Answer: The concentration of cow's milk after 5 years is 10691 Bq/L
Explanation:
All the radioactive reactions follow first order kinetics.
The equation used to calculate rate constant from given half life for first order kinetics:
[tex]t_{1/2}=\frac{0.693}{k}[/tex]
We are given:
[tex]t_{1/2}=30yrs[/tex]
Putting values in above equation, we get:
[tex]k=\frac{0.693}{30}=0.0231yr^{-1}[/tex]
The equation used to calculate time period follows:
[tex]N=N_o\times e^{-k\times t}[/tex]
where,
[tex]N_o[/tex] = initial concentration of Cow's milk = 12000 Bq/L
N = Concentration of cow's milk after 5 years = ?
t = time = 5 years
k = rate constant = [tex]0.0231yr^{-1}[/tex]
Putting values in above equation, we get:
[tex]N=12000Bq/L\times e^{-(0.0231yr^{-1}\times 5yr)}\\\\N_o=10691Bq/L[/tex]
Hence, the concentration of cow's milk after 5 years is 10691 Bq/L
Which of the following is an example of a qualitative measurement? A) blue crystal B) 2 moles of carbon atoms C) 10 g of salt D) 12 dl. of water
Answer:
A) blue crystal
Explanation:
Qualitative measurements measure the quality of something as opposed to quantity. The other options are quantitative as they contain numbers.
Determine the molality of a solution of benzene dissolved in toluene (methylbenzene) for which the mole fraction of benzene is 0.176. Give your answer to 2 decimal places
Answer:
2.32 m
Explanation:
So, according to definition of mole fraction:
[tex]Mole\ fraction\ of\ benzene=\frac {n_{benzene}}{n_{benzene}+n_{toluene}}[/tex]
Mole fraction = 0.176
Applying values as:
[tex]0.176=\frac {n_{benzene}}{n_{benzene}+n_{toluene}}[/tex]
[tex]0.176\times ({n_{benzene}+n_{toluene}})={n_{benzene}}[/tex]
So,
[tex]0.176\times n_{toluene}}=0.824\times {n_{benzene}}[/tex]
[tex]{n_{benzene}}=\frac {0.176}{0.824}\times n_{toluene}}[/tex]
[tex]{n_{benzene}}=0.2136\times n_{toluene}}[/tex]
Also, Molar mass of toluene = 92.14 g/mol
Thus,
The formula for the calculation of moles is shown below:
[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]
[tex]Mass=92.14\times n_{toluene}}\ g[/tex]
Also, 1 g = 0.001 kg
So,
[tex]Mass\ of\ toluene=0.09214\times n_{toluene}}\ kg[/tex]
Molality is defined as the moles of the solute present in 1 kg of the solvent.
It is represented by 'm'.
Thus,
[tex]Molality\ (m)=\frac {0.2136\times n_{toluene}}{0.09214\times n_{toluene}}[/tex]
Molality of benzene = 2.32 m
Final answer:
The molality of the solution of benzene dissolved in toluene is 0.00543 mol/kg.
Explanation:
The molality of a solution can be calculated using the mole fraction and the molar mass of benzene and toluene. The mole fraction of benzene can be calculated by dividing the moles of benzene by the total moles of benzene and toluene. The moles of benzene can be determined using the given volumes of benzene and toluene and their respective densities. The molar mass of benzene is 78.11 g/mol. By substituting the values into the formula, we can calculate the molality of the solution to be 0.176 * 78.11 g/mol / (1000 g + 0.867 g/mL * 100 mL + 0.874 g/mL * 300 mL) = 0.00543 mol/kg.
How many protons and neutrons are in 119_Sn? O a. 50 n and 119 p O b. 50 p and 169 1 O c. 50 p and 69 O d. 50 n and 169 p O e. None of the above.
Answer: The given isotope of tin has 50 protons and 69 neutrons.
Explanation:
Atomic number is defined as the number of protons or number of electrons that are present in neutral atom. It is represented as Z.
Atomic number = Number of protons = Number of electrons
Mass number is defined as the sum of number of protons and number of neutrons. It is represented as A.
Mass number = Number of protons + Number of neutrons
We are given:
An isotope having representation [tex]_{50}^{119}\textrm{Sn}[/tex]
Mass number of Sn = 19
Atomic number = 50
Number of neutrons = Mass number - Atomic number = 119 - 50 = 69
Hence, the given isotope of tin has 50 protons and 69 neutrons.
What is the volumetric flow rate in L/s of a stream of air (density = 1 kg/m3) at 1 kg/s?
Answer:
Volumetric flow rate: Q = 1000 L/s
Explanation:
Volumetric flow rate, also called the rate of fluid flow, is described as volume of fluid that passes a particular point per unit time. The SI unit of volumetric flow rate is m³/s.
Whereas, mass flow rate is defined as the mass of substance that passes through a point per unit of time. SI unit is kg/s.
Given- mass flow rate: ṁ = 1 kg/s and density: ρ = 1 kg/m³
Therefore, volumetric flow rate can be calculated by
[tex]Q = \frac{\dot{m}}{\rho } = \frac{1 kg/s}{1 kg/m^{3}} = 1 m^{3}/s[/tex]
Since, 1 m³/s = 1000 L/s
Therefore, volumetric flow rate: Q = 1 m³/s = 1000 L/s
The following procedure was carried out to determine thevolume
of a flask. The flask was weighed dry and then filled withwater. If
the masses of the empty flask and filled flask were 56.12g and
87.39 g, respectively, and the density of water is 0.9976g/mL,
Calculate the volume of the flask in mL.
Answer: Volume of the flask is 31.34 mL.
Explanation:
Weight of empty flask [tex]w_1[/tex] = 56.12 grams
Weight of flask with water [tex]w_2[/tex] = 87.39 grams
Weight of water [tex]w_3[/tex] = [tex]w_2-w_1[/tex] = (87.39 - 56.12) grams= 31.27 grams
Density of water = 0.9976 g/mL
0.9976 grams are contained in = 1 ml of water
Thus 31.27 grams are contained in = [tex]\frac{1}{0.9976}\times 31.27=31.34[/tex] ml of water.
Thus the volume of the flask is 31.34 mL.
The volume of the flask is calculated by subtracting the mass of the empty flask from the mass of the filled flask and then dividing by the density of water. The resulting volume is approximately 31.36 mL.
To calculate the volume of the flask in mL, we need to use the mass of the water that filled the flask and the known density of water. First, we find the mass of the water by subtracting the mass of the empty flask from the mass of the filled flask. Then, we use the density formula, which is Density = Mass/Volume, to find the volume of the flask.
Here's the step-by-step calculation:
Determine the mass of the water by subtracting the mass of the empty flask from the filled flask: 87.39 g - 56.12 g = 31.27 g.
Using the known density of water (0.9976 g/mL), calculate the volume using the formula Volume = Mass/Density.
Volume of water (Volume of flask) = 31.27 g / 0.9976 g/mL = 31.36 mL.
Therefore, the volume of the flask is approximately 31.36 mL.
39.20 mL of 0.5000 M AgNO3 is added to 270.00 mL
ofwater which contains 5.832 g K2CrO4. A
redprecipitate of Ag2CrO4 forms. What is
theconcentration, in mol/L, of
unprecipitatedCrO42-? Be sure to enter
the correct numberof significant figures. Assume
Ag2CrO4is completely insoluble.
Answer:
concentration of CrO4²⁻ ions in the final solution = 6.53 × 10⁻⁵ mol /L
Explanation:
First we calculate the number of moles of AgNO₃:
number of moles = molar concentration × volume
number of moles = 0.5 × 39.20 = 19.6 mmoles = 0,0196 moles AgNO₃
Then we calculate the number of moles of K₂CrO₄:
number of moles = mass / molar weight
number of moles = 5.832 / 194 = 0.03 moles K₂CrO₄
The chemical reaction will look like this:
2 AgNO₃ + K₂CrO₄ → Ag₂CrO₄ + 2 KNO₃
Now we devise the following reasoning:
if 2 moles of AgNO₃ are reacting with 1 mole of K₂CrO₄
then 0,0196 moles of AgNO₃ are reacting with X moles of K₂CrO₄
X = (0.0196 × 1) / 2 = 0.0098 moles of K₂CrO₄
now the the we calculate the amount of unreacted K₂CrO₄:
unreacted K₂CrO₄ = 0.03 - 0.0098 = 0.0202 moles
now the molar concentration of CrO4²⁻ ions:
molar concentration = number of moles / solution volume (L)
molar concentration = 0.0202 / (39.20 + 270) = 6.53 × 10⁻⁵ mol /L
the density of a metal is 10.5 g/cm3. If the mass of themetal
is 5.25 g and it is placed in 11.2 ml of water, how much willthe
water rise?
Answer:
11.7 mL
Explanation:
Density of a substance is given by the mass of the substance divided by the volume of the substance .
Hence , d = m / V
V = volume
m = mass ,
d = density ,
From the question ,
The density of the metal = 10.5 g/cm³
The mass of the metal = 5.25 g
Hence , the volume can be calculated from the above formula , i.e. ,
d = m / V
V = m / d
V = 5.25 g / 10.5 g/cm³
V = 0.5 cm³
Since , The unit 1 mL = 1 cm³
V = 0.5 mL
The vessel has 11.2 mL of water ,
The new volume becomes ,
11.2 mL + 0.5 mL = 11.7 mL
Write 0.03445750 in Scientific Notation with 4 significant figures.
Answer:
[tex]3.446\times 10^{-2}[/tex]
Explanation:
Scientific notation is the way of writing numbers which are either large or small. The number is written in the scientific notation when the number is between 1 and 10 and then multiplied by the power of 10.
The given number:
0.03445750 can be written as [tex]3.445750\times 10^{-2}[/tex]
Answer upto 4 significant digits = [tex]3.446\times 10^{-2}[/tex]
Choose the pure substance from the list below. osea water sugar air lemonade milk Question 2 (1 point) Saved A chemical change O occurs when methane gas is burned. occurs when paper is shredded. occurs when water is vaporized. occurs when salt is dissolved in water. occurs when powdered lemonade is stirred into water.
Sugar is the pure substance in the list. A chemical change occurs when methane gas is burned, as the chemical composition of methane is altered.
Explanation:In the list provided, the pure substance is sugar. Pure substances are materials that are composed of only one type of particle, and sugar, which is made up of sucrose, meets this criterion. In contrast, substances like sea water, air, lemonade, and milk are mixtures, as they contain more than one kind of particle.
As for the second question, a chemical change happens when the composition of a substance is altered by a chemical reaction. In this scenario, the correct option is 'occurs when methane gas is burned'. Methane's combustion is a chemical reaction that produces water and carbon dioxide, which are chemically distinct from the original methane. Other options like shredding paper, vaporizing water, dissolving salt in water, or stirring powdered lemonade into water are all physical changes, as they don't alter the chemical composition of the substances involved.
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Sugar is considered a pure substance because it maintains the same composition and properties. A chemical change occurs when methane gas is burned, resulting in different substances.
Explanation:From the given list, the pure substance is sugar. A pure substance has a constant composition. All specimens of a pure substance have exactly the same makeup and properties. An example of a pure substance is table sugar, or sucrose, which consists of 42.1% carbon, 6.5% hydrogen, and 51.4% oxygen by mass. It maintains the same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
Switching to the second question, the occurrence of a chemical change is evident when methane gas is burned. A chemical change always produces one or more types of matter that differ from the matter present before the change. An instance of this is the combustion or burning of methane which results in carbon dioxide and water. These yielded substances significantly differ from the original methane, hence signifying a chemical change.
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How many liters of 0.1107 M KCI contain 15.00 g of KCI (FW 74.6 g/mol)? O0.02227 L O 0.5502 L 01661 L O 1.816 L 18.16 L
Answer:
1,816 L
Explanation:
Molar concentration or molarity is a way to express the concentration of a chemical in terms of moles of substances per liter of solution.
To obtain the liters of this solution you must convert moles/L to g/L with formula weight (FW), thus:
0,1107 mol of KCl / L × (74,6 g / mol) = 8,258 g of KCl / L.
It means that in one liter you have 8,258 g of KCl. Thus, 15,00 g of KCl are contained in:
15,00 g × (1 L / 8,258 g) = 1,816 L
I hope it helps!
Which of the following reagents and biomolecules are necessary to make a recombinant DNA? a. Restriction enzyme b. DNA fragment to be cloned C. Glucose d. DNA ligase e. Chymotrypsin f. Calcium chloride g. starch h. Ampicillin
Answer:
All of them can be necessary.
Explanation:
In typical DNA cloning, the gene of interest is inserted into a plasmid, this is achieved by using enzymes that "cut and paste" DNA producing a recombinant DNA, considering this we will first need a DNA fragment to be cloned. To "cut and paste" these fragments of DNA we will need restriction enzymes (to cut) and DNA ligase (to paste), this enzyme will recognize the specific target sequence and I'll cut it, another restriction enzyme will also cut the plasmid, then DNA ligase will link the plasmid and target gene together. Now we need to introduce the plasmid into bacteria, to extract it we use glucose as a buffer to maintain the pH-controlled for the plasmid to be stable, so that linear dsDNA (sheared chromosomal DNA) is denatured but closed-circular DNA (plasmid) is not. Once we have our plasmid isolated we can put it into our bacteria (this is called transformation), this is achieved by giving the bacteria a shock that encourages them to take foreign DNA, calcium chloride can improve the results by binding plasmids to lipopolysaccharides in the bacteria. After this shock, some bacteria will accept the plasmid but a portion won't, this is why plasmids typically contain antibiotic resistance genes to allow the bacteria that contain the plasmids to survive after the application of such antibiotic, this means ampicillin is also necessary to isolate our bacteria with recombinant DNA. Finally, you can use these bacteria as "factories" to produce proteins and then obtain them by splitting the bacteria, to achieve this splitting we can use proteases, for example, chymotrypsin. NOw you'll need to purify the proteins you extract one method to do it is using the starch binding domain (SBD) that can be found in some amylolytic enzymes, we can add a recombinant proteins for transferring the starch binding capacity to the target proteins, we will observe both proteins fused to the SBDtag, only the target protein will remain over the starch granules after the wash process.
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Why doesn’t molecular hydrogen produce an FTIR spectrum? Explain.
Explanation:
FTIR spectroscopy is method which is used to determine structures of the molecules with characteristic absorption of the infrared radiation by the molecule.
When the molecules is exposed to the infrared radiation, the sample molecules absorb the radiation of wavelengths (specific to molecule) which causes change of the dipole moment of the sample molecules. The vibrational energy levels of the sample molecules consequently transfer from the ground state to the excited state.
Frequency of absorption peak is determined by vibrational energy gap.
Intensity of absorption peaks is related to change of dipole moment and possibility of transition of the energy levels.
Thus, by analyzing infrared spectrum,abundant structure information of the molecule can be known.
Most of the molecules/ compounds are infrared active but for homo-nuclear molecules which are diatomic like [tex]H_2[/tex], [tex]N_2[/tex], [tex]Cl_2[/tex], [tex]O_2[/tex] are inactive due to zero dipole change in vibration and the rotation of such molecules.
Final answer:
Molecular hydrogen does not produce an FTIR spectrum because as a homonuclear diatomic molecule, it does not have a change in dipole moment during vibration, which is a requirement for IR activity.
Explanation:
Molecular hydrogen does not produce a Fourier Transform Infrared (FTIR) spectrum because it is a homonuclear diatomic molecule, meaning it consists of two identical atoms. These molecules lack a permanent electric dipole moment, which is necessary for interaction with infrared light in FTIR spectroscopy. Infrared radiation can be absorbed by a molecule if the radiation causes a change in the dipole moment of the molecule, leading to vibrations within the molecule. Since molecular hydrogen's atoms are identical, they share electrons equally and there is no net dipole moment to be altered by the infrared radiation.
The fundamental requirement for a molecule to be IR active is a change in the molecular dipole moment as it vibrates. Homonuclear diatomic molecules like [tex]H_{2}[/tex] do not exhibit this change in dipole moment because the atoms involved are of the same electronegativity and thus share electrons equally, ensuing no dipole moment is generated during vibration. This is why molecular hydrogen doesn't show up on an FTIR spectrum.
The mean for a set of measurements is 4.17 and the standard deviation is 0.14. To show 95% confidence limits, we can write the result of the measurements as 4.17+ -
Answer:
The 95% confidence level is
[tex]4.17 \pm 0.2744[/tex]
Explanation:
If we can apply the central limit theorem, we can approximate this distribution to a normal distribution.
The confidence level (for n=1) is defined as
[tex]X\pm \frac{z*\sigma}{\sqrt{n}}=X\pm z*\sigma[/tex]
For a 95% confidence interval, according to the normal distribution, z=1.96.
Then we have:
[tex]X\pm z*\sigma=4.17 \pm 1.96*0.14=4.17 \pm 0.2744[/tex]
Final answer:
To calculate the 95% confidence interval for a set of measurements with a mean of 3.095 g and a standard deviation of 0.0346 g, you first determine the standard error, then use it to find the margin of error, and finally compute the confidence interval, yielding an estimate that the true mean weight of a penny lies between 3.088 and 3.102 g.
Explanation:
To find the 95% confidence interval for a set of measurements, you utilize statistical principles that involve the mean, standard deviation, and sample size of the data. The basic formula to calculate the confidence interval is mean ± (critical value) * (standard deviation / √n), where √n is the square root of the sample size, and the critical value is determined based on the confidence level. For a 95% confidence level, the critical value (often represented as a z-score in the context of a normal distribution) is approximately 1.96.
Let's assume you're working with a sample size large enough for the central limit theorem to apply, simplifying the computation of the confidence interval to just involving the mean and standard deviation, due to a large sample size making the distribution of sample means approximately normal. Therefore, for the sample of 100 pennies with a mean of 3.095 g and a standard deviation of 0.0346 g, the 95% confidence interval can be calculated as follows:
First, calculate the standard error: SE = 0.0346 / √100 = 0.00346.Then, calculate the margin of error: Margin of Error = 1.96 * SE = 1.96 * 0.00346 = approximately 0.00678.Finally, determine the confidence interval: 3.095 ± 0.00678, which calculates to an interval of approximately 3.088 to 3.102 g.This calculation reveals that we estimate with 95% confidence that the true mean weight of a penny lies between 3.088 and 3.102 g.
How much power (energy per unit time) can be provided by a 75 m high waterfall with a flow rate of 10,000 L/s? Give answer in kW rate given here is volume per unit time; 10,000 L/s mean that every second 10,000 L of water go through the water fall
Explanation:
It is given that flow rate is 10,000 L/s. As 1 L equals 0.001 [tex]m^{3}[/tex].
Hence, flow rate will be 10 [tex]m^{3}/s[/tex]. Calculate mass of water flowing per second as follows.
Mass flowing per second = density × flow rate
= [tex]1000 kg/m^{3} \times 10 m^{3}/s[/tex]
= [tex]10^{4} kg/s[/tex]
Also, energy provided per second will be as follows.
E = mgh
Putting the given values into the above formula as follows.
E = mgh
= [tex]10^{4} kg/s \times 9.8 m/s^{2} \times 75 m[/tex]
= [tex]735 \times 10^{4} W[/tex]
or, = 7350 kW
Thus, we can conclude that energy per unit time provided will be 7350 kW.
What will be the final pH when 5.865 mL of 3.412 M NaOH is added to 0.5000 L of 1.564 x 10-3 M HCl?
Answer: 12.5
Explanation:
Molarity of a solution is defined as the number of moles of solute dissolved per Liter of the solution.
[tex]Molarity=\frac{moles}{\text {Volume in L}}[/tex]
moles of [tex]NaOH=Molarity\times {\text {Volume in L}}=3.412\times 5.865\times 10^{-3}L=0.02moles[/tex]
moles of [tex]HCl=Molarity\times {\text {Volume in L}}=1.564\times 10^{-3}\times 0.5000L=0.782\times 10^{-3}moles[/tex]
[tex]NaOH+HCl\rightarrow NaCl+H_2O[/tex]
According to stoichiometry:
1 mole of [tex]HCl[/tex] require 1 mole of [tex]NaOH[/tex]
Thus [tex]0.782\times 10^{-3}moles[/tex] will combine with [tex]0.782\times 10^{-3}moles[/tex] of [tex]NaOH[/tex]
Thus [tex](0.02-0.782\times 10^{-3})moles=0.019moles[/tex] of [tex]NaOH[/tex] will be left
Thus Molarity of [tex]OH^-=\frac{0.019}{0.56L}=0.03M[/tex]
[tex]pOH=-\log[OH^-][/tex]
Putting in the values:
[tex]pOH=-\log[0.03][/tex]
[tex]pOH=1.5[/tex]
[tex]pH+pOH=14[/tex]
[tex]pH=14-1.5=12.5[/tex]
Thus final pH will be 12.5.
Calculate the number of mg of Mn2+ left
unprecipitated in 100 mL of a 0.1000M solution of MnSO4
to whichenough Na2S has been added to makethe final
sulfide ion (S2-)concentration equal to 0.0900 M. Assume
no change in volume due tothe addition of Na2S.
ThepKsp of MnS is 13.500.
Answer:
1.930 * 10⁻⁹ mg of Mn⁺² are left unprecipitated.
Explanation:
The reaction that takes place is:
Mn⁺² + S⁻² ⇄ MnS(s)
ksp = [Mn⁺²] [S⁻²]
If the pksp of MnS is 13.500, then the ksp is:
[tex]ksp=10^{-13.500}=3.1623*10^{-14}[/tex]
From the problem we know that [S⁻²] = 0.0900 M
We use the ksp to calculate [Mn⁺²]:
3.1623*10⁻¹⁴= [Mn⁺²] * 0.0900 M
[Mn⁺²] = 3.514 * 10⁻¹³ M.
Now we can calculate the mass of Mn⁺², using the volume, concentration and atomic weight. Thus the mass of Mn⁺² left unprecipitated is:
3.514 * 10⁻¹³ M * 0.1 L * 54.94 g/mol = 1.930 * 10⁻¹² g = 1.930 * 10⁻⁹ mg.
A polymer P is made up of two monodisperse fractions; fraction A with molecular weight of 1000 g/mole and fraction B with a molecular weight of 100,000 g/mole. The batch contains an equal mole fraction of each fraction. Calculate the number average and the Weight average of polymer P.
Answer:
a)Number average molecular weight is 50, 500 g/mol
b) Weight average molecular weight is 99, 019.8 g/mol
Explanation:
We have a polymer P made up of two monodisperse fractions.
A with molecular weight of MA = 1000 g/mol and B with MB =100000 g/mol.
The batch contains an equal mole fraction of each component A and B.
Let's suppose a total number (Nt) of mols 2 moles. Equal fraction means XA = 0.5 and XB =0.5
Nt = 2 mol
Na = 2*0.5 = 1 mol
Nb = 2*0.5 = 1 mol.
So, we have 1 mol of A, 1 mol of B and 2 moles in total.
a) The number average molecular weight (NAM) is calculate using the mole numbers of each component. In this case, we will multiple each component molecular weight by the number of moles of each one. After that we will sum them and finally to divide by the total number of moles.
NAM = (Na*MA + Nb*MB)/(Nt)
NAM = (1 mol *1000 g/mol + 1*100000 g/mol ) /(2 mol)
NAM = 50500 g/mol
The number average molecular weight for the polymer P is 50,500 g/mol
b) Weight average molecular weight (WAM) is calculated using the mass quantities of each component. Weight mass of A (WA), weight mass of B (WB) are calculate using the moles of A, B and their molecular weights respectively. Total Weight (WT)
WA = Na*MA = 1 mol *1000 g/mol = 1000 g A
WB = Nb*MB = 1mol * 100000 g/mol = 100 000 gB
WT = WA + WB = 101 000 g
Now we will calculate average molecular using weights, we will multiple each component molecular weight by the mass of each one. After that we will sum them and finally to divide by the total mass.
WAM = (WA*MA + WB*MB)/(WT)
WAM = (1000 g *1000 g/mol + 100000 g*100000 g/mol )/(101 000 g)
WAM = 99 019.8 g/mol
The weight average molecular weight for polymer P is 99, 019.8 g/mol
Final answer:
The number average molecular weight (Mn) for the polymer is 50,500 g/mol, while the weight average molecular weight (Mw) is 198,019,802 g/mol, given the equal mole fraction of the two monomer fractions.
Explanation:
The number average molecular weight (Mn) and the weight average molecular weight (Mw) of a polymer comprising two monodisperse fractions.
Firstly, to calculate the Mn, we consider the definition that Mn is the total weight of the polymer divided by the total number of moles. Since each fraction has an equal mole fraction, we take the simple average of the two given molecular weights:
Mn = (1000 g/mol + 100,000 g/mol) / 2 = 50,500 g/molNext, to compute the Mw, which is the sum of the products of the weight contribution of each fraction and its molecular weight squared, divided by the total weight:
Mw = [(1/2) × 1000 g/mol × 1000 g/mol + (1/2) × 100,000 g/mol × 100,000 g/mol] / [(1/2) × 1000 g/mol + (1/2) × 100,000 g/mol]Mw = [1,000,000 + 1 × 10^10] / 50,500Mw = 198,019,802 g/molTo summarize, for a polymer with an equal mole fraction of two fractions with molecular weights of 1000 g/mol and 100,000 g/mol, the number average molecular weight is 50,500 g/mol and the weight average molecular weight is 198,019,802 g/mol.
In the following reaction, identify the oxidized species, reduced species, oxidizing agent, and reducing agent. Be sure to answer all parts. Cl2(aq) + 2 KI(aq) → 2 KCl(aq) +12(aq) Cl, is the (select) KI is the (select) and the (select) and the (select) A. A.
Answer :
[tex]Cl_2[/tex] is reduced species.
[tex]KI[/tex] is oxidized species.
[tex]Cl_2[/tex] is oxidizing agent.
[tex]KI[/tex] is reducing agent.
Explanation :
Redox reaction or Oxidation-reduction reaction : It is defined as the reaction in which the oxidation and reduction reaction takes place simultaneously.
Oxidation reaction : It is defined as the reaction in which a substance looses its electrons. In this, oxidation state of an element increases. Or we can say that in oxidation, the loss of electrons takes place.
Reduction reaction : It is defined as the reaction in which a substance gains electrons. In this, oxidation state of an element decreases. Or we can say that in reduction, the gain of electrons takes place.
Reducing agent : It is defined as the agent which helps the other substance to reduce and itself gets oxidized. Thus, it will undergo oxidation reaction.
Oxidizing agent : It is defined as the agent which helps the other substance to oxidize and itself gets reduced. Thus, it will undergo reduction reaction.
The balanced redox reaction is :
[tex]Cl_2(aq)+2KI(aq)\rightarrow 2KCl(aq)+I_2(aq)[/tex]
The half oxidation-reduction reactions are:
Oxidation reaction : [tex]2I^-\rightarrow I_2+2e^-[/tex]
Reduction reaction : [tex]Cl_2^++2e^-\rightarrow 2Cl^-[/tex]
From this we conclude that the [tex]'KI'[/tex] is the reducing agent that loses an electron to another chemical species in a redox chemical reaction and itself gets oxidized and [tex]'Cl_2'[/tex] is the oxidizing agent that gain an electron to another chemical species in a redox chemical reaction and itself gets reduced.
Thus, [tex]Cl_2[/tex] is reduced species.
[tex]KI[/tex] is oxidized species.
[tex]Cl_2[/tex] is oxidizing agent.
[tex]KI[/tex] is reducing agent.
Iodine from potassium iodide (KI) is oxidized, and chlorine from chlorine gas (Cl2) is reduced; Cl2 is the oxidizing agent and KI is the reducing agent in the reaction.
Explanation:In the reaction Cl2(aq) + 2 KI(aq) → 2 KCl(aq) + I2(aq), the oxidized species is iodine (I) from potassium iodide (KI), and the reduced species is chlorine (Cl) from chlorine gas (Cl2). During the reaction, I- loses electrons and is therefore oxidized to I2; its oxidation number changes from -1 to 0. Conversely, each Cl atom in Cl2 gains one electron to become Cl-, going from an oxidation state of 0 to -1. Thus, the oxidizing agent is Cl2 because it accepts electrons (is reduced), and the reducing agent is KI because it donates electrons (is oxidized).
Henry low is Obeyed by a gas when gas has high • Pressure • Temperature • Solubility • Non of the above
Answer:
None of the above
Explanation:
Henry's law -
This law was given by William Henry in the year 1803 , it is also known as the gas law ,
According to Henry's law , the amount of gas which gets dissolved in a liquid is directly related to the partial pressure of gas that is in equilibrium with the liquid , at a constant temperature .
Or it can stated as ,
The gases' solubility in a liquid is directly related to the partial pressure of gas that is in equilibrium with the liquid .
This law is applicable for sparingly soluble gases in liquid solvents .
And the solubility of a gas is independent of temperature and pressure .
Hence ,
the correct option is None of the above .
Chemical Equations
Instructions: Solve the following chemical equations.
For the following reaction, calculate how many moles of NO2forms when 0.356 moles of the reactant completely reacts. 2 N2O5(g) ---> 4 NO2(g) + 02(g)
Answer:
0.712 moles of NO₂ are formed.
Explanation:
First, we need to write the balanced equation:
2 N₂O₅(g) ⇄ 4 NO₂(g) + O₂(g)
From the balanced equation, we can see the relationship between the moles of N₂O₅ and the moles of NO₂. Every 2 moles of N₂O₅ that react, 4 moles of NO₂ are formed. Let us apply this relationship to the information given by the problem (0.356 moles of N₂O₅):
[tex]0.356molN_{2}O_{5}.\frac{4molNO_{2}}{2molN_{2}O_{5}} =0.712molNO_{2}[/tex]
For each of the following units and concentration values, mention if they are parts per million (ppm), parts per billion (ppb) or parts per trillion (ppt) to
a. g / Ton
b. mg / L
c. μg / L
d. ng / L (ng = nanogram) and e
e. mg / ton
Answer:
a) ppm
b) ppm
c) ppb
d) ppt
e) ppb
Explanation:
a) You know that 1000 g are 1 kg, and 1000 kg are 1 ton, so (1000)*(1000) g are 1 ton, so 1,000,000 grams are one ton.
b) 1000 mg are 1 g, and 1000 g are 1 liter, so 1,000,000 grams are one liter.
c) You know that 1000 ug are 1 mg, so with the b), we just need to multiply the answer by 1000, so 1,000,000,000 ug are 1 liter.
d) The same as c, 1000 ng are 1 mg. So we are talkinf of ppt.
e) 1000 mg are 1 g. And 1000 g are 1 kg, then 1000 kg are one ton. So 1,000,000,000 mg are one ton.
A student is heating a chemical in a beaker with a Bunsen burner.
In a paragraph of at least 150 words, identify the safety equipment that should be used and the purpose of it for the given scenario.
Answer:The student should be wearing a lab coat or maybe an apron to prevent chemicals from spilling or exploding onto their clothes, I do recommend a lab coat better though because it can protect your skin better. Next, make sure while messing with chemicals you are always wearing goggles, if you are not wearing them there is a chance that after touching chemicals you could touch your eyes. And that brings me to washing your hands straight away after messing with chemicals. You could also wear gloves and just take them off when you're done but if you don't have clean hands afterward you could always put the chemicals all over your skin. But in case you do touch your eyes there is always an emergency eyewash station somewhere in the lab room. And if you are to get Chemicals on your skin, in your hair, on your clothes, or to be on fire, there shall be a shower somewhere to get rid of that. But if you read the instructions or listen closely to the teacher you shall have no problem.
Explanation:
I kinda got off topic
When a student is warming a chemical in a container using a special burner, it is very important to focus on safety by using the right safety tools.
What is the safety equipmentFirst, the student needs to wear the right safety clothes like a lab coat, gloves, and goggles to protect themselves from getting splashed or hurt by chemicals. A lab coat stops chemicals from touching the skin, gloves keep the hands safe, and safety goggles protect the eyes from chemicals
and hot things.
Furthermore, using a fume hood is necessary to make sure there is enough fresh air circulating and to remove any dangerous fumes or gases that might be released while heating things up.
Read more about safety equipment here:
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Determine the percent yield of the following reaction when 2.80 g of P reacts with excess oxygen. The actual yield of this reaction is determined to by 3.89 g of P2O5.
4 P + 5 O2 -----> 2 P2O5
Answer : The percent yield of [tex]P_2O_5[/tex] is, 30.39 %
Solution : Given,
Mass of P = 2.80 g
Molar mass of P = 31 g/mole
Molar mass of [tex]P_2O_5[/tex] = 284 g/mole
First we have to calculate the moles of P.
[tex]\text{ Moles of }P=\frac{\text{ Mass of }P}{\text{ Molar mass of }P}=\frac{2.80g}{31g/mole}=0.0903moles[/tex]
Now we have to calculate the moles of [tex]NH_3[/tex]
The balanced chemical reaction is,
[tex]4P+5O_2\rightarrow 2P_2O_5[/tex]
From the reaction, we conclude that
As, 4 mole of [tex]P[/tex] react to give 2 mole of [tex]P_2O_5[/tex]
So, 0.0903 moles of [tex]P[/tex] react to give [tex]\frac{0.0903}{4}\times 2=0.04515[/tex] moles of [tex]P_2O_5[/tex]
Now we have to calculate the mass of [tex]P_2O_5[/tex]
[tex]\text{ Mass of }P_2O_5=\text{ Moles of }P_2O_5\times \text{ Molar mass of }P_2O_5[/tex]
[tex]\text{ Mass of }P_2O_5=(0.04515moles)\times (284g/mole)=12.8g[/tex]
Theoretical yield of [tex]P_2O_5[/tex] = 12.8 g
Experimental yield of [tex]P_2O_5[/tex] = 3.89 g
Now we have to calculate the percent yield of [tex]P_2O_5[/tex]
[tex]\% \text{ yield of }P_2O_5=\frac{\text{ Experimental yield of }P_2O_5}{\text{ Theoretical yield of }P_2O_5}\times 100[/tex]
[tex]\% \text{ yield of }P_2O_5=\frac{3.89g}{12.8g}\times 100=30.39\%[/tex]
Therefore, the percent yield of [tex]P_2O_5[/tex] is, 30.39 %
To determine the percent yield of a reaction, compare the actual yield to the theoretical yield. The theoretical yield can be calculated using stoichiometry and the balanced equation. In this case, the percent yield is 60.7%.
Explanation:To determine the percent yield of a reaction, you need to compare the actual yield to the theoretical yield. The theoretical yield is the maximum amount of product that can be formed according to the stoichiometry of the balanced equation. In this case, the balanced equation is 4 P + 5 O2 → 2 P2O5. The molar mass of P2O5 is 141.944 g/mol, so the theoretical yield can be calculated as:
Therefore, the theoretical yield is 6.41 g P2O5. To calculate the percent yield, divide the actual yield by the theoretical yield and multiply by 100:
Percent Yield = (Actual Yield ÷ Theoretical Yield) × 100
Percent Yield = (3.89 g ÷ 6.41 g) × 100 = 60.7%
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Calculate ln (0.345). Report your answer to 3 significant figures.
Answer:
-1.06
Explanation:
0.345 has three significant figures since the zero does not represent a significant figure.
So, usign the calculator, we find ln (0.345) = -1.06421086195
Now, the problem says that you need to report your answer to three significant figures.
So, you should take the first three numbers of the answer:
ln (0.345) = -1.06
The solubility of acetanilide is 12.8 g in 100 mL of ethanol at 0 ∘C, and 46.4 g in 100 mL of ethanol at 60 ∘C. What is the maximum percent recovery that can be achieved for the recrystallization of acetanilide from ethanol?
A student was given a sample of crude acetanilide to recrystallize. The initial mass of the the crude acetanilide was 171 mg.The mass after recrystallization was 125 mg.
Calculate the percent recovery from recrystallization.
Answer: 72.41% and 26.90% respectively.
Explanation:
At 60°C, you can dissolve 46.4g of acetanilide in 100mL of ethanol. If you lower the temperature, at 0°C, you can dissolve just 12.8g, which means (46.4g-12.8g)=33.6g of acetanilide must have precipitated from the solution.
We can calculate recovery as:
[tex]\%R=\frac{crystalized\ mass}{initial\ mass}*100 =\frac{33.6\ g}{46.4\ g}*100=72.41\%[/tex]
So the answer to the first question is 72.41%.
For the second part just use the same formula, the mass of the precipitate is the final mass minus the initial mass, (171mg-125mg)=46mg.
[tex]\%R=\frac{crystalized\ mass}{initial\ mass}*100 =\frac{46\ mg}{171\ mg}*100=26.90\%[/tex]
So the answer to the second question is 26.90%.
A1.00 m long beam of stainless steel with a square 2.00 cm x 2.00 cm cross section has a mass of 3.02 kg. What is its density in grams per cubic centimeter? Round your answer to two decimal places.
Answer:
density = 7.55 g/cm^3
Explanation:
we need to get the volume first to get the density , and the volume formula is:
the volume = area * thickness
where :
area = 2 cm * 2 cm = 4 cm^2
and thickness = 100 cm
by substitution:
the volume = 4 * 100 = 400 cm^3
where
density = mass / volume
we have to convert mass from kg to g = 3020 g
by substitution:
density = 3020 g / 400 cm^3
= 7.55 g/cm^3
Write the isotopic symbol for the following (show your work) a) An isotope of iodine whose atoms have 78 neutrons b) An isotope of cesium whose atoms have 82 neutrons c) An isotope of strontium whose atoms have 52 neutrons
Final answer:
The isotopic symbol for an isotope of iodine with 78 neutrons is 131I53. The isotopic symbol for an isotope of cesium with 82 neutrons is 137Cs55. The isotopic symbol for an isotope of strontium with 52 neutrons is 90Sr38.
Explanation:
An isotope of iodine with 78 neutrons would have an atomic number of 53. To write the isotopic symbol, we include the atomic number as a subscript and the mass number (atomic number + number of neutrons) as a superscript. Therefore, the isotopic symbol for the iodine isotope with 78 neutrons would be 131I53.
An isotope of cesium with 82 neutrons would have an atomic number of 55. So, the isotopic symbol for the cesium isotope with 82 neutrons would be 137Cs55.
An isotope of strontium with 52 neutrons would have an atomic number of 38. Hence, the isotopic symbol for the strontium isotope with 52 neutrons would be 90Sr38.
estimate the density of air (g/L) at 40 degrees celsius and 3 atm. Report answer in units of g/L & two significant figures.
2) Estimate the molecular weight of Linanyl acetate (C12 H20 O2) in terms of (g/mol) using 3 significant figures.
Answer:
1) The density of air at 40 degrees Celsius and 3 atm pressure is 3.4 g/L.
2) Molecular mass of linanyl acetate is 196 g/mol.
Explanation:
1) Average molecular weight of an air ,M= 28.97 g/mol
[tex]PV=nRT[/tex]
or [tex] PM=dRT[/tex]
P = Pressure of the gas
T = Temperature of the gas
d = Density of the gas
M = molar mass of the gas
R = universal gas constant
P = 3 atm, T = 40°C = 313.15 K, M = 28.97 g/mol
[tex]d=\frac{PM}{RT}=\frac{3 atm \times 28.97 g/mol}{0.0821 atm L/ mol K\times 313.15 K}[/tex]
d = 3.4 g/mL
The density of air at 40 degrees Celsius and 3 atm pressure is 3.4 g/L.
2) Molecular formula of Linanyl acetate = [tex]C_{12}H_{20}O_2[/tex]
Atomic mass sof carbon = 12.01 g/mol
Atomic mass of hydrogen = 1.01 g/mol
Atomic mass of oxygen = 16.00 g/mol
Molecular mass of Linanyl acetate :
[tex]12\times 12.01 g/mol+20\times 1.01 g/mol+2\times 16.00 g/mol =196.32 g/mol \approx 196 g/mol[/tex]
The rate of reaction at 550 K is ten times faster than the rate of reaction at 440 K. Find the activation energy from the collision theory. a) 40075.14 J/mol b) 50078.5J/mol c) 44574.5 J/mol d) 43475.5 J/mol
Answer : a) 40075.14 J/mol
Explanation :
According to the Arrhenius equation,
[tex]K=A\times e^{\frac{-Ea}{RT}}[/tex]
or,
[tex]\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}][/tex]
where,
[tex]K_1[/tex] = rate constant at [tex]440K[/tex] = k
[tex]K_2[/tex] = rate constant at [tex]550K[/tex] = 10 k
[tex]Ea[/tex] = activation energy for the reaction = ?
R = gas constant = 8.314 J/mole.K
[tex]T_1[/tex] = initial temperature = 440 K
[tex]T_2[/tex] = final temperature = 550 K
Now put all the given values in this formula, we get :
[tex]\log (\frac{10k}{k})=\frac{Ea}{2.303\times 8.314J/mole.K}[\frac{1}{440K}-\frac{1}{550K}][/tex]
[tex]Ea=40075.14J/mol [/tex]
Therefore, the activation energy for the reaction is 40075.14J/mol.
The distance from Earth to the Moon is approximately 240.000 mi Part C The speed of light is 3.00 x 10 m/s How long does it take for light to travel from Earth to the Moon and back again? Express your answer using two significant figures.
Answer:
2.6 sec
Explanation:
The distance between the Earth and the moon = 240,000 miles
Also,
1 mile = 1609.34 m
So,
Distance between the Earth and the moon = 240,000 × 1609.34 m = 386241600 m
Speed of the light = 3 × 10⁸ m/s
Distance = Speed × Time.
So,
Time = Distance / Speed = 386241600 m / 3 × 10⁸ m/s = 1.3 sec
For back journey = 1.3 sec
So, total time = 2.6 sec