Answer:
the water evaporates into the carbon dioxide
Explanation:
i just know by heart
Please circle the process which does not involve irreversibility: (A) The conversion of mechanical work to heat by friction. (B) Conversion of electrical energy to thermal energy through a resistor heater. (C) Mixing of O2 and N2 for the production of air. (D) The theoretical conversion from electricity to mechanical work.
Answer:
Mixing of O2 and N2 for the production of air.
Explanation:
An irreversible process is defined as any process which cannot return both the system and its surroundings to their original conditions. That is, the system and its surroundings would not return to their original conditions if the process was reversed. Irreversible Processes usually increase the entropy of the universe.
Processes that involve evolution of heat are usually irreversible processes since heat is lost to the surrounding. Hence the answer
Which of the following is the net ionic equation for the reaction that occurs when a few drops of HCl are added to a buffer containing a weak base (B) and its conjugate acid (BH+)? B(aq) + OH−(aq) → BOH−(aq) BH+(aq) + OH−(aq) → H2O(l) + B(aq) H+(aq) + OH−(aq) → H2O(l) H+(aq) + B(aq) → BH+(aq) B(aq) + H2O(l) begin mathsize 12px style rightwards harpoon over leftwards harpoon end style BH+(aq) + OH−(aq)
Answer:
H+(aq) + B(aq) → BH+(aq)
Explanation:
When an acid is added onto a buffer, it is neutralized by the base.
So we pretty much have;
HCl + Weak base
Since HCl completely dissociates in water, it is represented as;
HCl(aq) --> H+(aq) + Cl-(aq)
The weak base reacts with the H+
So our Net ionic reaction is given as;
H+(aq) + B(aq) → BH+(aq)
1. Submit a detailed mechanism for the synthesis of benzopinacolone starting with benzophenone. 2. Draw the structure for the phenonium ion intermediate. 3. What is the literature value of the melting point of benzopinacol
Answer:
The first stage of this reaction involves the 2-propanol reacting with benzophenone which involves the formation of the most stable carbocation, the reaction is then heated under high temperature and pressure to form benzopinacol, on cooling the benzopinacololone crystallizes out
Melting point of benzopinacolol= 184-186°C
Explanation:
Please find attached the detailed step by step mechanism of synthesis of benzopinacololone
: A chemical company is testing a new product that it believes will increase the growth rate of food plants. Suppose you are able to view the slides of onion root tips that have been treated with the product. If the product is successful how might the slides look different from the slides you viewed in this lab?
Answer:
Explanation:
Larger percentage of the cells would be in mitosis, although the differences in percentages within the different stages of mitosis would still look alike, and interphase might likely still maintain the largest percentage, although it might sometimes be 50% and not 88%.
The slides you viewed in this lab are different from the slides, A larger percentage of the meristematic cells would be in mitosis in treated onion tips
The differences in percentages within the different stages of mitosis look the same, and interphase might likely still maintain the largest percentage.
The Increased growth rate in size in the meristematic cells means an increased rapid division of cells by mitosis This time if the chemical causing the increased growth, you will observe mitosis more number of cells under mitosis in comparison to onion tips without such chemicals, the onion root tips that have been treated will show more number of cells in mitosis division.Thus, The slides you viewed in this lab are different from the slides, A larger percentage of the meristematic cells would be in mitosis in treated onion tips
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A flexible container at an initial volume of 6.13 L contains 3.51 mol of gas. More gas is then added to the container until it reaches a final volume of 16.3 L. Assuming the pressure and temperature of the gas remain constant, calculate the number of moles of gas added to the container. number of moles of gas: mol
Answer: The number of moles of gas added to the container are 5.82
Explanation:
Avogadro's law states that volume is directly proportional to number of moles at constant temperature and pressure.
The equation used to calculate number of moles is given by:
[tex]\frac{V_1}{n_1}=\frac{V_2}{n_2}[/tex]
where,
[tex]V_1[/tex] and [tex]n_1[/tex] are the initial volume and number of moles
[tex]V_2[/tex] and [tex]n_2[/tex] are the final volume and number of moles
Putting values in above equation, we get:
[tex]\frac{6.13}{3.51}=\frac{16.3}{n_2}\\\\n_2=9.33[/tex]
number of moles of gas added to the container = (9.33-3.51) = 5.82
Thus the number of moles of gas added to the container are 5.82
A chemist titrates 130.0mL of a 0.4248 M lidocaine (C14H21NONH) solution with 0.4429 M HBr solution at 25 degree C . Calculate the pH at equivalence. The pKb of lidocaine is 7.94 . Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of HBr solution added.
Answer:
pH = 3.36
Explanation:
Lidocaine is a weak base to be titrated with the strong acid HBr, therefore at equivalence point we wil have the protonated lidocaine weak conjugate acid of lidocaine which will drive the pH.
Thus to solve the question we will need to calculate the concentration of this weak acid at equivalence point.
Molarity = mol /V ∴ mol = V x M
mol lidocaine = (130 mL/1000 mL/L) x 0.4248 mol/L = 0.0552 mol
The volume of 0.4429 M HBr required to neutralize this 0.0552 mol is
0.0552 mol x (1L / 0.4429mol) = 0.125 L
Total volume at equivalence is initial volume lidocaine + volume HBr added
0 .130 L +0.125 L = 0.255L
and the concentration of protonated lidocaine at the end of the titration will be
0.0552 mol / 0.255 L = 0.22M
Now to calculate the pH we setup our customary ICE table for weak acids for the equilibria:
protonated lidocaine + H₂O ⇆ lidocaine + H₃O⁺
protonated lidocaine lidocaine H₃O⁺
Initial(M) 0.22 0 0
Change -x +x +x
Equilibrium 0.22 - x x x
We know for this equilibrium
Ka = [Lidocaine] [H₃O⁺] / [protonaded Lidocaine] = x² / ( 0.22 - x )
The Ka can be calculated from the given pKb for lidocaine
Kb = antilog( - 7.94 ) = 1.15 x 10⁻⁸
Ka = Kw / Kb = 10⁻¹⁴ / 1.15 x 10⁻⁸ = 8.71 x 10⁻⁷
Since Ka is very small we can make the approximation 0.22 - x ≈ 0.22
and solve for x. The pH will then be the negative log of this value.
8.71 x 10⁻⁷ = x² / 0.22 ⇒ x = √(/ 8.71 X 10⁻⁷ x 0.22) = 4.38 x 10⁻⁴
( Indeed our approximation checks since 4.38 x 10⁻⁴ is just 0.2 % of 0.22 )
pH = - log ( 4.4x 10⁻⁴) = 3.36
The pH at the equivalence point of a titration of lidocaine with HBr is calculated using the pKb of lidocaine to find its pKa. The pH at equivalence is equal to the pKa of lidocaine, which is 6.06.
Explanation:To calculate the pH at the equivalence point in the titration of lidocaine with HBr, we use the pKb of lidocaine to find its pKa and then apply the Henderson-Hasselbalch equation. Since lidocaine is a weak base, at equivalence point it is completely neutralized by HBr, forming its conjugate acid. At this point, the concentration of the conjugate acid equals the original concentration of the base due to stoichiometry.
The pKa of lidocaine is calculated from its pKb using the formula pKa + pKb = pKw, where pKw is 14.00 at 25°C. Therefore, the pKa of lidocaine is 14.00 - 7.94 = 6.06.
At the equivalence point, the pH is equal to the pKa since the concentration of the conjugate acid (lidocaine) equals the concentration of the conjugate base (HBr). Consequently, the pH at the equivalence point is 6.06.
Suppose the formation of nitrogen dioxide proceeds by the following mechanism
step elementary reaction rate constant
1 2NO(g) → N2O2(g) k1
2 NO2 (g) + O2 (g) → 2NO2 (g) k2
Suppose also k1<
Write the balanced chemical equation for the overall chemical reaction:
Write the experimentally- observable rate law for the overall chemical reaction rate:
Final answer:
The balanced chemical equation for the overall reaction is 2NO(g) + O2(g) → 2NO2(g). The experimentally-observable rate law, assuming the second step is rate-determining, is rate = k[NO]^2[O2], where k is the overall rate constant.
Explanation:
The balanced chemical equation for the overall reaction combining the two steps 2NO(g) → N2O2(g) and NO2(g) + O2(g) → 2NO2(g) is:
2NO(g) + O2(g) → 2NO2(g)
To write the experimentally-observable rate law for the overall reaction, we must identify the rate-determining step. Assuming the second step is the rate-determining step, and given that the first step is a fast equilibrium, the overall rate can be expressed as:
rate = k2[N2O2][O2]
Since [N2O2] is the intermediate formed in the first step and we know that the rate of formation of N2O2 is proportional to the square of [NO] concentration, we can express [N2O2] in terms of [NO]. Substituting into the rate law, we get:
rate = k2k1[NO]2[O2]
Here, k = k1k2 represents the overall rate constant for the reaction. Therefore, the rate law for the overall chemical reaction is:
rate = k[NO]2[O2]
1. Compare and contrast the rate of solution formation between the three physical forms of salt that were placed in the vial and not agitated with the three forms of salt that were placed in the vial and were agitated.
Answer:
Explanation:
The salt that was in pellet form took the longest time before it could be dissolved during all the trials. The salt with fine texture dissolves first during the trials, and the salt with coarse texture took the middle position during all the trials.
Salt with agitation dissolves faster than salts without any agitation.
Suppose you have just added 200.0 ml of a solution containing 0.5000 moles of acetic acid per liter to 100.0 ml of 0.5000 M NaOH. What is the final pH? The Ka of acetic acid is 1.770 × 10-5
Answer:
The final pH is 3.80
Explanation:
Step 1: Data given
Volume of acetic acid = 200.0 mL = 0.200 L
Number of moles acetic acid = 0.5000 moles
Volume of NaOH = 100.0 mL = 0.100 L
Molarity of NaOH = 0.500 M
Ka of acetic acid = 1.770 * 10^-5
Step 2: The balanced equation
CH3COOH + NaOH → CH3COONa + H2O
Step 3: Calculate moles
moles = molarity * volume
Moles NaOH = 0.500 M * 0.100 L
Moles NaOH = 0.0500 moles
Step 4: Calculate the limiting reactant
For 1 mol CH3COOH we need 1 mol NaOH to produce 1 mol CH3COONa and 2 moles H2O
NaOH is the limiting reactant. It will completely be consumed (0.0500 moles). CH3COOH is in excess. There will react 0.0500 moles . There will remain 0.500 - 0.0500 = 0.450 moles
There will be produced 0.0500 moles CH3COONa
Step 5: Calculate the total volume
Total volume = 200.0 mL + 100.0 mL = 300.0 mL
Total volume = 0.300 L
Step 6: Calculate molarity
Molarity = moles / volume
[CH3COOH] = 0.450 moles / 0.300 L
[CH3COOH] = 1.5 M
[CH3COONa] = 0.0500 moles / 0.300 L
[CH3COONa]= 0.167 M
Step 7: Calculate pH
pH = pKa + log[A-]/ [HA]
pH = -log(1.77*10^-5) + log (0.167/ 1.5)
pH = 4.75 + log (0.167/1.5)
pH = 3.80
The final pH is 3.80
To calculate the final pH of the solution, you need to consider the reaction between acetic acid (CH3COOH) and NaOH. The concentration of OH- ions in the final solution determines the pH, which can be calculated using the formula pH = -log10(H+ concentration). Using the given information, we can calculate the concentration of OH- ions, and then convert that to the concentration of H+ ions to find the pH of the solution.
Explanation:To calculate the final pH of the solution, we need to consider the reaction between acetic acid (CH3COOH) and NaOH. The reaction between the two compounds forms sodium acetate (CH3COONa) and water.
The balanced equation for the reaction is:
CH3COOH + NaOH → CH3COONa + H2O
Since NaOH is a strong base, it completely dissociates in water to produce OH- ions. These OH- ions react with the acetic acid to form water. Therefore, the concentration of OH- ions will determine the pH of the final solution.
Using the given information, we can calculate the moles of acetic acid and OH- ions:
Moles of acetic acid = volume of acetic acid solution (L) x concentration of acetic acid (M)
= 0.200 L x 0.5000 M = 0.100 moles
Moles of OH- ions = volume of NaOH solution (L) x concentration of NaOH (M)
= 0.100 L x 0.5000 M = 0.050 moles
Since the mole ratio between acetic acid and OH- ions is 1:1, there will be an equal number of moles of OH- ions and acetic acid in the solution after the reaction is complete.
Therefore, the concentration of OH- ions in the final solution is:
Concentration of OH- ions = Moles of OH- ions / volume of solution (L)
= 0.050 moles / 0.300 L = 0.167 M
To calculate the final pH, we can use the formula: pH = -log10(H+ concentration)
Since in water, OH- ions and H+ ions are inversely proportional, we can calculate the concentration of H+ ions using:
H+ concentration = Kw / OH- concentration
Where Kw is the ion product of water and is equal to 1.0 x 10^-14 at 25°C.
Therefore, H+ concentration = 1.0 x 10^-14 / 0.167 M = 5.99 x 10^-14 M
Finally, calculating the pH:
pH = -log10(5.99 x 10^-14) ≈ 13.22
what substance is produced by the reaction: H+[aq]+OH-[aq]=?
Answer:
It produces water.
Explanation:
H+ + OH- produces H2O.
It is a type of Neutralization reaction.
In cases of ethylene glycol poisoning, treatment involves administration of Ethanol (grain alcohol), which works by competitively inhibiting ADH, an enzyme that oxidizes ethylene glycol to organic acids. As a competitive inhibitor, ethanol: decreases apparent Km without affecting Vmax· increases apparent Vmax without affecting Km. decreases both apparent Vmax and apparent Km. increases apparent Km without affecting Vmax· decreases apparent Vmax without affecting Km.
Answer:
Option B is the correct option- Ethanol increases apparent Km without affecting Vmax.
Explanation:
Vmax remains the same, and Km increases in competitive inhibition. There is an increment in Km because competitive inhibitors interfere with substrate binding to the enzyme. Vmax is not affected because the competitive inhibitor cannot bind to ES and therefore does not alter the catalysis.
Option B is the correct option- Ethanol increases apparent Km without affecting Vmax.
In the attached image, the first picture is the Michaelis Menten Plot for competitive inhibition in which an increase in km but constant Vmax is observed.
In the images, ............................. represents the case with competitive inhibitor, while _______________ represents the case without competitive inhibitor.
Phosphorous acid, H 3 PO 3 ( aq ) , is a diprotic oxyacid that is an important compound in industry and agriculture. p K a1 p K a2 1.30 6.70 Calculate the pH for each of the points in the titration of 50.0 mL of 1.5 M H 3 PO 3 ( aq ) with 1.5 M KOH ( aq ) . A molecule of phosphorous acid. A central phosphorus atom is single bonded to a hydrogen atom and two O H groups. An oxygen atom is also double bonded to the phosphorus atom.
a. before addition of any KOH :
b. after addition of 25.0 mL KOH :
c. after addition of 50.0 mL KOH :
d. after addition of 75.0 mL KOH :
e. after addition of 100.0 mL KOH :
Answer:
a. 0.60
b. 1.30
c. 4.00
d. 6.70
e. 10.20
Explanation:
The 3 attached files shows a comprehensive solution
to the problems with answers highlighted as above
A common recipe is to make 3%(wt/vol) HCl in ethanol. HCl has a formula weight of 36.46 grams per mole. If the stock solution of HCl is 1 moles per 1000 mL, how many mL of HCl need to be added to achieve a final volume of 250 mL of acid alcohol solution? Report your answer to two decimal places.
Answer: 205.70 mL of acid solution is needed
Explanation: Please see the attachments below
Tritium 3 1H decays to 3 2He by beta emission. Find the energy released in the process. Answer in units of keV.
Answer:
The energy released in the decay process = 18.63 keV
Explanation:
To solve this question, we have to calculate the binding energy of each isotope and then take the difference.
The mass of Tritium = 3.016049 amu.
So,the binding energy of Tritium = 3.016049 *931.494 MeV
= 2809.43155 MeV.
The mass of Helium 3 = 3.016029 amu.
So, the binding energy of Helium 3 = 3.016029 * 931.494 MeV
= 2809.41292 MeV.
The difference between the binding energy of Tritium and the binding energy of Helium is: 32809.43155 - 2809.412 = 0.01863 MeV
1 MeV = 1000keV.
Thus, 0.01863 MeV = 0.01863*1000keV = 18.63 keV.
So, the energy released in the decay process = 18.63 keV.
8. Compare the rates of effusion for hydrogen and oxygen gases.
When compared to oxygen gas, hydrogen gas emits approximately 2.82 times faster.
Rate of effusion refers to the speed at which a gas escapes or diffuses through a small opening or porous membrane into a vacuum or another gas. It is a measure of how quickly gas molecules can move and pass through a barrier.
The rate of effusion for a gas is determined by its molar mass. According to Graham's law of effusion, the rate of effusion of a gas is inversely proportional to the square root of its molar mass.
The molar mass of hydrogen is 2.02 g/mol, while the molar mass of oxygen is 32.00 g/mol. Therefore, the molar mass of oxygen is significantly larger than that of hydrogen.
Using Graham's law, we can calculate the ratio of the rates of effusion for hydrogen and oxygen:
Rate of effusion of hydrogen / Rate of effusion of oxygen = √ (Molar mass of oxygen / Molar mass of hydrogen)
Rate of effusion of hydrogen / Rate of effusion of oxygen = √ (32.00 g/mol / 2.02 g/mol)
= 2.82
Therefore, on comparing hydrogen gas effuses approximately 2.82 times faster than oxygen gas.
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Final answer:
Hydrogen gas effuses approximately 4 times faster than oxygen gas according to Graham's law of effusion.
Explanation:
According to Graham's law of effusion, the rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since hydrogen has a smaller molar mass than oxygen, it will effuse at a faster rate.
For example, if we consider the rate of effusion of hydrogen to be 1, then the rate of effusion of oxygen would be √((molar mass of hydrogen)/(molar mass of oxygen)).
Therefore, hydrogen gas effuses at a rate that is approximately 4 times faster than oxygen gas.
Provide a stepwise synthesis of 1-cyclopentylethanamine using the Gabriel synthesis. Collapse question part Testbank, Question 065a Correct answer. Your answer is correct. Using the reagents below, list in order (by letter, no period) those necessary to provide this synthesis. a. Mg(OH)2 b. KOH c. 1-bromo-1-cyclohexylethane d. 1-bromo-1-cyclopentylethane e. NH3 f. xs LiAlH4 g. H3O , then OH- Step 1 Step 2 Step 3 Entry field with correct answer Entry field with correct answer Entry field with correct answer
Answer:
Azide synthesis is the first method on the table of synthesis of primary amines. The Lewis structure of the azide ion, N3−, is as shown below.
an azide ion
An “imide” is a compound in which an N−−H group is attached to two carbonyl groups; that is,
imide linkage
You should note the commonly used trivial names of the following compounds.
phthalic acid, phthalic anhydride, and phthalimide
The phthalimide alkylation mentioned in the reading is also known as the Gabriel synthesis.
If necessary, review the reduction of nitriles (Section 20.7) and the reduction of amides (Section 21.7).
Before you read the section on reductive amination you may wish to remind yourself of the structure of an imine (see Section 19.8).
The Hofmann rearrangement is usually called the Hofmann degradation. In a true rearrangement reaction, no atoms are lost or gained; however, in this particular reaction one atom of carbon and one atom of oxygen are lost from the amide starting material, thus the term “rearrangement” is not really appropriate. There is a rearrangement step in the overall degradation process, however: this is the step in which the alkyl group of the acyl nitrene migrates from carbon to nitrogen to produce an isocyanate.
Explanation:
Transport of aspirin is expected to be faster in the ____. The speed of nonmediated absorption depends strongly on the polarity and charge of molecules. When p H is low (as it is in the _______), the aspirin molecule will be _______ and thus _______, due to _____ of H+ in the solution. The higher pH is, the _______ charged and polar will become the molecule, leading to the ____--- in the speed of absorption. One more evidence to this conclusion is that the pH in the _______ is much lower than pKa of aspirin comparing to the pH of the _______.
The missing words in the blanks are-
Stomach Stomach highly protonated uncharged high concentration more decrease stomach intestine.The transport of aspirin is more in the bloodstream from the stomach as absorption speed depends on the polarity and charge of molecules of the aspirin.
The pH of the stomach is low then molecules of aspirin become highly protonated due to the high concentration of H+ ion they are uncharged.So it is clear that an increase in pH charge and polarity of the molecules also increases which causes less absorption speed of molecules.the pKa of aspirin in the intestine is much more than the pH in the stomach.Thus,
The missing words in the blanks are-
Stomach Stomach highly protonated uncharged high concentration more decrease stomach intestine.Learn more:
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For Na2HPO4:(( (Note that for H3PO4, ka1= 6.9x10-3, ka2 = 6.4x10-8, ka3 = 4.8x10-13 ) a) The active anion is H2PO4- b) The active anion is HPO4 3- c) is basic d) Is acidic
Answer:
Check the explanation
Explanation:
Answer – Given, [tex]H_3PO_4[/tex] acid and there are three Ka values
[tex]K_{a1}=6.9x10^8, K_{a2} = 6.2X10^8, and K_{a3}=4.8X10^{13}[/tex]
The transformation of [tex]H_2PO_4- (aq) to HPO_4^2-(aq)[/tex]is the second dissociation, so we need to use the Ka2 = 6.2x10-8 in the Henderson-Hasselbalch equation.
Mass of KH2PO4 = 22.0 g , mass of Na2HPO4 = 32.0 g , volume = 1.00 L
First we need to calculate moles of each
Moles of KH2PO4 = 22.0 g / 136.08 g.mol-1
= 0.162 moles
Moles of Na2HPO4 = 32.0 g /141.96 g.mol-1
= 0.225 moles
[H2PO4-] = 0.162 moles / 1.00 L = 0.162 M
[HPO42-] = 0.225 moles / 1.00 L = 0.225 M
Now we need to calculate the pKa2
pKa2 = -log Ka
= -log 6.2x10-8
= 7.21
We know Henderson-Hasselbalch equation
pH = pKa + log [conjugate base] / [acid]
pH = 7.21 + log 0.225 / 0.162
= 7.35
The pH of a buffer solution obtained by dissolving 22.0 g of KH2PO4 and 32.0 g of Na2HPO4 in water and then diluting to 1.00 L is 7.35
Write the names of the following ionic compounds: 1) NaOH _____________________________________________________ 2) Co 3 P 2 _____________________________________________________ 3) Pb(CO 3 ) 2 _____________________________________________________ 4) MgF 2 _____________________________________________________ 5) Li 2 SO 3 _____________________________________________________ 6) (NH 4 ) 3 PO 4 _____________________________________________________ 7) FeO _____________________________________________________ 8) CaSO 4 _____________________________________________________ 9) Ag 3 N _____________________________________________________ 10) Na 2 S
Answer:
1. NaOH is sodium hydroxide
2. Co3P2 is cobalt (II) phosphide
3. Pb(CO3)2 is lead(iv) carbonate or lead(iv) trioxocarbonate(iv)
4. MgF2 is magnesium fluoride
5. Li2SO3 is lithium sulphite
6. (NH4)3PO4 is ammonium phosphate.
7. FeO is iron(II) oxide
8. CaSO4 is calsium sulphate
9. Ag3N is called silver nitride
10. Na2S is sodium sulfide
Explanation:
Step 1:
Data obtained from the question. This includes:
NaOH
Co3P2
Pb(CO3)2
MgF2
Li2SO3
(NH4)3PO4
FeO
CaSO4
Ag3N
Na2S
Step 2:
Namig the compound
1. NaOH.
NaOH is a binary ionic compound containing sodium Na and hydroxyl OH. It therefore a binary compound (i.e it contains two elements). Binary compounds end with - ide.
NaOH is called sodium hydroxide
2. Co3P2. In this case we must determine the oxidation state of Co. This is illustrated below:
Co3P2 = 0
3Co + 2P = 0
3Co + (2x-3) = 0
3Co - 6 = 0
Collect like terms
3Co = 6
Divide both side by 3
Co = 6/3
Co = +2
Co3P2 contains cobalt Co and phosphorus P. It is binary compound and the oxidation state of Co is +2 in the compound. Therefore, the name of Co3P2 is cobalt (II) phosphide
3. Pb(CO3)2. In this case, we must determine the oxidation state of Pb. This is illustrated below:
Pb(CO3)2 = 0
Pb + 2 [ 4 + (-2x3)] = 0
Pb + 2[ 4 - 6] = 0
Pb + 2[-2] = 0
Pb - 4 = 0
Pb = +4
The name of the compound is lead(iv) carbonate or lead(iv) trioxocarbonate (iv)
4. MgF2 is a binary compound containing magnesium Mg and fluorine F. The name therefore is magnesium fluoride
Note: oxidation number of the group 1, 2 and 3 metals are not indicated in their names since their oxidation number is constant.
5. Li2SO3 is a binary ionic compound containing lithium and sulphite. Therefore, the name is lithium sulphite
6. (NH4)3PO4 contain ammonium NH4 and the phosphate. Therefore the name is ammonium phosphate
7. FeO. This is a binary compound, but we must determine the oxidation state of Fe. This is illustrated below:
FeO = 0
Fe + (-2) = 0
Fe - 2 = 0
Fe = +2
Therefore, the name of FeO is iron(II) oxide
8. CaSO4 is binary ionic compound containing calsium and sulphate. It is name as calsium sulphate
9. Ag3N is a binary compound containing silver and nitrogen. It is therefore called silver nitride
10. Na2S is a binary compound containing sodium and sulphur. It is named as sodium sulfide
The names of the ionic compounds are Sodium hydroxide (NaOH), Cobalt (III) phosphide (Co3P2), Lead (II) carbonate (Pb (CO3)2), Magnesium fluoride (MgF2), Lithium sulfite (Li2SO3), Ammonium phosphate ((NH4)3PO4), Iron (II) oxide (FeO), Calcium sulfate (CaSO4), Silver nitride (Ag3N), Sodium sulfide (Na2S)
Explanation:The names of the given ionic compounds are:
Sodium hydroxide (NaOH)Cobalt(III) phosphide (Co3P2)Lead(II) carbonate (Pb(CO3)2)Magnesium fluoride (MgF2)Lithium sulfite (Li2SO3)Ammonium phosphate ((NH4)3PO4)Iron(II) oxide (FeO)Calcium sulfate (CaSO4)Silver nitride (Ag3N)Sodium sulfide (Na2S)Learn more about Naming ionic compounds here:https://brainly.com/question/32037662
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Elemental mercury is a silver liquid at room temperature. Its normal freezing point is –38.9 °C, and its molar enthalpy of fusion is ∆Hfusion = 2.29 kJ/mol. What is the entropy change of the system (in J/K) when 5.590 g of Hg(l) freezes at the normal freezing point?
Answer:
[tex]\Delta _fS=0.2724\frac{J}{K}[/tex]
Explanation:
Hello,
In this case, we define the entropy change for such freezing process as:
[tex]\Delta _fS=\frac{n_{Hg}\Delta _fH}{T_f}[/tex]
Thus, we compute the moles that are in 5.590 g of liquid mercury:
[tex]n_{Hg}=5.590 gHg*\frac{1molHg}{200.59gHg} =0.02787molHg[/tex]
Hence, we compute the required entropy change, considering the temperature to be in kelvins:
[tex]\Delta _fS=\frac{0.02787mol*2.29\frac{kJ}{mol} }{(-38.9+273.15)K}\\\\\Delta _fS=2.724x10^{-4}\frac{kJ}{K} *\frac{1000J}{kJ} \\\\\Delta _fS=0.2724\frac{J}{K}[/tex]
Best regards.
Answer:
ΔS = -0.272 J/K
Explanation:
Step 1: Data given
Its normal freezing point is –38.9 °C
molar enthalpy of fusion is ∆Hfusion = 2.29 kJ/mol
Mass of Hg = 5.590 grams
Step 2:
ΔG = ΔH - TΔS
At the normal freezing point, or any phase change in general,
ΔG =0
0 = Δ
Hfus
−
Tfus Δ
S
fus
Δ
S
fus = Δ
Hfus
/Tfus
Δ
S
fus = 2290 J/mol / 234.25 K
Δ
S
fus = 9.776 J/mol*K
Since fusion is from solid to liquid. Freezing is the opposite process, so the entropy change of freezing is -9.776 J/mol*K
Step 3: Calculate moles Hg
Moles Hg = 5.590 grams / 200.59 g/mol
Moles Hg = 0.02787 moles
Step 4: Calculate the entropy change of the system:
Δ
S = -9.776 J/mol*K * 0.02787 moles
ΔS = -0.272 J/K
Bromobenzene is converted to a compound with the molecular formula C7H7Br in the reaction scheme below. Draw the structures of the product and the two intermediates, and identify the reagents in each of the three steps.
Complete Question:
The first file attached contains the complete question
Answer:
The reagents play a vital role in a reaction to undergo a transformation. Each reagent plays a different role in the chemical reaction.
Grignard reagent: Grignard reagent R - Mg - X . R represents an alkyl group or aryl group. X represents halides (I,Br,Cl) . The main purpose of a Grignard reagent is the formation of new C−C bond. Grignard reagent undergoes reaction with carbonyl groups (like ketone ( {\rm{ - C = O}}−C=O ), Aldehyde ( - C( = O)H}}−C(=O)H ), Ester ( - C( = O)OR}}−C(=O)OR )) to form an addition product.
Nucleophilic addition: the addition of nucleophile (electron rich) with electrophiles (electron deficient). In this reaction, the double bond is converted to a single bond.
Nucleophilic substitution: In this, the Nucleophile (electron rich) forms a bond with an electrophile (electron deficient) and replaces the leaving group.
The attached file contained detailed solution
The temperature –60 °C is higher than –60 °F.
Answer:
false
Explanation:
it is MUCH lower in temperature
Temperature comparison on the Celsius and Fahrenheit scales are being compared, with a focus on -60 °C and -60 °F. -60 °C is colder than -60 °F because the Celsius scale has a smaller degree interval.
The question is about comparing temperatures in different units, specifically Celsius and Fahrenheit. In physics, temperature is measured using a scale known as the Celsius scale.
The Celsius scale is based on the freezing and boiling points of water, with 0 °C being the freezing point and 100 °C being the boiling point at standard atmospheric pressure. On the other hand, the Fahrenheit scale is another temperature scale commonly used in countries like the United States.
The freezing point of water on the Fahrenheit scale is 32 °F, while the boiling point is 212 °F at standard atmospheric pressure.
To answer the question, let's compare -60 °C and -60 °F. Since the Fahrenheit scale has a larger degree interval between freezing and boiling points, it means that each degree on the Fahrenheit scale is smaller than each degree on the Celsius scale.
So, -60 °C is actually colder than -60 °F. This is because -60 °C is closer to the freezing point of water (0 °C) than -60 °F is to the freezing point of water (32 °F).
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The probable question may be:
The temperature –60 °C is higher than –60 °F. Explain.
Which of the following statements is true? Only the first principle energy level can have s orbitals. Every principle energy level can have only one s orbital. Every principle energy level can have one s orbital, 3 p orbitals, 5 d orbitals, and 7 f orbitals. The fourth principle energy level is the first energy level that has d orbitals. Every principle energy level can have an s orbital and 3 p orbitals.
Answer:
Every principle energy level can have only one s orbital.
Explanation:
For many-electron atoms we use the Pauli exclusion principle to determine electron configurations. This principle states that no two electrons in an atom can have the same set of four quantum numbers. If two electrons in an atom should have the same Principal, Angular Momentum and Magnetic quantum numbers' values (that is, these two electrons are in the same atomic orbital), then they must have different values of Electron Spin Quantum Number. In other words, only two electrons may occupy the same atomic orbital, and these electrons must have opposite spins.
Answer:
B
Explanation:
Every principle energy level can have only one s orbital.
Aufbau principle works in the following formula:
1s2, 2s2 2p6, 3s2 3p6, 4s2 3d10 4p6, and so on.
In the absence of sodium methoxide, the same alkyl bromide gives a different product. Draw an arrowpushing mechanism to account for its formation. 6. (a) In the reaction in part 5(a), two additional products, which contain only carbon and hydrogen, are also formed. Draw their structures and propose mechanisms for their formation. Predict which of these two products would be formed in greater quantities. (b) In the reaction in part 5(b), two additional products, which contain only carbon
Answer:
See explanation below
Explanation:
The question is incomplete, cause you are not providing the structure. However, I found the question and it's attached in picture 1.
Now, according to this reaction and the product given, we can see that we have sustitution reaction. In the absence of sodium methoxide, the reaction it's no longer in basic medium, so the sustitution reaction that it's promoted here it's not an Sn2 reaction as part a), but instead a Sn1 reaction, and in this we can have the presence of carbocation. What happen here then?, well, the bromine leaves the molecule leaving a secondary carbocation there, but the neighbour carbon (The one in the cycle) has a more stable carbocation, so one atom of hydrogen from that carbon migrates to the carbon with the carbocation to stabilize that carbon, and the result is a tertiary carbocation. When this happens, the methanol can easily go there and form the product.
For question 6a, as it was stated before, the mechanism in that reaction is a Sn2, however, we can have conditions for an E2 reaction and form an alkene. This can be done, cause the extoxide can substract the atoms of hydrogens from either the carbon of the cycle or the terminal methyl of the molecule and will form two different products of elimination. The product formed in greater quantities will be the one where the negative charge is more stable, in this case, in the primary carbon of the methyl it's more stable there, so product 1 will be formed more (See picture 2)
For question 6b, same principle of 6a, when the hydrogen migrates to the 2nd carbocation to form a tertiary carbocation the methanol will promove an E1 reaction with the vecinal carbons and form two eliminations products. See picture 2 for mechanism of reaction.
To prepare a buffer you weigh out 7.20 grams of NaHCO3 and place it into a 400.00 mL volumetric flask. To this flask you add 56.0 mL of 5.60 M H2CO3 and then fill it about halfway with distilled water, swirling to dissolve the contents. Finally, the flask is filled the rest of the way to the mark with distilled water.What is the pH of the buffer that you have created?Acid KaH2CO3 4.3 X 10⁻⁷ HCN 4.9 X 10⁻¹⁰HNO2 4.6 X 10⁻⁴C6H5COOH 6.5 X 10⁻⁵
Answer:
pH = 5.80
Explanation:
The buffer solution is:
H₂CO₃(aq) + H₂O(l) ⇄ HCO₃⁻Na⁺(aq) + H₃O⁺(aq)
To find the pH of the buffer solution we will use the Henderson-Hasselbalch equation:
[tex]pH = pKa + log(\frac{[NaHCO_{3}]}{[H_{2}CO_{3}]})[/tex] (1)
First, we need to find the concentration of the buffer solution. For the NaHCO₃ we have:
[tex][NaHCO_{3}] = \frac{mol}{V} = \frac{m}{M*V}[/tex]
Where:
m: is the mass of the NaHCO₃ = 7.20 g
M: is the molar mass of the NaHCO₃ = 84.007 g/mol
V: is the volume of the solution = 400.0 mL
Hence, the concentration of NaHCO₃ is:
[tex][NaHCO_{3}] = \frac{7.20 g}{84.007 g/mol*400.0 \cdot 10^{-3} L} = 0.214 M[/tex]
Now, the concentration of H₂CO₃ is:
[tex] V_{i}C_{i} = V_{f}C_{f} [/tex]
Where:
Vi: is the initial volume of H₂CO₃ = 56.0 mL
Ci: is the initial concentration of H₂CO₃ = 5.60 M
Vf: is the final volume of H₂CO₃ = 400.0 mL
Cf: is the final concentration of H₂CO₃ (to find)
[tex] C_{f} = \frac{V_{i}C_{i}}{V_{f}} = \frac{56.0 mL*5.60 M}{400.0 mL} = 0.784 M [/tex]
Finally, we can use the equation (1) to find the pH of the buffer solution:
[tex] pH = -log(4.3 \cdot 10^{-7}) + log(\frac{0.214 M}{0.784 M}) = 5.80 [/tex]
I hope it helps you!
This reaction between an enamine and an alkyl halide involves the following steps: 1. The enamine acts as a nucleophile in an SN2 reaction, displacing bromide ion to form addition product 1; 2. Deprotonation yields carbanion 2; 3. Ring closure leads to the final product. Write the mechanism out on a sheet of paper, and then draw the structure of carbanion 2.
Answer:
See explanation
Explanation:
Enamines are nucleophiles, and will react with alkyl halides to give alkylation products. Subsequent treatment with aqueous acid will give ketones.
The mechanism of an enamine reaction is shown in the image attached.
The structure of the carbanion is also shown in the image attached.
In contracting skeletal muscle, a sudden elevation of cytosolic Ca2 concentration will result in: Inactivation of phosphorylase kinase caused by the action of protein phosphatase. Activation of cAMP-dependent protein kinase. Dissociation of cAMP-dependent protein kinase into catalytic and regulatory subunits. Conversion of cAMP to AMP by phosphodiesterase. Activation of phosphorylase kinase.
Final answer:
The sudden rise in cytosolic Ca²+ concentration in skeletal muscle leads to activation of phosphorylase kinase, not inactivation. This process is essential for muscle contraction, where Ca²+ plays a critical role by binding to proteins to expose actin for myosin attachment.
Explanation:
In response to a sudden elevation of cytosolic Ca²+ concentration in a contracting skeletal muscle, the activation of phosphorylase kinase occurs. This elevation is primarily due to excitation-contraction coupling, where an action potential triggers the release of Ca²+ from the sarcoplasmic reticulum into the cytosol. Immediately following this, calcium ions interact with troponin, altering its configuration and moving tropomyosin off the actin-binding sites. This allows the myosin head to bind to actin, resulting in muscle contraction.
Separately, in the context of ß-adrenergic receptor activation by adrenaline, an increase in cyclic AMP (cAMP) inside the muscle cell activates PKA (protein kinase A), leading to the phosphorylation of enzymes involved in glycogen degradation and inhibition of glycogen synthesis. Specifically, cAMP-dependent protein kinase is activated, causing a ready pool of glucose to be available for muscular activity.
Therefore, the correct answer is that a sudden increase in Ca²+ results in the activation of phosphorylase kinase, which is critical for initiating muscle contraction and metabolic responses.
The quantity of heat required to change the temperature of 1 g of a substance by 1°C is defined as ____.
a joule
a calorie
density
specific heat
Answer:
specific heat
Explanation:
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What volume of oxygen at 423.0 K and a pressure of 127.4 kPa is produced by the decomposition of 129.7 g of BaO2 to BaO and O2?
The volume of oxygen produced by the decomposition of 129.7 g of BaO2 at 423.0 K and a pressure of 127.4 kPa is 10.37 L.
Explanation:The decomposition of BaO2 (Barium peroxide) to BaO (Barium oxide) and O2 (Oxygen) is represented by the balanced chemical reaction: 2BaO2(s) → 2BaO(s) + O2(g). Using the molar mass of BaO2 (169.33 g/mol), we can calculate the number of moles of BaO2 in 129.7 g which is 0.766 moles. From the reaction stoichiometry, we can see that 2 moles of BaO2 produces 1 mole of O2. Therefore, 0.766 moles of BaO2 produces 0.766/2 = 0.383 moles of O2. Using the ideal gas law, PV=nRT, we can solve for volume (V) using n=0.383 moles, R=8.314 kPa L/mol K (universal gas constant) and T=423 K (Temperature), and P=127.4 kPa (Pressure) which gives us, V = (nRT)/P , V = (0.383 moles * 8.314 kPa L/mol K * 423 K) / 127.4 kPa = 10.37 L. Thus, the volume of oxygen produced by the decomposition of 129.7 g of BaO2 at 423.0 K and a pressure of 127.4 kPa is 10.37 L.
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The volume of oxygen produced by the decomposition of 129.7 g of BaO2 under the given conditions is approximately 13.2 liters.
Explanation:The decomposition of barium peroxide (BaO2) to barium oxide (BaO) and oxygen (O2) is a reaction that can be described by the equation:
2 BaO2(s) → 2 BaO(s) + O2(g)
From the molar mass of BaO2, which is 169.34 g/mol, we can calculate the number of moles of BaO2 that the 129.7 g represents:
moles of BaO2 = 129.7 g / 169.34 g/mol ≈ 0.766 moles
According to the balanced equation, 2 moles of BaO2 produce 1 mole of O2, hence:
moles of O2 produced = 0.766 moles BaO2 / 2 ≈ 0.383 moles
Using the ideal gas law equation PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant (0.0821 L·atm/K·mol), and T is the temperature:
We first convert the pressure from kPa to atm: 127.4 kPa = 1.258 atm (using the conversion 101.3 kPa = 1 atm).
Then, we solve for V using the ideal gas law equation:
V = nRT / P = (0.383 moles) × (0.0821 L·atm/K·mol) × (423.0 K) / 1.258 atm ≈ 13.2 L
Therefore, the volume of oxygen produced under the given conditions is approximately 13.2 liters.
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we make 200 mL of a solution with a 0.025 M concentration of Ca(OH)2 The solution is then diluted to 1.00 L by adding additional water what is the pH of the solution after dilution?
Answer:
12.00
Explanation:
Final answer:
To find the pH of the diluted Ca(OH)₂ solution, calculate the new concentration after dilution, determine the [OH-], find pOH, and then subtract from 14 to get pH. The final pH of the solution after dilution to 1 L will be 12.
Explanation:
The question is about calculating the pH of a diluted solution of Ca(OH)₂ after it has been diluted to 1.00 L. We begin by finding the new concentration of Ca(OH)₂ after dilution, which would be:
Determine the initial number of moles of Ca(OH)₂ : moles = 200 mL times 0.025 M = 0.005 moles.
Calculate the new concentration after dilution: concentration = 0.005 moles / 1.00 L = 0.005 M.
As Ca(OH)₂ dissociates to give 2 OH - per molecule, the [OH-] = 2 times 0.005 M = 0.01 M.
Calculate the pOH: pOH = -log(0.01) = 2.
Finally, calculate the pH: pH = 14 - pOH = 14 - 2 = 12.
The pH of the solution after dilution to 1 L will be 12.