Answer:
Degree of ionization = 0.0377
pH of the solution = 1.769
Explanation:
Initial concentration of HF = 0.45 M
[tex]K_a = 6.8 \times 10^{-4}[/tex]
[tex]HF \leftrightharpoons H^+ + F^-[/tex]
Initial 0.45 0 0
At equi 0.45 - x x x
Equilibrium constant = [tex]\frac{[H^+][F^-]}{HF}[/tex]
[tex]6.8 \times 10^{-4}= \frac{[x][x]}{0.45 - x}[/tex]
[tex]x^2 + 6.8 \times 10^{-4} x - 6.8 \times 10^{-4} \times 4.5 = 0[/tex]
x = 0.017 M
x = Cα
α = Degree of ionization
C = Concentration
Degree of ionization = [tex]\frac{0.017}{0.45} = 0.0377[/tex]
[tex]pH = -log[H^+][/tex]
[H^+]=0.017 M
[tex]pH = -log[0.017][/tex]
= 1.769
Final answer:
The acid dissociation reaction for hydrofluoric acid in water is [tex]HF (aq) + H_2O (l)[/tex] ⇌ [tex]H_3O^+ (aq) + F- (aq)[/tex]. The concentration of a 0.1 L solution containing 0.05 g of HF is 0.025 M. To find the pH for such a solution using the given Ka, the ICE table method can be utilized.
Explanation:
To answer your questions regarding hydrofluoric acid (HF) and its properties, we can proceed as follows:
a) Write out the acid dissociation reaction for hydrofluoric acid. Label the conjugate acid/base pairs.
Hydrofluoric acid dissociates in water as follows:
[tex]HF (aq) + H_2O (l)[/tex] ⇌ [tex]H_3O^+ (aq) + F- (aq)[/tex]
In this reaction, HF is the conjugate acid and F- is the conjugate base.
b) What is the concentration (M) of a solution containing 0.05 g of HF in 0.1 L H2O?
The molecular weight of HF is approximately 20.01 g/mol. To find the molarity, first convert grams to moles:
0.05 g HF × (1 mol HF/20.01 g HF) = 0.0025 mol HF
Then, divide the moles of HF by the volume of the solution in liters:
0.0025 mol HF / 0.1 L = 0.025 M
c) Using the given Ka value, calculate the pH of the solution from part b
Since HF is a weak acid, and given that Ka = 7.2 × [tex]10^-^4[/tex], you can use the ICE table method to find the concentration of H3O+ and then calculate the pH.
how many grams of solid NaOH are required to prepare a 400ml of a 5N solution? show your work!
Answer: The mass of solid NaOH required is 80 g
Explanation:
Equivalent weight is calculated by dividing the molecular weight by n factor. The equation used is:
[tex]\text{Equivalent weight}=\frac{\text{Molecular weight}}{n}[/tex]
where,
n = acidity for bases = 1 (For NaOH)
Molar mass of NaOH = 40 g/mol
Putting values in above equation, we get:
[tex]\text{Equivalent weight}=\frac{40g/mol}{1eq/mol}=40g/eq[/tex]
Normality is defined as the umber of gram equivalents dissolved per liter of the solution.
Mathematically,
[tex]\text{Normality of solution}=\frac{\text{Number of gram equivalents} \times 1000}{\text{Volume of solution (in mL)}}[/tex]
Or,
[tex]\text{Normality of solution}=\frac{\text{Given mass}\times 1000}{\text{Equivalent mass}\times \text{Volume of solution (in mL)}}[/tex] ......(1)
We are given:
Given mass of NaOH = ?
Equivalent mass of NaOH = 40 g/eq
Volume of solution = 400 mL
Normality of solution = 5 eq/L
Putting values in equation 1, we get:
[tex]5eq/L=\frac{\text{Mass of NaOH}\times 1000}{40g/eq\times 400mL}\\\\\text{Mass of NaOH}=80g[/tex]
Hence, the mass of solid NaOH required is 80 g
in which of these substances is significant hydrogen bonding possible: methylene chloride (CH2Cl2), phosphine (PH3), chloramine (NH2Cl), acetone (CH3COCH3) ?
Answer:
Significant hydrogen bonding is possible in [tex]NH_{2}Cl[/tex]
Explanation:
Hydrogen bonding takes place between an electronegative atom (O, N and F) and a H atom attached to those electronegative atoms.Lewis structure reveals that H atom attached to N in [tex]NH_{2}Cl[/tex].In all other compounds no such H atom is present attached to O or N or F.Hence significant hydrogen bonding is possible only in [tex]NH_{2}Cl[/tex]Lewis structures are given below.The only substance from above in which significant hydrogen bonding possible is chloramine ( NH2Cl )
What are organic compounds?Organic compounds are substances which contain carbon and hydrogen. Some few groups of organic compounds include:
AlkanesAlkenesAlkynesAlkanolsAlkanalsAlkanonesKetonesAminesSo therefore, the only substance from above in which significant hydrogen bonding possible is chloramine ( NH2Cl )
Learn more about organic compounds:
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When 0.491 grams of a protein were dissolved in 44 mL of benzene at 24.4 degrees C, the osmotic pressure was found to be 50.9 torr. Calculate the molar mass of the protein.
Answer:
4057.85 g/mol
Explanation:
Hello, the numerical procedure is shown in the attached file.
- In this case, since we don't have the density of the protein, we must assume that the volume of the solution is solely given by the benzene's volume, in order to obtain the moles of the solute (protein).
-Van't Hoff factor is assumed to be one.
Best regards.
To calculate the molar mass of the protein, use the formula M = (RT) / (V * P), where M is the molar mass, R is the ideal gas constant, T is the temperature, V is the volume, and P is the osmotic pressure.
Explanation:To calculate the molar mass of the protein, we can use the formula:
M = (RT) / (V * P)
Where M is the molar mass, R is the ideal gas constant (0.0821 L.atm/mol.K), T is the temperature in Kelvin (24.4 + 273 = 297.4 K), V is the volume in liters (44 mL / 1000 = 0.044 L), and P is the osmotic pressure in atm (50.9 torr / 760 = 0.067 atm).
Substituting the values into the formula:
M = (0.0821 * 297.4) / (0.044 * 0.067) = 25567.14 g/mol
Therefore, the molar mass of the protein is approximately 25567.14 g/mol.
An AM radio station broadcasts at 1030 kHz , and its FM partner broadcasts at 98.5 MHz .
partA;Calculate the energy of the photons emitted by the AM radio station.
partB;Calculate the energy of the photons emitted by the FM radio station.
partC;Compare the energy of the photons emitted by the AM radio station with the energy of the photons emitted by the FM radio station.
The energy of the photons emitted by the AM and FM radio stations can be calculated using Planck's equation (E = hf). The calculated energies show that the FM radio station's photons have higher energy than the AM radio station's photons.
Explanation:To calculate the energy of the photons emitted by radio stations, we use the formula:
E = hf, where E is the energy, h is Planck's constant (6.62607015 × 10⁻³⁴ Js) and f is the frequency.
(For the sake of this calculation, we are going to convert the frequency from kHz and MHz to Hz.)
The AM radio station broadcasts at 1030 kHz, which is equal to 1.03×10⁶ Hz. Substitute the values into the formula: E = (6.62607015 × 10⁻³⁴ Js) × (1.03 × 10⁶ Hz) = 6.825 × 10⁻²⁸ joules.The FM radio station broadcasts at 98.5 MHz, which is equal to 98.5×10^6 Hz. Substitute the values into the formula: E = (6.62607015 × 10⁻³⁴ Js) × (98.5 × 10⁶ Hz) = 6.527 × 10⁻²⁶ joules.Comparing these energy values, it's clear that the FM radio station's emitted photons have a higher energy than the AM radio station's photons, due to its higher frequency.
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Air enters a diffuser witha velocity of 400 m/s, a pressure of 1 bar and temperature of 25 C. It exits with a temperature of 100 C. What is the exit velocity of the air? Assume there are no heat losses or change in potential energy Data:= 0.718 kJ/kg.°C. MW = 28.9 g/mol
Answer:
Exit velocity of air is 96.43 m/s.
Explanation:
Given that
[tex]V_1=400\ m/s[/tex]
[tex]T_1=25C[/tex]
[tex]T_2=100C[/tex]
For air
[tex]C_p=1.005\ KJ/kg.K[/tex]
Now from first law of thermodynamics for open system at steady state
[tex]h_1+\dfrac{V_1^2}{2000}+Q=h_2+\dfrac{V_2^2}{2000}+w[/tex]
For diffuser
[tex]h_1+\dfrac{V_1^2}{2000}=h_2+\dfrac{V_2^2}{2000}[/tex]
We know that
[tex]h=C_pT[/tex]
[tex]h_1+\dfrac{V_1^2}{2}=h_2+\dfrac{V_2^2}{2000}[/tex]
[tex]1.005\times 25+\dfrac{400^2}{2000}=1.005\times 100+\dfrac{V_2^2}{2}[/tex]
[tex]V_2=96.43\ m/s[/tex]
So the exit velocity of air is 96.43 m/s.
A weak acid. What is the pH of a 0.1 M solution of acetic acid (pKa = 4.75)?
(Hint: Let x be the concentration of H+ ions released from acetic acid when it dissociates. The solutions to a quadratic equation of the form ax^2 + bx + c = 0 are x = (-b +- squareroot (b^2- 4ac)/2a.
Answer:
pH of acetic acid solution is 2.88
Explanation:
[tex]pK_{a}=4.75[/tex]
or, [tex]-log(K_{a})=4.75[/tex]
or, [tex]K_{a}=10^{-4.75}=1.78\times 10^{-5}[/tex]
We have to construct an ICE table to determine concentration of [tex]H^{+}[/tex] and corresponding pH. Initial concentration of acetic acid is 0.1 M.
[tex]CH_{3}COOH\rightleftharpoons CH_{3}COO^{-}+H^{+}[/tex]
I(M): 0.1 0 0
C(M): -x +x +x
E(M): 0.1-x x x
So, [tex]\frac{[CH_{3}COO^{-}][H^{+}]}{[CH_{3}COOH]}=K_{a}[/tex]
or, [tex]\frac{x^{2}}{0.1-x}=1.78\times 10^{-5}[/tex]
or, [tex]x^{2}+(1.78\times 10^{-5}\times x)-(1.78\times 10^{-6})=0[/tex]
So, [tex]x=\frac{-(1.78\times 10^{-5})+\sqrt{(1.78\times 10^{-5})^{2}+(4\times 1\times 1.78\times 10^{-6})}}{2\times 1}[/tex](M)
so, [tex]x=1.33\times 10^{-3}M[/tex]
Hence [tex]pH=-log[H^{+}]=-log(1.33\times 10^{-3})=2.88[/tex]
When a compound is dissolved in hot ethanol during a recrystallization, what is changing on a molecular level? The intermolecular forces between the solute and solvent The covalent bonds of the solute The compound slowly melts into the hot solvent The covalent bonds between the solute and solvent
Answer:
The intermolecular forces between the solute and solvent.
Explanation:
When you are heating a solvent, the intermolecular forces are reduced because the distances between molecules are large. Thus, in a solution where solvent is hot the intermolecular forces between solute and solvent are lower than those solutions where solvent is in room temperature.
The covalent bonds do not change because this mean a chemical reaction that doesn't occur in a solution.
Usually solid solutes melts in a higher temperature than boiling point in solvents. Thus, a compound normally doesn't melt in a hot solvent.
I hope it helps!
When a compound is dissolved in hot ethanol during recrystallization, the intermolecular forces between the solute and solvent are changing on a molecular level. The process of solution formation involves the formation of new intermolecular forces between the solute and solvent molecules, allowing the compound to dissolve in the solvent.
Explanation:Intermolecular forces are attractive or repulsive forces between molecules. They include London dispersion forces, dipole-dipole interactions, and hydrogen bonding. These forces influence physical properties like boiling points and solubility in molecular substances. The intermolecular forces between the solute and solvent are changing on a molecular level when a compound is dissolved in hot ethanol during recrystallization.
When the compound is dissolved in the hot solvent, the solute-solvent interactions which is also known as solvatio then naturally takes place. In addition to this, these interactions involve the formation of new intermolecular forces between the solute and solvent molecules, which are nearly as strong as the intermolecular forces within the solute and solvent alone. This favorable solution formation process allows the compound to dissolve in the solvent.
A liquid mixture contains 1 kg of water, 1.9 lb of ethanol, and 4.6 lb of methyl acetate. What is the weight fraction of ethanol in this mixture? Report your answer to the nearest hundredths place.
Answer: The weight fraction of ethanol in the mixture is
Explanation:
We are given:
Mass of water = 1 kg = 2.205 lb (Conversion factor: 1 kg = 2.205 lb)
Mass of ethanol = 1.9 lb
Mass of ethyl acetate = 4.6 lb
Mass of mixture = [2.205 + 1.9 + 4.6] = 8.705 lb
To calculate the percentage composition of ethanol in mixture, we use the equation:
[tex]\%\text{ composition of ethanol}=\frac{\text{Mass of ethanol}}{\text{Mass of mixture}}\times 100[/tex]
Mass of mixture = 8.705 lb
Mass of ethanol = 1.9 lb
Putting values in above equation, we get:
[tex]\%\text{ composition of ethanol}=\frac{1.9lb}{8.705lb}\times 100=21.8\%[/tex]
Hence, the weight fraction of ethanol in the mixture is 21.8 %
What type of chemical bond would form between an atom of carbon (C) and an atom of nitrogen (N). Explain specifically why this type of bond would form.
Answer:
Due to the low difference of electronegativity in carbon and nitrogen, these will form a covalent bond, and this covalent union of C-N is one of the most common bonds in the organic chemistry and biological systems. This type of bonds can be found in amines, amides, imines, etc. Also, a single atom of C and a single atom of N can form a cyanide, that is a triple covalent bond between the atoms.
ObIel WiLll unt COl.. USSMS A certain chemical reaction releases 31.2 kJ/g of heat for each gram of reactant consumed. How can you calculate what mass of reactant will produce 1080. J of heat? Set the math up. But don't do any of it. Just leave your answer as a math expression. Also, be sure your answer includes all the correct unit symbols. mass X ? Explanation Check ducabon ARghtsserved T of Ue Phacy The I'm esc
Answer:
The expression to calculate the mass of the reactant is [tex]m = \frac{1.080kJ}{31.2kJ/g}[/tex]
Explanation:
The amount of heat released is equal to the amount of heat released per gram of reactant times the mass of the reactant. To keep to coherence between units we need to transform 1,080 J to kJ. We do so with proportions:
[tex]1,080J.\frac{1kJ}{10^{3}J } =1.080kJ[/tex]
Then,
[tex]1.080kJ=31.2\frac{kJ}{g} .m\\m = \frac{1.080kJ}{31.2kJ/g}[/tex]
Answer:
1. The expression is: [tex]m=\frac{E}{\Delta _rH}[/tex]
2. The computed mass is: [tex]m=0.0346g[/tex]
Explanation:
Hello,
In this case, we know the so called enthalpy of reaction whose symbol and value is shown below:
[tex]\Delta _rH=31.2\frac{kJ}{g}[/tex]
In addition, we know that the energy released by the involved reactant is:
[tex]E=1080 J[/tex]
Therefore, the expression to compute the required mass, based on the given units is:
[tex]m=\frac{E}{\Delta _rH}[/tex]
Finally, the computed mass turns out:
[tex]m=\frac{1080J*\frac{1kJ}{1000J} }{31.2\frac{kJ}{g}} \\m=0.0346g[/tex]
Best regards.
One molecule of the spherically shaped, oxygen‑carrying protein in red blood cells, hemoglobin, has a diameter of 5.5 nm . What is this diameter in meters?
Answer:
[tex]5.5*10x^{-9}m[/tex]
Explanation:
As you have the diameter of the sphere in nanometers (nm), you need to use de conversion factor to find the diameter in meters (m):
First you should put the quantity that you want to convert with its respective units:
[tex]Diameter=5.5nm[/tex]
Then you put the conversion factor, always you should put the same unit that you want to convert in the denominator:
Diameter = [tex]5.5nm*\frac{1*10^{-9}m}{1nm}[/tex]
And finally, you should multiply and/or divide the quantities:
Diameter = [tex]5.5*10^{-9}m[/tex]
Define "Dispersed System", "Dispersion Medium", and "Dispersed Particles
Answer:
Dispersion system is a system in which certain particles are scattered in a continuous liquid or solid medium. The two phases present in this system are the dispersed particles and dispersion medium. These phases may or may not be present in the same state.
In a dispersion system, the particles that are dispersed are known as the dispersed particles and the medium in which the particles are dispersed is known as the dispersion medium.
List and discuss two major sources of errors in numerical methods
Answer:
There are three major sources of errors in numerical method, namely human error, truncation error and round off error, but here we have to discuss only two sources-
Human error: This type of error occurs when the experiment is being performed but student isn't attentive during the experiment, or noted down the wrong observation, this error is very difficult to detect.There are rules for significant figures and rounding off, but if we round off the values incorrectly it will lead to error in final answer.Answer:
sdfsdfsdf
Explanation:dsf
Which of the following describes what takes place
whensolutions of Pb(NO3)2 and
NH4Clare mixed? Detail the manner in which the
application of thesolubility rules reveal this answer.
A. Pb(NO3)2(aq)
+2NH4Cl(aq)-->NH4NO3(aq)
+PbCl2(s)
B. Pb2++2Cl- --> PbCl2(s)
C. Pb2+(aq) +
2NO3-(aq)+2NH+4(aq)
+2Cl-(aq)-->2NH+4(aq)
+2NO3-(aq) + PbCl2(s)
D. NH+4(aq) +
NO3-(aq)-->2NH4NO32NH4NO3(s)
E. No reaction occurs when the solutions aremixed.
Answer: The correct answer is Option B.
Explanation:
The chemical equation for the reaction of lead (II) nitrate and ammonium chloride follows:
[tex]Pb(NO_3)_2(aq.)+2NH_4Cl(aq.)\rightarrow PbCl_2(s)+2NH_4NO_3(aq.)[/tex]
Ionic form of the above equation follows:
[tex]Pb^{2+}(aq.)+2NO_3^-(aq.)+2NH_4^+(aq.)+Cl^-(aq.)\rightarrow PbCl_2(s)+2NH_4^+(aq.)+2NO_3^-(aq.)[/tex]
Net ionic equation of any reaction does not include any spectator ions.
Spectator ions are defined as the ions which does not get involved in a chemical equation. They are found on both the sides of the chemical reaction when it is present in ionic form.
As, ammonium and nitrate ions are present on both the sides of the reaction. Thus, it will not be present in the net ionic equation and are spectator ions.
The net ionic equation for the above reaction follows:
[tex]Pb^{2+}(aq.)+2Cl^-(aq.)\rightarrow PbCl_2(s)[/tex]
Solubility rules:
Chlorides of silver, mercury and lead are insoluble in water. So, they appear as a solid known as precipitate.Nitrates of most of the metals are soluble in water. So, they appear as ions in solution.Hence, the correct answer is Option B.
2.4 Bromium has two naturally occurring isotopes: 79Br, with an atomic weight of 78.918 amu, and 81Br, with an atomic weight of 80.916 amu. If the average atomic weight for Br is 79.903 amu, calculate the fraction-of-occurrences of these two isotopes.
Answer:
49.3% 81Br and 50.7% 79Br or [tex]\frac{493}{1000}[/tex] 81Br and [tex]\frac{507}{1000}[/tex] 79BR
Step-by-step explanation:
To get the fraction-of-occurrences of the isotopes we must write the following equation. x is the isotopic abundance of 81Br, we can use 1 - x to get the isotopic abundance of 79Br.
(78.918)(1 - x) + (80.916)(x) = 79.903
78.918 - 78.918x + 80.916x = 79.903
1.998x = 0.985
x = 0.493
0.493 × 100 = 49.3% 81Br
100 - 49.3 = 50.7% 79Br
49.3% 81Br and 50.7% 79Br or [tex]\frac{493}{1000}[/tex] 81Br and [tex]\frac{507}{1000}[/tex] 79BR
How many atoms are found in 4.20 g of Magnesium?
Answer:
There are 1.041×10²³ atoms in 4.20g of Magnesium.
Explanation:
To find the amount of atoms in 4.20 g of Magnesium we need de molar mass of Mg: 24.305 g/mol
According to Avogadro number there are 6.022×10²³ particles in 1 mol, so the number of atoms of Mg is:
[tex]4.20 g Mg*\frac{1 molMg}{24.305gMg} *\frac{6.022*10^{23}atoms }{1 mol Mg} = 1.041*10^{23}atoms Mg[/tex]
Answer: The number of atoms found in given amount of magnesium is [tex]1.042\times 10^{23}[/tex]
Explanation:
To calculate the number of moles, we use the equation:
[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]
Given mass of magnesium = 4.20 g
Molar mass of magnesium = 24.31 g/mol
Putting values in above equation, we get:
[tex]\text{Moles of magnesium}=\frac{4.20g}{24.31g/mol}=0.173mol[/tex]
According to mole concept:
1 mole of an element contains [tex]6.022\times 10^{23}[/tex] number of atoms
So, 0.173 moles of an element contains = [tex]0.173\times 6.022\times 10^{23}=1.042\times 10^{23}[/tex] number of atoms
Hence, the number of atoms found in given amount of magnesium is [tex]1.042\times 10^{23}[/tex]
A student made an initial 1:5 dilution of protein lysate. Then 2mL of that was added to 8mL of water. Lastly, the student made a 1:20 dilution of the second tube. What is the final dilution of protein lysate.
Answer:
The final dilution is 1:400
Explanation:
Let's analyze what we are told: we have an initial 1:5 dilution of protein lysate. This means that the initial solution (stock solution) was diluted 5 times. Then, from this dilution the student prepared another dilution taking 2 mL of the first dilution in 8 mL of water. This is the same as saying we took 1 mL of first dilution in 4 mL of water (the ratio is the same), so we now have a second 1:4 dilution of the first dilution (1:5). Finally, the student made a third 1:20 dilution, this means that the second dilution was further diluted 20 times.
So, to calculate the final dilution of protein lysate, we have to multiply all the dilution factors of every dilution prepared: in this case we have a final dilution of 1:20, this means we have a factor dilution of 20. But it was previously diluted 4 times, so we have a factor dilution of 20×4 = 80. However, this dilution was also previously diluted 5 times, so the new dilution factor is 80 × 5 = 400
This means that the final dilution of the compound was diluted a total of 400 times compared to the initial concentration of stock solution.
Compute the following:
a. 0.034 x 4.13
b. (1.6 x 10-8 )/(7.25 x 10-8 )
c. 0.034 x 4.13
5) (1 pt) The density of titanium is 4.54 g/ml. What is the volume in liters of 2.63 kg of titanium?
3) (1 pts) How many milliseconds are there in 2.25 hours?
Answer:
a. 0.14042
b. 0.221
c. equal to a.
5) 0.579 L
3) 8.1e6 ms
Explanation:
Hello,
In the attached photo you'll find the numerical procedure to get the results.
Best regards.
A certain insulation has a thermal conductivity of 0.2 W/m °C What thickness is necessary to effect a temperature drop of 400°C for a heat flux of 200 W/m2?
Answer:
It is necessary 1 meter of thickness.
Explanation:
You need to know the equation (P/A)=(k*T)/(L), where P/A is the heat flux, k is the thermal conductivity, T the temperature drop, and L the unknown thickness. So if rearrange the variables you will have that L = (k*T)/(P/A), and substituting the terms L = (0.2*400)/(200) = 1 meter
Final answer:
The necessary thickness of insulation to achieve a temperature drop of 400°C with a heat flux of 200 W/m^2, given a thermal conductivity of 0.2 W/m°C, is 0.4 meters.
Explanation:
The necessary thickness of insulation for a specific temperature drop and heat flux. By using the equation of thermal conduction Q = (kAΔT)/d, where Q is the heat flux, k is the thermal conductivity, A is the area, ΔT is the temperature difference, and d is the thickness, we can solve for the thickness d.
To start, we know that k (thermal conductivity) is 0.2 W/m°C, the temperature drop ΔT is 400°C, and the heat flux Q is 200 W/m^2. Plugging these values into the equation gives us d = (kAΔT)/Q. Since the area A is not specified, it will cancel out in this case, allowing us to solve for d directly. Rearranging the equation yields d = (kΔT)/Q, which equals (0.2 W/m°C * 400°C)/200 W/m^2, resulting in d = 0.4 m. Therefore, the thickness required for this insulation is 0.4 meters.
What percentage of the mass of a carbon-12 atom is
contributedby its electrons? Given the mass of an electron is
(1/1836)amu.
Answer:
% of mass of electrons in C = 0.0272
Explanation:
Atomic no. of carbon = 6
So, no. of electron = 6
Mass of an electron = [tex]\frac{1}{1836} amu[/tex]
Mass of 6 electrons = [tex]6 \times \frac{1}{1836} = 0.003268 amu[/tex]
Mass of C = 12.0107 u
% of mass of electrons in C = [tex]\frac{Mass\ of\ all\ electrons}{Mass\ of\ C}\times 100[/tex]
% of mass of electrons in C = [tex]\frac{0.003268}{12.0107}\times 100=0.0272 \%[/tex]
2. Sitting on a bench top are several samples: lithium metal (d = 0.53 g/mL), gold (d = 19.3 g/mL), aluminum (d = 2.70 g/mL), and lead (d = 11.3 g/mL). If all of the samples have the same mass, which one occupies the largest volume? Why?
Answer:
The sample of lithium occupies the largest volume.
Explanation:
Given the densities for the four elements, we have the expression [tex]d=\frac{m}{V}[/tex] that shows the relationship between mass and Volume to express the density of an element.
For each element we have:
[tex]d_{lithium}=\frac{m_{lithium}}{V_{lithium}}=0.53g/mL[/tex]
[tex]d_{gold}=\frac{m_{gold}}{V_{gold}}=19.3g/mL[/tex]
[tex]d_{aluminum}=\frac{m_{aluminum}}{V_{aluminum}}=2.70g/mL[/tex]
[tex]d_{lead}=\frac{m_{lead}}{V_{lead}}=11.3g/mL[/tex]
The problem says that all the samples have the same mass, so:
[tex]m_{lithium}=m_{gold}=m_{aluminum}=m_{lead}=m[/tex]
it means that m is a constant
Now, solving for the Volume in each element and with m as a constant, we have:
[tex]V_{lithium}=\frac{m}{d_{lithium}}[/tex]
[tex]V_{lithium}=\frac{1}{0.53\frac{g}{mL}} *m[/tex]
[tex]V_{lithium}=1.88\frac{mL}{g}*m[/tex]
[tex]V_{gold}=\frac{m}{d_{gold}}[/tex]
[tex]V_{gold}=\frac{1}{19.3\frac{g}{mL}} *m[/tex]
[tex]V_{gold}=5.18*10^{-2}\frac{mL}{g}*m[/tex]
[tex]V_{aluminum}=\frac{m}{d_{aluminum}}[/tex]
[tex]V_{aluminum}=\frac{1}{2.70\frac{g}{mL}} *m[/tex]
[tex]V_{aluminum}=3.70*10^{-1}\frac{mL}{g}*m[/tex]
[tex]V_{lead}=\frac{m}{d_{lead}}[/tex]
[tex]V_{lead}=\frac{1}{11.3\frac{g}{mL}} *m[/tex]
[tex]V_{lead}=8.85*10^{-2}\frac{mL}{g}*m[/tex]
If we assume m = 1g, we find that:
[tex]V_{lithium}=1.88mL[/tex]
[tex]V_{gold}=5.18*10^{-2}mL[/tex]
[tex]V_{aluminum}=3.70*10^{-1}mL[/tex]
[tex]V_{lead}=8.85*10^{-2}mL[/tex]
So we can see that the sample of lithium occupies the largest volume with 1.88mL
Note that m only can take positive values, so if you change the value of m, always will be the lithium which occupies the largest volume.
Why is it important to compensate for pressure and temperature when an orifice is used to measure gas flow
Explanation:
Orifice meters require to compensate for pressure and temperature when one uses these meters to measure the steam or the gas flow in the pipes with the variable operating pressure as well as temperature conditions.
Normally chemists do not have online density measurement tool and thus to avoid complications, the chemists consider density as constant parameter.
In the steam or the gas flow measurement, density of steam or gas changes as the pressure and the temperature change. This significant change in the density can affect accuracy of measured flow rate if the change is uncompensated and thus, this has to be fixed in order to avoid errors. Therefore, it is important to compensate for the pressure and the temperature when orifice is used to measure the steam or the gas flow.
Ethyl acetate can be prepared by an SN2 reaction. Draw the alkylbromide and nucleophile used in the reaction. Remember to include formal charges (do not include counterions).
Answer:
Few important points related to [tex]S_N2[/tex] reaction:
1. [tex]S_N2[/tex] is a one-step reaction that follows second order kinetics.
2. In [tex]S_N2[/tex] reaction, a transition state is formed in situ.
3. Strong nucleophiles like [tex]OH^- \ or\ CN^-[/tex] are used in case of bi-molecular nucleophilic substitution reaction.
Ethyl acetate can be prepared by a second-order nucleophilic substitution reaction between acetic acid and ethyl bromide.
The reaction between acetic acid and ethyl bromide is drawn below:
In the SN2 reaction to create ethyl acetate, the nucleophile acetate ion attacks the alkyl bromide, leading to the formation of ethyl acetate and bromide ions.
Explanation:Ethyl acetate can be prepared by an SN2 reaction. In this context, an alkylbromide and nucleophile initiate the reaction. Ethyl bromide (CH3CH2Br) would be the alkylbromide used in the reaction. The nucleophile, in this case, would be acetate ion (CH3COO-).
Ethyl bromide is a good leaving group and acetate ion is a strong nucleophile, which comes from acetic acid (ethanoic acid). In SN2 reactions, the nucleophile attacks the substrate, and the leaving group (Br- in this case) leaves, leading to a reverse configuration. In this reaction, the nucleophile (acetate ion) will attack the alkyl bromide, resulting in the formation of ethyl acetate, CH3COOCH2CH3, and bromide ions, which is a good leaving group.
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At 14,000 ft elevation the air pressure drops to 0.59 atm. Assume you take a 1L sample of air at this altitude and compare it to 1 L of air taken at sea level. How much less O2 (in g) is available in 1 L of air at 14,000 ft (assume temperature of 298 K and that relative gas percentages are constant in both locations).
Answer:
There are 0.1125 g of O₂ less in 1 L of air at 14,000 ft than in 1 L of air at sea level.
Explanation:
To solve this problem we use the ideal gas law:
PV=nRT
Where P is pressure (in atm), V is volume (in L), n is the number of moles, T is temperature (in K), and R is a constant (0.082 atm·L·mol⁻¹·K⁻¹)
Now we calculate the number of moles of air in 1 L at sea level (this means with P=1atm):
1 atm * 1 L = n₁ * 0.082 atm·L·mol⁻¹·K⁻¹ * 298 K
n₁=0.04092 moles
Now we calculate n₂, the number of moles of air in L at an 14,000 ft elevation, this means with P = 0.59 atm:
0.59 atm * 1 L = n₂ * 0.082 atm·L·mol⁻¹·K⁻¹ * 298 K
n₂=0.02414 moles
In order to calculate the difference in O₂, we substract n₂ from n₁:
0.04092 mol - 0.02414 mol = 0.01678 mol
Keep in mind that these 0.01678 moles are of air, which means that we have to look up in literature the content of O₂ in air (20.95%), and then use the molecular weight to calculate the grams of O₂ in 20.95% of 0.01678 moles:
[tex]0.01678mol*\frac{20.95}{100} *32\frac{g}{mol} =0.1125 gO_{2}[/tex]
What volume of concentrated (10.2 M) HCl would be required to prepare 1.11 x 104 mL of 1.5 M HC1? Enter your answer in scientific notation. Be sure to answer all parts. x 10 (select) L
Answer:
The required volume is 1.6 x 10³mL.
Explanation:
When we want to prepare a dilute solution from a concentrated one, we can use the dilution rule to find out the required volume to dilute. This rule states:
C₁ . V₁ = C₂ . V₂
where,
C₁ and V₁ are the concentration and volume of the concentrated solution
C₂ and V₂ are the concentration and volume of the dilute solution
In this case, we want to find out V₁:
C₁ . V₁ = C₂ . V₂
[tex]V_{1} = \frac{C_{2}.V_{2}}{C_{1}} = \frac{1.5M \times1.11.10^{4}mL }{10.2M} =1.6\times10^{3} mL[/tex]
We know that one mole of Oxygen gas contains two moles of O atoms (remember that O is a diatomic element in nature and is written O2). If we have a sample of O2 that contains 1.0000 x 10-20 mol, we will have (blank)
atoms of O in the sample.
Answer:
12.4 × 10∧3 atoms
Explanation:
Given data:
moles of oxygen molecule= 1.0000 x 10-20 mol
atoms =?
Solution:
32 g O2 = 1 mol = 6.02 × 10∧23
1.0000 x 10∧-20 mol × 6.02 × 10∧23 × 2 = 12.4 × 10∧3 atoms
Conversion of flow quantities by the continuity equation Water flows through a 3-inch, schedule 40 steel pipe (inside diameter- 3.068 inches) with an average velocity of 4 ft/s. Compute: (a) mass flow rate in lb/h, (b) volumetric flow rate in ft /h, and (c) mass velocity (mass flux) in lb/h-ft.
Answer:
a) m = 2398256.64 Ib/hr
b) Q = 38433.6 ft^3/hr
c) J = = 898560 lb/h-ft2
Explanation:
a) To get the mass flow rate in lb/h we are going to use this formula:
m = ρνA
note: we have to change some units to reach to the final units
when m is the mass flow rate which we need to calculate
ρ is the density of water in lb/ft3 = 62.4 lbs/ft3 it is a constant numbers you can get it from anywhere
ν is the velocity of the water = 4 ft/s we need to change it to ft/h unit so
when 1 ft/s = 3600 ft/hr (note : 3600 is a result of converting hr to sec 60min*60sec)
so the velocity of the water = 4 ft/s * 3600 ft/hr= 14400 ft/hr
now , we need to get the area of the pipe in feet also when:
A = π*diameter * length
diameter = 3.068 inches
when 1 inch = 0.0833333333 feet so,
diameter in feet = 3.068 * 0.0833333333 =.300 0.2557ft
and length = 40 * 0.0833333333 = 3.333 ft
so the area of the pipe in feet^2 = 3.14*0.255*3.33 =2.669 ft^2
by substitution in the mass flow rate:
m = 62.4 lbs/ft3 * 14400 ft/hr *2.669 ft^2 = 2398256.64 Ib/hr
b) now to calculate volumetric flow rate in ft /h we are going to use this formula:
Q = AV
when Q is the volume flow rate
A is the cross-sectional area filled by water =2.669 ft^2
V is the average velocity of the water = 14400 ft/hr
so , by substitution:
Q = 2.669 ft^2* 14400 ft/hr= 38433.6 ft^3/hr
C) To calculate mass velocity (mass flux) in lb/h-ft we are going to use this formula:
J = m / A
when J is the mass flux
and m is the mass flow rate which we calculated above = 2398256.64 Ib/hr
and A is the cross section area of the pipe which we calculated above and = 2.669 ft^2
so, by substitution:
J = 2398256.64 Ib/hr / 2.669 ft^2
= 898560 lb/h-ft2
As the volume of confined gas decreases at the constant temperature, the pressure exerted by the gas________________.
Fluctuates
decreases
Increases
stays the same
As the volume of confined gas decreases at the constant temperature, the pressure exerted by the gas increases . The correct option is C.
What is the Boyle's law?Boyle–Mariotte law is a gas law, shows the relation between pressure and volume. With the increase in the volume, the pressure decreases.
The pressure exerted by the mass, is inversely proportional to the volume of the gas.
Thus, the correct option is C, increases.
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A sample of helium gas has a volume of 1.50 L at 159 K and 5.00 atm. When the gas is compressed to 0.200 L at 50.0 atm, the temperature increases markedly. What is the final temperature? Enter your answer in the provided box. K
Answer:
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Explanation:
The given data is as follows.
[tex]V_{1}[/tex] = 1.50 L, [tex]T_{1}[/tex] = 159 K,
[tex]P_{1}[/tex] = 5.00 atm, [tex]V_{2}[/tex] = 0.2 L,
[tex]T_{2}[/tex] = ?, [tex]P_{2}[/tex] = 50.0 atm
And, according to ideal gas equation,
[tex]\frac{P_{1}V_{1}}{T_{1}} = \frac{P_{2}V_{2}}{T_{2}}[/tex]
Hence, putting the given values into the above formula to calculate the value of final temperature as follows.
[tex]\frac{5.0 atm \times 1.50 L}{159 K} = \frac{5 atm \times 0.2 L}{T_{2}}[/tex]
[tex]T_{2}[/tex] = 21.27 K
Thus, we can conclude that the final temperature is 21.27 K .
What is the chemical formula for Iron(III) hydroxide? Hydroxide is OH O a. Fe(OH)2 O b. FeOH Fe2OH O c. O d. Fe(OH)3 O e. Fe2(OH)3
The correct chemical formula for Iron(III) hydroxide is Fe(OH)3, which is formed by combining one iron ion with a +3 charge (Fe3+) with three hydroxide ions (OH-).
Explanation:The chemical formula for Iron(III) hydroxide is Fe(OH)3. This compound consists of an iron ion with a +3 charge (Fe3+) and three hydroxide ions (OH-). The number in parentheses after iron indicates the oxidation state of iron, which in this case is +3. The formula reflects the stoichiometry required to balance the charges, resulting in one Fe3+ for every three OH- ions to form the neutral compound. Therefore, the correct answer is Fe(OH)3.
The correct answer is d. Fe(OH)₃.