.27885 M

Step 5: Calculate mass of acetic acid

Mass acetic acid = moles * molar mass

Mass acetic acid = 0.00697125 moles * 60.05g/mol

Mass acetic acid = 0.4186 grams

Step 6: Calculate mass of sample

Total volume = 60.75 mL = 0.06075 L

Mass of sample 60.75 mL * 1g/mL = 60.75 grams

Step 7: Calculate the percentage of acetic acid in the solution

% acetic acid = (0.4186 grams / 60.75 grams ) * 100 %

% acetic acid = 0.69%

1) Analysis subquestions (7 points): (a) Draw the mechanism of the reaction - remember, there are two main parts to the aldol condensation, the addition step, followed by the elimination. (b) Explain why your reaction forms the enone product, rather than the hydroxyketone intermediate. 2) Critical analysis (7 points): a) You have been given a 1H NMR spectrum of your product. Fully assign this spectrum (i.e. determine which peaks in the 1H NMR correspond to which hydrogens in the product). The peaks have been labeled 1-8 on the spectrum, and the relevant hydrogens Ha-Hh below. b) Calculate the coupling constant between He and Hf. Explain how can this can help determine the stereochemistry (i.e. cis vs. trans) of the double bond. (7) Acetone is a symmetrical molecule, so there are two positions that can react. Draw the product you would expect to obtain if you used two molar equivalents of vanillin rather than one. c) Acetone is a symmetrical molecule, so there are two positions that can react. Draw the product you would expect to obtain if you used two molar equivalents of vanillin rather than one.

Answers

Find the attachments

g Which compounds are bases in aqueous solution according to Brønsted–Lowry theory?A chain of four carbon atoms connected by single bonds. Single bonds connect the first carbon atom to 3 hydrogen atoms. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom. The single bonded oxygen atom is connected to a hydrogen atom by a single bond. Both oxygen atoms have 2 lone pairs.A chain of 4 carbon atoms connected by single bonds. The first carbon atom is connected to 3 hydrogen atoms by single bonds. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom with 2 lone pairs, and single bonded to 1 oxygen atom with 3 lone pairs. The oxygen atom with 3 lone pairs is marked with a minus sign.

Answers

Answer:

A chain of four carbon atoms connected by single bonds. Single bonds connect the first carbon atom to 3 hydrogen atoms. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom. The single bonded oxygen atom is connected to a hydrogen atom by a single bond. Both oxygen atoms have 2 lone pairs.

Explanation:

In the Brownstead-Lowry definition of a base; a base is any substance that accepts a proton. Hence, a base must have available lone pairs to accept a proton and possess a plus sign afterwards. Only the bonding situation described in the answer meets this description.

The description in the second option should be a Brownstead-Lowry acid because it will rather donate a proton.

The compounds that are bases in aqueous solution according to Bronsted-Lowry theory is ; ( A , B, C, D and E ).

A chain of four carbon atoms connected by single bonds.Single bonds connect the first carbon atom to 3 hydrogen atomsThe second and third carbons are each connected to 2 hydrogen atoms by single bonds.The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom.The single bonded oxygen atom is connected to a hydrogen atom by a single bond.Both oxygen atoms have 2 lone pairs.

Bronsted-Lowry theory states that a compound which is capable of accepting protons from another compound is a base while a compound that transfers protons to other compounds is categorised as an acid.  The compounds listed in the answer are capable of accepting protons because of the availability of lone pairs of protons.

Hence we can conclude that the compounds that re bases in aqueous solutions are as listed above.

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You have two beakers. One beaker contains 100 mL of NaOH (a strong base); the other contains 100 mL of aqueous Na3PO4 (a weak base). You test the pH of each solution. Which of the following statements is true ?

Answers

Answer:

D. If the pH of NaOH is 12, then that of Na₃PO₄ solution has to be lesser than 12.

Explanation:

In this problem, we are comparing the pH of a strong base to a weak base. A strong base is one that ionizes completely in aqueous solutions where as a weak base ionizes slightly.

The pH scale is good tool for measuring the acidity and alkalinity of various substances. It ranges from 1 - 14;

   

      1                                      7                                               14

                         ←                                       →

      increasing acidity                          increasing alkalinity

                                        neutrality

Strong bases have their pH value close to 14 and weak bases are close to 7.

Since Na₃PO₄ is a weak base, it will have lesser pH value compared to a strong base such as NaOH

The question lack options, that are as follows"

a. The Na3PO4 has a higher pH because it has more sodium ions than NaOH. NaOH(aq- Na3PO4(aq)b. It is possible for the solutions in each beaker to have the same pHC. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be greater than 12.00.d. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be less than 12.00.

The following statements are true in the given question:

d. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be less than 12.00.

We know that:

NaOH is a strong base and Na3PO4 is a weak base.  As the strength of OH- in 100ml NaOH and that of OH- in 100ml  Na3PO4 is different. They have different pH values.  As we know that pH is inversely proportional to H+ ion concentration.  This means the higher the pH value lower is H+ ion concentration.  

Again,

PH +POH =14

From the above equation,

the higher the PH value of a solution less will be its value of POH vice versa. Hence greater is the OH- ion concentration.  

So,

the pH of a solution is directly proportional to OH-ion concentration.  

Thus, If pH NaOH = 12.00, NaOH is a strong base and Na3PO4 is a weak base. For the solution, the weak base OH-ion concentration is less. Clearly, the pH of Na3PO4 is less than 12.00.

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Conceptual Checkpoint 18.13 When 1,3-dinitrobenzene is treated with nitric acid and sulfuric acid at elevated temperature, the product is 1,3,5-trinitrobenzene. Draw the sigma complex for each possible pathway to compare the relative stability of each sigma complex. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph.

Answers

Using sulfuric acid in the nitration of benzene generates a more reactive nitronium ion, which then reacts with benzene. The detailed mechanisms of nitration and sulfonation involve sigma complexes with resonance stabilization. An energy diagram for nitration shows intermediates and activation energy.

The importance of using sulfuric acid in the nitration of benzene by nitric acid is to activate the HNO₃, creating a more reactive electrophile, the nitronium ion (NO₂+). This ion then reacts with benzene to form nitrobenzene. In the mechanism of the sulfonation of benzene, sulfur trioxide (SO₃) acts as the electrophile, which is generated from sulfuric acid. The detailed mechanisms for both reactions involve the formation of a sigma complex with resonance forms and the restoration of aromaticity through deprotonation.

For the nitration of benzene, an energy diagram shows the activation energy and intermediates formed. The sigma complex for 1,3-dinitrobenzene undergoing further nitration to form 1,3,5-trinitrobenzene illustrates how the meta position stabilizes the complex by avoiding the creation of high-energy intermediates with adjacent positive charges, as seen in ortho and para substitution.

The equations representing the nitration and sulfonation of benzene are as follows:

Nitration: C₆H₆ + HNO₃ -> C₆H₅NO₂ + H₂OSulfonation: C₆H₆ + SO₃/H₂SO₄ -> C₆H₅SO₃H + H₂O

An alkyne with the molecular formula C6H10 was treated with ozone followed by water to produce only one type of carboxylic acid. Draw the structure of the starting alkyne and the product of ozonolysis.

Answers

Final answer:

The starting alkyne is 3-hexyne, and after the ozonolysis process and treatment with water, the resulted product is hexanoic acid.

Explanation:

In the given question, an alkyne with the molecular formula C6H10 is treated with ozone followed by water, to produce one type of carboxylic acid via the process of ozonolysis. The starting alkyne for this reaction probably is 3-hexyne. During ozonolysis, the alkyne triple bond is cleaved, forming two equivalent aldehydes. But these aldehydes are further oxidized into carboxylic acids when water is used as second reagent. The produced product, hence, is hexanoic acid.

Remember, in the process of ozonolysis, alkynes are oxidized and cleaved into smaller molecules. These molecules usually have carbonyl groups such as aldehydes and ketones. But in this scenario, because of the hydration step, we end up with a carboxylic acid.

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Gasoline is a remarkably interesting soup of hydrocarbons of various sorts, with bits of this and that added, but the average chemistry is not too far from being carbon and hydrogen, with two hydrogen atoms for each carbon. Burning involves combining gasoline with oxygen to make water and carbon dioxide. (Other things that are made in small quantities, such as carbon monoxide, are not as nice.) The chemical formula for burning gasoline can then be written something like: CH2+1.5 O2 --> CO2+H2O (If you don’t like having one-and-a-half oxygen molecules, you can think of two hydrocarbons plus three oxygens making two carbon dioxides and two waters; it is the same thing, really.) In burning, each carbon atom, C, in gasoline eliminates two hydrogens and replaces them with two oxygens each carbon atom weighs 12 atomic mass units each hydrogen weighs 1 each oxygen weighs 16; So, CH2 starts out weighing 14 (12 from carbon and 2 from hydrogen), and CO2 ends up weighing 44 (12 from carbon and 32 from oxygen)—the weight has more than tripled. Rounding that off a little, the total weight of CO2 put out by a typical U.S. driver is three times larger than the weight of gasoline burned. To get the number of pounds of CO2 per year from a typical car, then, multiply your answer from the previous question by 3.

Answers

Answer:GASOLINE IS NOT FUYKING SOUP IF YOU EAT IT YOULL DIE

Explanation:

Just a fair warning

This answer explains that during the combustion of gasoline, each carbon atom forms carbon dioxide (CO₂) and each hydrogen atom forms water (H₂O). This process increases the total mass due to the addition of oxygen atoms, resulting in CO₂ emissions being roughly three times the weight of the gasoline burned.

In this question, we explore the combustion of gasoline, a complex mixture of hydrocarbons. The main reaction for burning gasoline can be approximated by the equation:

CH₂ + 1.5 O₂ → CO₂ + H₂O

This indicates that each carbon atom in the gasoline molecule combines with oxygen to form carbon dioxide (CO₂), while each hydrogen atom combines with oxygen to form water (H₂O). The average chemical formula for gasoline is close to CH₂; thus, if you burn hydrocarbons, the products will primarily be CO₂ and H₂O.

For example, burning gasoline with the empirical formula CH₂ involves replacing two hydrogen atoms with oxygen, resulting in carbon dioxide and water. Here's a more balanced version of the reaction:

2 CH₂ + 3 O₂ → 2 CO₂ + 2 H₂O

This reaction results in a mass increase as the products (CO₂ and H₂O) weigh more than the original reactants (CH₂ and O₂). Specifically, for each carbon atom (12 atomic mass units) and two hydrogen atoms (2 atomic mass units) in the gasoline, the resulting CO₂ and H₂O (carbon dioxide: 44 AMU; water: 18 AMU) demonstrate an overall tripling of mass due to the addition of oxygen atoms.

By understanding this principle, one can estimate that the weight of CO₂ released by burning gasoline is roughly three times the weight of the gasoline itself. This is why a typical car emits a substantially larger mass of CO₂ relative to the fuel it consumes.

Calculate the amount of heat released to convert 150.0 g of to water to ice at 0ºC.
-50100 J

-339,000 J

-627 J

-307.5 J

Answers

Answer:

There correct answer is option 1 (-50100 J)

Explanation:

Step 1: Data given

Mass of water = 150.0 grams

ΔHfus = 334 J/g

Temperature = 0°C

ΔHfus = the amount of energy needed to change phase of 1 mol water to ice

Step 2: Calculate the amount of heat required

Q = m*ΔHfus

⇒Q = the amount of heat reuired = TO BE DETERMINED

⇒m =the mass of water = 150.0 grams

⇒ΔHfus = 334 J/g

Q = 150.0 grams * 334 J/g

Q = 50100 J  of heat required

Step 3: Calculate heat released

Qrequired = -Q released

Qreleased = -50100 J

There correct answer is option 1 (-50100 J)

Answer:

The answer is -50100 J

Explanation:

I just took the test as I'm in GCA as well (11th grade). My teacher walked us through each formula and gave us multiple practice questions in Jigsaw.

Honestly, all you need to be aware of is the fusion formula which is:

q = m*Hfusion

q = amount of energy

m = mass in grams

Hfusion = 334 J/g (it will not change)

Write down what we're given and what we're looking for:

q = ?

m = 150

Hfusion = 334 J/g

Set up the equation:

q = 150 * 334

Multiply 150 by 334 to get 50100.

You must keep in mind that we're finding how much heat is released which means the energy will be negative.

Add the negative sign to the number to get -50100 Joules

I don't know why that chart is there, it doesn't do anything for this equation. Disregard it for this problem.

Hope I helped! :D

The copper(I) ion forms a chloride salt (CuCl) that has Ksp = 1.2 x 10-6. Copper(I) also forms a complex ion with Cl-:Cu+ (aq) + 2Cl- (aq) ⇄ CuCl2- (aq) K = 8.7 x 104(a) Calculate the solubility of CuCl in pure water. (Ignore CuCl2- formation for part a).(b) Calculate the solubility of CuCl in 0.100 M NaCl solution.

Answers

Answer: (a) The solubility of CuCl in pure water is [tex]1.1 \times 10^{-3} M[/tex].

(b) The solubility of CuCl in 0.1 M NaCl is [tex]9.5 \times 10^{-3} M[/tex].

Explanation:

(a)  Chemical equation for the given reaction in pure water is as follows.

           [tex]CuCl(s) \rightarrow Cu^{+}(aq) + Cl^{-}(aq)[/tex]

Initial:                         0            0

Change:                    +x           +x

Equilibm:                   x             x

[tex]K_{sp} = 1.2 \times 10^{-6}[/tex]

And, equilibrium expression is as follows.

          [tex]K_{sp} = [Cu^{+}][Cl^{-}][/tex]

       [tex]1.2 \times 10^{-6} = x \times x[/tex]

             x = [tex]1.1 \times 10^{-3} M[/tex]

Hence, the solubility of CuCl in pure water is [tex]1.1 \times 10^{-3} M[/tex].

(b)  When NaCl is 0.1 M,

       [tex]CuCl(s) \rightarrow Cu^{+}(aq) + Cl^{-}(aq)[/tex],  [tex]K_{sp} = 1.2 \times 10^{-6}[/tex]

   [tex]Cu^{+}(aq) + 2Cl^{-}(aq) \rightleftharpoons CuCl_{2}(aq)[/tex],  [tex]K = 8.7 \times 10^{4}[/tex]

Net equation: [tex]CuCl(s) + Cl^{-}(aq) \rightarrow CuCl_{2}(aq)[/tex]

               [tex]K' = K_{sp} \times K[/tex]

                          = 0.1044

So for, [tex]CuCl(s) + Cl^{-}(aq) \rightarrow CuCl_{2}(aq)[/tex]

Initial:                     0.1                 0

Change:                -x                   +x

Equilibm:            0.1 - x                x

Now, the equilibrium expression is as follows.

              K' = [tex]\frac{CuCl_{2}}{Cl^{-}}[/tex]

         0.1044 = [tex]\frac{x}{0.1 - x}[/tex]

              x = [tex]9.5 \times 10^{-3} M[/tex]

Therefore, the solubility of CuCl in 0.1 M NaCl is [tex]9.5 \times 10^{-3} M[/tex].

Final answer:

The solubility of CuCl in pure water and in 0.100 M NaCl solution both turn out to be 1.1 x 10^-3 M when formation of CuCl2- is ignored, determined using the provided Ksp.

Explanation:

To calculate the solubility of CuCl in pure water, we can use the solubility product constant (Ksp). The dissociation of CuCl can be represented as:

CuCl(s) ⇌ Cu+(aq) + Cl-(aq)

Let the solubility of CuCl be 's' moles per liter. At equilibrium, the concentration of Cu+ and Cl- ions will both be 's' M. So, the Ksp expression for CuCl is:

Ksp = [Cu+][Cl-] = (s)(s) = s²

Giving us:

s = √(1.2 x 10^-6) = 1.1 x 10^-3 M

This is the solubility of CuCl in pure water.

For the solubility of CuCl in 0.100 M NaCl solution, we have to consider the common ion effect. In this case, Cl- is the common ion. With the presence of 0.100 M NaCl, the concentration of Cl- ions at equilibrium will be higher. However, since we ignore the formation of CuCl2-, the solubility will still be governed by the Ksp of CuCl. The calculation will remain the same as in pure water, due to the assumption of ignoring CuCl2- formation:

s = 1.1 x 10^-3 M

Therefore, the presence of NaCl does not affect the solubility under the given conditions for this specific case.

what do you think could be happening to the sand eels​

Answers

Answer:

is there like a passage to answer this question?

Explanation:

Answer:

Increasing fishing for them is thought to be causing problems for some of their natural predators, especially the auks which take them in deeper water. They are also tied as flies to catch fish. An instance of this was the RSPB report linking a population crash of seabirds in the North Sea to fishing for sand eels.

Explanation:

The compound most likely to be ionic is: carbon tetrachloride, potassium fluoride, carbon dioxide, or iodine monochloride?

Answers

Answer:

Potassium fluoride

Explanation:

Because potassium is strongly electropositive combined ionically with Fluorine which is highly electronegative this has the greatest tendency of been ionic

Convert 10 liter into m3.

Answers

0.01 cubic meters
Hope this helps

10 litres = 0.01 cubic meter

Which of the following statements concerning gas pressure is/are correct? (1) Gas pressure arises from gas molecules sticking to the wall of the container holding the gas. (2) The force exerted on the inside walls of a gas-filled container is inversely proportional to the number of gas molecules within the container. (3) As the temperature of a gas increases, gas molecules exert more force on the walls of their container.

Answers

Answer:

As the temperature of a gas increases, gas molecules exert more force on the walls of their container.

Explanation:

Pressure is the force exerted by a substance per unit area on another substance. The pressure of a gas is the force that the gas exerts on the walls of its container.

Gases collide frequently with each other and the walls of the container. This pressure of the gas increases with increase in temperature since increase in temperature increases the kinetic energy of gas molecules. They now collide more frequently with the walls of the container hence the answer.

The gas pressure is defined as the force exerted by the gas particles when they collide with the walls of the container. It is the pressure exerted per unit area.

The correct option is:

Option C. As the temperature of a gas increases, gas molecules exert more force on the walls of their container.

The correct explanation can be given as:

The gas molecules are in random motions, and continuously exert pressure on the walls of the container.

As the temperature rises, the kinetic energy of the particles is also increased, which causes a faster collision.

Thus, the gas pressure is increased as the temperature is increased.

Therefore, option C is correct.

To know more about gas pressure, refer to the following link:

https://brainly.com/question/18124975

what is the molecule OH- called?

Answers

Answer:

it hydroxide ion

Hope it will help you

Final answer:

The molecule OH- is termed as a hydroxide ion. It comprises one hydrogen ion and one oxygen ion and holds a negative charge. Hydroxide ions are observed in water-based solutions and play a crucial role in chemical reactions such as hydrolysis; they also impact the pH levels in solutions.

Explanation:

The molecule OH- is called a hydroxide ion. This comes from the fact that it consists of one hydrogen ion (H) and one oxygen ion (O). An ion is an atom or molecule that carries a charge, in this case, the charge of the hydroxide ion is -1 because it has gained one electron. Hydroxide ions are found in solutions resulting from the ionization of water.

The molecule OH- plays an important role in various chemical reactions. For example, in hydrolysis, a molecule of water disrupts a compound; the water splits into H and OH. One part of the divided compound bonds with the hydrogen atom, and the other part bonds with the hydroxide group. The presence of hydroxide ions also has a significant effect in determining the pH of a solution; the higher the concentration of hydroxide ions, the more basic or alkaline the solution is.

Learn more about Hydroxide Ion here:

https://brainly.com/question/36592185

#SPJ2

12. The Action of Phospholipases The venom of the Eastern diamondback rattler and the Indian cobra contains phospholipase A2, which catalyzes the hydrolysis of fatty acids at the C-2 position of glycerophospholipids. The phospholipid breakdown product of this reaction is lysolecithin (lecithin is phosphatidylcholine). At high concentrations, this and other lysophospholipids act as detergents, dissolving the membranes of erythrocytes and lysing the cells. Extensive hemolysis may be life- threatening. (a) All detergents are amphipathic. What are the hydrophilic and hydrophobic portions of lysolecithin

Answers

Answer:

Explanation:

Compounds derived from Phosphatidyl choline are referred to as Lysolecithins.  These compounds are  amphiphatic in nature and have both hydrophilic and hydrophobic regions.

Choline, glycerol, and phosphate represent the hydrophyilic portion of lysolecithins,while the fatty acid on C1 is hydrophobic in nature.

Glycerol, choline and phosphate act as a polar tail whereas the fatty acid acts as a long polar head which represents an amphipathic molecule like detergents.

A chemist fills a reaction vessel with 9.20 atm nitrogen monoxide (NO) gas, 9.15 atm chlorine (CI) gas, and 7.70 atm nitrosyl chloride (NOCI) gas at a temperature of 25.0°C. Under these conditions, calculate the reaction free energy AG for the following chemical reaction: 2NO(g) +CI (8) - 2NOCI (8) Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoule

Answers

Answer:

The reactions free energy [tex]\Delta G = -49.36 kJ[/tex]

Explanation:

From the question we are told that

      The pressure of (NO) is [tex]P_{NO} = 9.20 \ atm[/tex]

      The  pressure of  (Cl) gas is  [tex]P_{Cl} = 9.15 \ atm[/tex]

       The  pressure of nitrosly chloride (NOCl) is [tex]P_{(NOCl)} = 7.70 \ atm[/tex]

The reaction is

              [tex]2NO_{(g)} + Cl_2 (g)[/tex]    ⇆   [tex]2 NOCl_{(g)}[/tex]

 From the reaction we can  mathematically evaluate the [tex]\Delta G^o[/tex] (Standard state  free energy ) as

                    [tex]\Delta G^o = 2 \Delta G^o _{NOCl} - \Delta G^o _{Cl_2} - 2 \Delta G^o _{NO}[/tex]

The Standard state  free energy for NO is  constant with a value  

                 [tex]\Delta G^o _{NO} = 86.55 kJ/mol[/tex]

 The Standard state  free energy for [tex]Cl_2[/tex] is  constant with a value                  

             [tex]\Delta G^o _{Cl_2} = 0kJ/mol[/tex]

 The Standard state  free energy for [tex]NOCl[/tex] is  constant with a value

         [tex]\Delta G^o _{NOCl} =66.1kJ/mol[/tex]

Now substituting this into the equation

        [tex]\Delta G^o = 2 * 66.1 - 0 - 2 * 87.6[/tex]

                [tex]= -43 kJ/mol[/tex]

The pressure constant is evaluated as

         [tex]Q = \frac{Pressure \ of \ product }{ Pressure \ of \ reactant }[/tex]

Substituting  values  

        [tex]Q = \frac{(7.7)^2 }{(9.2)^2 (9.15) } = \frac{59.29}{774.456}[/tex]

           [tex]= 0.0765[/tex]

The free energy for this reaction is evaluated as

           [tex]\Delta G = \Delta G^o + RT ln Q[/tex]

Where R is gas constant with a value  of  [tex]R = 8.314 J / K \cdot mol[/tex]

          T is temperature in K  with a given value of  [tex]T = 25+273 = 298 K[/tex]

   Substituting value

                [tex]\Delta G = -43 *10^{3} + 8.314 *298 * ln [0.0765][/tex]

                       [tex]= -43-6.36[/tex]

                      [tex]\Delta G = -49.36 kJ[/tex]

A mixture of compounds containing diethylamine, phenol, ammonia, and acetic acid is separated using liquid-liquid extraction as follows: Step 1: Concentrated HCl is added followed by draining the aqueous layer. Step 2: Dilute NaOH is added to the organic layer followed by draining the aqueous layer. Step 3: Concentrated NaOH is added to the organic layer followed by draining the aqueous layer. Which compound would you expect to be extracted into the aqueous layer after the addition of dilute NaOH, step 2?

Answers

Answer:

I would expect to extract the acetic acid.

Explanation:

In the first step, since we are adding a concentrated acid, it will react with the bases present in the mixture (diethylamine and ammonia) forming salts, which are soluble in water. Therefore, after draining the aqueous layer, we will have phenol and acetic acid left in the organic layer.

In the second step, we are adding a diluted base, so it will react with a strong acid. This compound is acetic acid, and its salt will be present in the aqueous layer. Phenol will be left on the organic layer.

Which reaction is an example of heterogeneous catalysis?

Answers

Answer:

Explanation:

Industrial examples

Process Reactants, Product(s)

Ammonia synthesis (Haber–Bosch process) N2 + H2, NH3

Nitric acid synthesis (Ostwald process) NH3 + O2, HNO3

Hydrogen production by Steam reforming CH4 + H2O, H2 + CO2

Ethylene oxide synthesis C2H4 + O2, C2H4O

Answer:

The answer is A - Ethene gas reacts with hydrogen gas by using a nickel catalyst.

Explanation:

just did on Edge

Be sure to answer all parts.

(a) How many atoms are directly bonded to the central atom in a trigonal planar molecule?

i. two
ii. three
iii. six
iv. eight

(b) How many atoms are directly bonded to the central atom in a trigonal bipyramidal molecule?

i. three
ii. four
iii. five
iv. six

(c) How many atoms are directly bonded to the central atom in an octahedral molecule?

i. three
ii. four
iii. six
iv. eight

Answers

Answer:

a) ii

b)iii

c)iii

Explanation:

three atoms directly bonded then only it is possible to achieve trigonal planar

trigonal bipyramidal means five atoms should attach to central atom

for octahedral six atoms must directly connected to central atom

Iron (II) is measured in abandoned mine drainage using a phenanthroline method (Standard Methods for the examination of water and wastewater, method 3500-Fe). In 9. solution and diluted to 100.0 ml. The solution turns deep red and is measured at 510 nm. A series of standards from 0.50 -2.00 ug/ml iron(II) are prepared and their absorbance measured. The data for these solutions is given below. Using this data calculate the concentration of iron(II) in the original mine drainage samples. Fe Conc (ug/ml) Absorbance 0.00 0.50 1.000.134 1.50 2.00 0.002 0.045 0.096 0.196 Mine drainage 0.115 0.120

Answers

Answer:

Mine drainage Sample 1:   [tex][Fe(II)] sample 1 = \frac{121 \mu gFe(II)}{1ml} = 121 \frac{\mu g}{ml}[/tex]

Mine drainage Sample 2:   [tex][Fe(II)] sample 2 = \frac{127 \mu gFe(II)}{1ml} = 127 \frac{\mu g}{ml}[/tex]

Explanation:

Other Questions
Multiple-choice questions on Advanced Placement exams have five options: A, B, C, D, and E. A random sample of the correct choice on 400 multiple-choice questions on a variety of AP exams1 shows that B was the most common correct choice, with 90 of the 400 questions having B as the answer. Does this provide evidence that B is more likely to be the correct choice than would be expected if all five options were equally likely? Show all details of the test. The data are available in APMultipleChoice. which is the independent variable "year" or "degrees Celsius"? While watching a movie, Daysha notices that a few brands have been conspicuously integrated with its screenplay. The main character drives a particular brand of car and drinks only a specific brand of beer. Daysha figures out that this is a marketing strategy that employs _____. product placementpreattentive effectsexplicit memory What is the measure of JL (the minor arc)? The number of years that have passed since the rock formed is the rock's ______ absolute agegeologic timelinerelative agehalf life Getaway Travel Agency surveyed a random sample of 454545 of their clients about their vacation plans. Of the clients surveyed, 212121 expected that they would go on 333 vacations in the next year. There are 516516516 Getaway Travel Agency clients. Based on the data, what is the most reasonable estimate for the number of Getaway Travel Agency clients who expect to go on 333 vacations in the next year? Choose 1 answer: Choose 1 answer: At the beginning of Year 1, Mitchell Company purchased office equipment for $15,000. The machine has an estimated residual value of $1,000 and an estimated service life of 5 years. If Mitchell uses straight-line depreciation, it will make which of the following entries related to depreciation at the end of Year 1? A telephone poll conducted July 9th through July 13th, 2008, found that 'one in five American adults - 22% - believe thatany state or region has the right to 'peaceably secede from the United States and become an independent republicWhat answer would you give if you received this call? Why?I believe any state or region has theright to peaceably secede and becomean independent republie:AgreeDisagreeNot sure When Alyssa imports data from one database to another database, she notices some of the field names are different. She will need to _____ them.mapmergelinkexport The ransom note in the Lindbergh kidnapping case included some obvious spelling errors and other foreign and regional language. 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Each dot represents how many boxes it took to get all 444 prizes in that trial. Temporary Housing Services Incorporated (THSI) is considering a project that involves setting up a temporary housing facility in an area recently damaged by a hurricane. THSI will lease space in this facility to various agencies and groups providing relief services to the area. THSI estimates that this project will initially cost $ 6 million to set up and will generate $ 23 million in revenues during its first and only year in operation (paid in one year). Operating expenses are expected to total $ 12 million during this year and depreciation expense will be another $ 2 million. THSI will require no working capital for this investment. THSI's marginal tax rate is 35%.Ignoring the original investment of $5 million, what is THSI's free cash flow for the first and only year of operation?a. $5.0 millionb. $3.75 millionc. $8.0 milliond. $6.25 million On March 1, 2021, Beldon Corporation purchased land as a factory site for $60,000. An old building on the property was demolished, and construction began on a new building that was completed on December 15, 2021. Costs incurred during this period are listed below: Demolition of old building $ 4,000 Architects fees (for new building) 12,000 Legal fees for title investigation of land 2,000 Property taxes on land (for period beginning March 1, 2021) 3,000 Construction costs 500,000 Interest on construction loan 5,000 Salvaged materials resulting from the demolition of the old building were sold for $2,000. Required: Determine the amounts that Beldon should capitalize as the cost of the land and the new building. This table gives a few (x,y)(x,y)left parenthesis, x, comma, y, right parenthesis pairs of a line in the coordinate plane.xxxyyy-7979minus, 79-6868minus, 68-6868minus, 68-5151minus, 51-5757minus, 57-3434minus, 34What is the xxx-intercept of the line? What are the solutions to x2 + 4x - 12 = 0?x= -2 or x = 6x= 3 or x= -4x= 2 or x = -6x= 4 or x = -3 The frequency table represents the job status of a number of high school students.A 4-column table with 3 rows titled job status. The first column has no label with entries currently employed, not currently employed, total. The second column is labeled looking for job with entries 12, 38, 50. The third column is labeled not looking for a job with entries 28, 72, 100. The fourth column is labeled total with entries 40, 110, 150.Which shows the conditional relative frequency table by column?A 4-column table with 3 rows titled job status. The first column has no label with entries currently employed, not currently employed, total. The second column is labeled looking for a job with entries 0.3, nearly equal to 0.33, 1.0. The third column is labeled not looking for job with entries 0.7, nearly equal to 0.65, 1.0. the fourth column is labeled total with entries nearly equal to 0.27, nearly equal to 0.73, 1.0.A 4-column table with 3 rows titled job status. The first column is blank with entries currently employed, not currently employed, total. The second column is labeled Looking for a job with entries 0.12, 0.38, 050. The third column is labeled not looking for a job with entries 0.28, 0.72, 1.00. The fourth column is labeled total with entries 0.4, 1.1, 1.5.A 4-column table with 3 rows titled job status. The first column has no label with entries currently employed, not currently employed, total. The second column is labeled looking for a job with entries 0.24, 0.76, 1.0. The third column is labeled not looking for a job with entries 0.28, 0.72, 1.0. The fourth column is labeled total with entries nearly equal to 0.27, nearly equal to 0.73, 1.0.A 4-column table with 3 rows titled job status. The first column has no label with entries currently employed, not currently employed, total. The second column is labeled looking for job with entries 0.08, nearly equal to 0.25, nearly equal to 0.33. The third column is labeled not looking for a job with entries nearly equal to 0.19, 0.48, nearly equal to 0.67. The fourth column is labeled total with entries nearly equal to 0.27, nearly equal to 0.73, 1.0. 65=15+x^2 solve for x A rectangle has a lenght that is 9 inches less than twice its width. The area of the rectangle is 180 square inches. What is the width of the rectangle? CT Stores has debt with a book value of $325,000 and a market value of $319,000. The firm's equity has a book value of $526,000 and a market value of $684,000. The tax rate is 21 percent and the cost of capital is 11.2 percent. What is the market value of this firm based on MM Proposition I without taxes