Prepare benzoic acid from from benzyl alcohol. What is the purpose of the addition of the sulfuric acid?Include chemical reaction.

Answers

Answer 1

Answer:

Benzoic acid can be prepared from benzyl alcohol using potassium dichromate and sulfuric acid.

Explanation:

Benzyl alcohol is a primary alcohol that can be transformed into benzoic acid by an oxidation reaction.

The reactants needed are potassium dichromate and sulfuric acid.

The sulfuric acid is needed to react with the potassium dichromate and form cromic acid, which is a strong oxidizing agent that will convert the alcohol to its equivalent carboxylic acid.

The chemical reaction is

3ФCH₂OH + 2Cr₂O⁷⁻ + 16 H⁺  3ФCOOH + 4Cr³⁺ + 11H₂O

Prepare Benzoic Acid From From Benzyl Alcohol. What Is The Purpose Of The Addition Of The Sulfuric Acid?Include

Related Questions

Calculate the mass of 1.0 L of helium (He), 1.0 L of chlorine gas (Cl2), and 1.0 L of air (79% N2, 21% O2 by volume) at 25°C and 1 atm total pressure. Explain why a balloon filled with helium rises and why leaks of chlorine gas can be dangerous.

Answers

To calculate the mass we use the following formulas:

PV=nRT     (1)

and

n = m / M    (2)

where:

P - pressure (atm)

V - volume (L)

n - moles

R - gas constant = 0.082 (L × atm) / (mol × K)

T - temperature (°K) (25°C + 273 = 298°K)

m - mass (g)

M - molecular mass (g/mole)

Now we rewrite equation (1):

n = PV / RT

And replace n with m / M from equation (2):

m / M = PV / RT

m = (P × V × M) / (R ×T)

1 L of He will have a mass of:

m = (1 × 1 × 4) / (0.082 × 298) = 0.1637 g

1 L of Cl₂ will have a mass of:

m = (1 × 1 × 71) / (0.082 × 298) = 2.9055 g

1.0 L of air will contain 0.79 L of N₂ and 0.21 L of O₂

0.79 L of N₂ will have a mass of:

m = (1 × 0.79 × 28) / (0.082 × 298) = 0.9052 g

0.21 L of O₂ will have a mass of:

m = (1 × 0.21 × 32) / (0.082 × 298) = 0.2750 g

mass of air = mass of N₂ + mass of O₂

mass of air = 0.9052 + 0.2750 = 1.1802 g

A balloon filed with helium will rise because as you see 1 L of helium is lighter than 1 L of air.

Chlorine gas is dangerous because chlorine is very toxic for human life and more of that is heavier than the air so will diffuse very hard from the area where the leak appeared.

In a five-fold serial dilution of a 20 pg/ml solution, all tube dilutions are 1/5. What is the substance concentration in the third tube of this series?

Answers

Answer:

0.8 pg/ml

Explanation:

To make the dilutions, you will take 1 ml of the original solution (tube 1) and add 4 ml of solvent. You will now have 20 pg per 5 ml of solution, so your new concentration will be 4 pg/ml (tube 2). Then you will repeat the process, so you will have 4 pg per 5 ml of solution, resulting in a concentration of 0.8 pg/ml (tube 3). The same process will be repeated for tubes 4 and 5.

In natural convection heat transfer, the parameter
a) Nusselt Number
b) Rayleigh Number
c) Grashof Number
c) Lewis Number

Answers

Answer:

correct answer is option c i.e Grashof Number

Explanation:

The Grashof number is a dimensionless number, which is named after renowned scientist  Franz Grashof. The Grashof quantity is defined as the proportion of the buoyant force to viscous force performing on a fluid in a pace boundary layer.

Its function in natural convection is more or less the same as that of Reynolds's number in compelled convection.

I have a 5 M stock solution of KCI (For a protocol 100 mM KCl is considered "1X" concentration). If I want to make 10 ml of a 4X concentration KCl solution, how much 5 M stock and how much water do I need to add together?

Answers

Answer:

You need 0.8 ml of 5M stock solution and you have to add 9.2 ml of water.

Explanation:

Protocol solution (1X): 100 mM=0.1M

4X: 0.4M

The concentration of a solution is inversely proportional to the volume of a solution, so:

[tex]M_{1}V_{1}=M_{2}V_{2}[/tex]

where:

M1= 5M stock solution

V1= amount of solution we need to collect

M2=4X solution

V2= 10 ml (volumen of 4X solution)

Therefore:

5M×V1=0.4M×10ml

V1={0.4M}{5M}10ml=0.8ml

[tex]5M*V_{1}=0.4M*10ml\\ V_{1}=\frac{0.4M}{5M}10ml=0.8ml[/tex]

To make a 10 ml solution we have to add 9.2 ml of water because V2 es 10 ml.

A piece of an unknown metal has a volume of 16.6 mL and a mass of 190.1 grams. The density of the metal is g/mL A piece of the same metal with a mass of 94.6 grams would have a volume of ml. Submit Answer

Answers

Answer: The density of the metal is 11.45 g/mL and the volume occupied by 94.6 grams is 8.26 mL

Explanation:

To calculate the density of unknown metal, we use the equation:

[tex]\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}[/tex]       ......(1)

Volume of unknown metal = 16.6 mL

Mass of unknown metal = 190.1 g

Putting values in equation 1, we get:

[tex]\text{Density of unknown metal}=\frac{190.1g}{16.6mL}\\\\\text{Density of unknown metal}=11.45g/mL[/tex]

The density of the metal remains the same.

Now, calculating the volume of unknown metal, using equation 1, we get:

Density of unknown metal = 11.45 /mL

Mass of unknown metal = 94.6 g

Putting values in above equation, we get:

[tex]11.45g/mL=\frac{94.6g}{\text{Volume of unknown metal}}\\\\\text{Volume of unknown metal}=8.26mL[/tex]

Hence, the density of the metal is 11.45 g/mL and the volume occupied by 94.6 grams is 8.26 mL


Which property of metals is explained by the "sea of electrons" within metallic bonding?

A. Malleability

B. All of the Above

C. Electrical conductivity

D. Thermal conductivity

Answers

Answer:

B. All of the Above

Explanation:

Sea of electrons -

This model of the metallic bonding helps in explaining the properties like ,  malleability , ductility ,high electrical conductivity ,  luster ,high thermal conductivity of the metals in solid state .

The metallic bonding is between metal atoms and the ionic bond links a metal and a non - metal together ,

In case of metallic bonding , bulk of metal atoms are joined .

hence from the question , all the given properties are correct .

The reaction of carboxylic acids with alcohol in the presence of an acid catalyst yields Select one: amides O esters O no reaction occurs O aldehydes

Answers

Answer:

esters

Explanation:

The -OR group of the alcohol replaces the -OH of the carboxylic acid, forming an ester. See attachment for condensed mechanism.

What is the focus on the biological organization levels for ecology?

Answers

Answer:

The biology of the ecosystem is always studied from the composition of organisms, population and  community.

Explanation:

In an ecosystem, various processes are sustained and these processes regulate the environment, as the biotic communities in the ecosystem make up the biosphere. Various life processes, their interaction, movement, and successional development ecosystem and the distribution of organisms are the focus of biological organization levels of ecology. First comes the organism ecology level as the researchers study their adaptations for the structure and physiographic behavior. Second is the population ecology level with a group of interbreeding organisms next level is of Community ecology and ecosystem ecology as they study the different species within the area using a three-dimensional model. After these the ecosystem ecology that is an extension of all the levels in the ecosystem. The natural environment can provide all the needed nutrients and life-supporting factors.

One solution has a formula C (n) H (2n) O (n) If this material weighs 288 grams, dissolves in weight 90 grams, the solution will have a boiling point of 101.24 ° C. Find the formula
The molecules of this substance When determining the Kb value of water = 0.512 ° C / m and the atomic weight H = 1, C = 12 and O = 16.

Answers

Explanation:

The given data is as follows.

Boiling point of water ([tex]T^{o}_{b}) = 100^{o}C[/tex] = (100 + 273) K = 323 K,

Boiling point of solution ([tex]T_{b}) = 101.24^{o}C[/tex] = (101.24 + 273) K = 374.24 K

Hence, change in temperature will be calculated as follows.

              [tex]\Delta T_{b} = (T_{b} - T^{o}_{b})[/tex]

                           = 374.24 K - 323 K

                           = 1.24 K

As molality is defined as the moles of solute present in kg of solvent.

            Molality = [tex]\frac{\text{weight of solute \times 1000}}{\text{molar mass of solute \times mass f solvent(g)}}[/tex]

Let molar mass of the solute is x grams.

Therefore,   Molality = [tex]\frac{\text{weight of solute \times 1000}}{\text{molar mass of solute \times mass f solvent(g)}}[/tex]

                        m = [tex]\frac{288 g \times 1000}{x g \times 90}[/tex]              

                          = [tex]\frac{3200}{x}[/tex]

As,    [tex]\Delta T_{b} = k_{b} \times molality[/tex]

                 [tex]1.24 = 0.512 ^{o}C/m \times \frac{3200}{x}[/tex]

                       x = [tex]\frac{0.512 ^{o}C/m \times 3200}{1.24}[/tex]

                          = 1321.29 g

This means that the molar mass of the given compound is 1321.29 g.

It is given that molecular formula is [tex]C_{n}H_{2n}O_{n}[/tex].

As, its empirical formula is [tex]CH_{2}O[/tex] and mass is 30 g/mol. Hence, calculate the value of n as follows.

                n = [tex]\frac{\text{Molecular mass}}{\text{Empirical mass}}[/tex]

                   = [tex]\frac{1321.29 g}{30 g/mol}[/tex]

                   = 44 mol

Thus, we can conclude that the formula of given material is [tex]C_{44}H_{88}O_{44}[/tex].

How many neutrons in an atom of 30p? O a. 17 O b. 30.974 O c. 15 O d. 14 O e. 16

Answers

Answer:

The correct option is: c. 15

Explanation:

Phosphorous is a chemical element which belongs to the group 15 of the periodic table and has atomic number 15. It is a highly reactive non-metal of the p-group.  

Since, atomic number of an atom is the number of electrons and number of protons for neutral atoms.

So, the number of protons = number of electrons = 15

The atomic mass is obtained by adding the number of neutrons and the protons.

So, number of neutrons + number of protons = 30

So, number of neutrons + 15 = 30

Therefore, the number of neutrons in ³⁰P = 15

What is the pH at each of the points in the titration of 25.00 mL of 0.2000 M
HCl by 0.2000 M NaOH:
i) Before adding NaOH

ii) After adding 24.00 mL NaOH

Answers

Answer:

i) pH = 0.6990

ii) pH = 2.389

Explanation:

i) Before adding aqueous NaOH, there are 25.00 mL of 0.2000 M HCl. HCl reacts with the water in the aqueous solution as follows:

HCl + H₂O ⇒ H₃O⁺ + Cl⁻

The HCl and H₃O⁺ are related to each other through a 1:1 molar ratio, so the concentration of H₃O⁺ is equal to the HCl concentration.

The pH is related to the hydronium ion concentration as follows:

pH = -log([H₃O⁺]) = -log(0.2000) = 0.699

ii) Addition of NaOH causes the following reaction:

H₃O⁺ + NaOH ⇒ 2H₂O + Na⁺

The H₃O⁺ and NaOH react in a 1:1 molar ratio. The amount of NaOH added is calculated:

n = CV = (0.2000 mol/L)(24.00 mL) = 4.800 mmol NaOH

Thus, 4.800 mmol of H₃O⁺ were neutralized.

The initial amount of H₃O⁺ present was:

n = CV = (0.2000 mol/L)(25.00 mL) = 5.000 mmol H₃O⁺

The amount of H₃O⁺ that remains after addition of NaOH is:

(5.000 mmol) - (4.800 mmol) = 0.2000 mmol

The concentration of H₃O⁺ is the amount of H₃O⁺ divided by the total volume. The total volume is (25.00 mL) + (24.00 mL ) = 49.00 mL

C = n/V = (0.2000 mmol) / (49.00 mL) = 0.004082 M

The pH is finally calculated:

pH = -log([H₃O⁺]) = -log(0.004082) = 2.389

Explain what D and L represent in stereoisomers

Answers

Final answer:

The D and L stereochemical descriptors are used to represent the configuration of stereoisomers in monosaccharides. The D- or L- designation is based on the position of the -OH group on the penultimate carbon in the Fisher projection. The D-configuration is commonly found in nature and only dextrorotary amino acids are used by cells to build proteins.

Explanation:

The D and L stereochemical descriptors are used to represent the configuration of stereoisomers, specifically in the context of monosaccharides or sugars. The designation of D or L is based on the position of the -OH group on the second-last carbon (penultimate C) in the Fisher projection. If the -OH group is on the right side, it is assigned D-configuration, and if it is on the left side, it is assigned L-configuration.

These descriptors do not indicate the rotation of plane polarized light, but purely define the configuration. Enantiomers that are D- and L- pairs have the same common name, with the D- or L- designation indicating their configuration. It's important to note that the D- and L- designation does not always correlate with the dextro/levo rotatory nature of the enantiomers in a polarimeter.

For example, D-glucose and L-glucose are enantiomers with the penultimate C defining D- or L-configuration. The D-configuration is commonly found in nature, and only dextrorotary d amino acids (L amino acids) are used by cells to build polypeptides and proteins.

If you feed 100 kg of N2 gas and 100 kg of H2 gas into a
reactor. What is the excess reactant?

Answers

Answer:

H₂ gas

Explanation:

The reaction between nitrogen gas and hydrogen gas forms ammonia (the Haber-Bosch process):

N₂ + 3H₂ ⇒ 2NH₃

The excess reactant can be found by comparing the moles of nitrogen and hydrogen. The molar mass of N₂ is 28.00 g/mol and the molar mass of H₂ is 2.02 g/mol.

(100 kg N₂)(1000g/kg)(mol/28.00g) = 3570 mol

(100 kg H₂)(1000g/kg)(mol/2.02g) = 49500 mol

The molar ratio between the reactant N₂ and H₂ is 1N₂:3H₂. The moles of nitrogen required to react with H₂ is:

(49500 mol H₂)(1N₂ / 3H₂) = 16500 mol

The amount of nitrogen required is more than what is available, so nitrogen is the limiting reagent and hydrogen is the excess reagent.

What is the preferred electrical charge of a Sodium ion? O a. +1 O O O b. +2 Oco O O d.-1 O e. 2 O

Answers

the answer is a) +1 (Na+)

Question 3 (1 point) The extinction coefficient for copper sulfate in aqueous solution is 12 M-1.cm-1 at 800 nm. If the absorbance of the copper sulfate solution in 0.50 cm cuvette is 0.50 at 800 nm, the concentration of copper sulfate in this solution is: O3M O 83 mm 8.3 mm 12 M-cm 0.042 M

Answers

Answer:

The concentration of the copper sulfate solution is 83 mM.

Explanation:

The absorbance of a copper sulfate solution can be calculated using Beer-Lambert Law:

A = ε . c . l

where

ε is the extinction coefficient of copper sulfate (ε = 12 M⁻¹.cm⁻¹)

c is its molar concentration (what we are looking for)

l is the pathlength (0.50 cm)

We can use this expression to find the molarity of this solution:

[tex]c=\frac{A}{\epsilon.l } =\frac{0.5}{12M^{-1}cm^{-1}0.50cm  } =0.083M=83mM[/tex]

Final answer:

The concentration of copper sulfate in the solution is calculated using Beer's law and the given values, resulting in a concentration of 0.042 M.

Explanation:

The concentration of copper sulfate in solution can be calculated using Beer's law, which is the relation A = εbc where A is absorbance, ε is the extinction coefficient, b is the path length, and c is the concentration. Given the question, the extinction coefficient for copper sulfate is 12 M-1.cm-1, the absorbance is 0.50, and the cuvette path length is 0.50 cm. To find the concentration c, rearrange the equation to c = A / (εb) and substitute into that the values provided, resulting in a concentration of 0.042 M for copper sulfate in the solution.

Glycerol is a syrupy liquid often used in cosmetics and soaps. A 3.25-L sample of pure glycerol has a mass of 4.10 x 10 g.
What is the density of glycerol in g/cm"? Express your answer in grams per cubic centimeter.

Answers

Explanation:

It is known that density is the amount of mass present in liter of solution or substance.

Mathematically,      Density = [tex]\frac{mass}{volume}[/tex]

It is given that volume is 3.25 L and mass is [tex]4.10 \times 10^{3} g[/tex]. Hence, calculate the density of glycerol as follows.

                     Density = [tex]\frac{mass}{volume}[/tex]

                                   = [tex]\frac{4.10 \times 10^{3} g}{3.25 L}[/tex]

                                    = [tex]1.26 \times 10^{3} g/L[/tex]

As, 1 L = 1000 [tex]cm^{3}[/tex].

So,           [tex]1.26 \times 10^{3} g/L \times \frac{1000 cm^{3}}{1 L}[/tex]

                 = [tex]1260 \times 10^{6} g/cm^{3}[/tex]    

Thus, we can conclude that the density of glycerol is [tex]1260 \times 10^{6} g/cm^{3}[/tex].

Which statement is true about obligate anaerobes? View Available Hint(s) Which statement is true about obligate anaerobes? They obtain energy by oxidizing ferrous ions. They will use O2 if it is present, but may obtain energy by fermentation if needed. They use O2 for cellular respiration and cannot grow without it. They are poisoned by O2. They live exclusively by cellular respiration or by anaerobic respiration.

Answers

Answer: They are poisoned by O₂

Explanation:

Obligate anaerobes cannot survive in normal concentrations of oxygen. Depending on the species, tolerance varies from 0.5% to 8% oxygen.

Under normal cellular conditions, O₂ turns into O₂⁻ and H₂O₂, toxic to the organism. Obligate anaerobes lack enzymes superoxide dismutase and catalase, capable of turning O₂⁻ and H₂O₂ back into breathable O₂.

The statement that is true about obligate anaerobes is they are poisoned by [tex]O_2[/tex].

Microorganisms known as obligatory anaerobes are incapable of surviving or developing in the presence of oxygen. They cannot detoxify the reactive oxygen species (ROS) created during aerobic respiration because they lack the enzymes catalase and superoxide dismutase. As a result, oxygen is poisonous to them. When cells are exposed to oxygen, toxic byproducts can arise that injure the cells' biological constituents and ultimately cause cell death.

Obligate anaerobes are constrained to anaerobic metabolic pathways, in contrast to facultative anaerobes, which can flip between aerobic and anaerobic metabolism depending on oxygen availability. Typically, they break down organic substances without the need of oxygen through fermentation or anaerobic respiration to produce energy.

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A tank with a height of 100 feet and a constant cross sectional area of 10 ft has a constant input flow of 15 ft /hour of pulp stock at 1% consistency and has a screen on the exit flow that only allows water to be removed and keeps all of the fiber in the tank. The tank is well mixed and completely full (i.e, an overflow type condition where flow in equals flow out). What is the consistency as a function of time if the tank contents starts off at 0% consistency. Plot it using excel or another spreadsheet tool, see below. The tank will become clogged when the consistency reaches 6%, when will this happen?

Answers

Answer:

(a) The consistency as a function of time is C=0.15*t.

(b) The tank will become clogged in 24 minutes.

Explanation:

The rate of accumulation of the pulp stock can be defined as

[tex]\frac{dC}{dt}=Q_{i}*C_{i}-Q_{o}*C_{o}[/tex]

In this case, Co is 0, because the exit flow is only water and 0% fiber.

[tex]frac{dC}{dt}=Q_{i}*C_{i}-Q_{o}*0=Q_{i}*C_{i}[/tex]

Rearranging adn integrating

[tex]dC = (Q_{i}*C_{i})dt\\\int dC = \int (Q_{i}*C_{i})dt\\C=(Q_{i}*C_{i})*t+constant[/tex]

At t=0, C=0,

[tex]C=(Q_{i}*C_{i})*t+constant\\0=(Q_{i}*C_{i})*0+constant\\0=constant\\\\C=(Q_{i}*C_{i})*t[/tex]

[tex]C=(15*0.01)*t=0.15*t[/tex]

(b) The time at when the concentration reaches 6% is 0.4 hours or 24 minutes.

[tex]C=0.15*t\\0.06=0.15*t\\t=0.06/0.15=0.4[/tex]

Final answer:

The consistency of the pulp stock in the tank can be calculated using the equation of continuity. The consistency as a function of time can be determined by calculating the flow rate, density, mass flow rate, and the ratio of fiber mass to pulp stock mass. The graph of consistency as a function of time can be plotted using time intervals and consistency values.

Explanation:

The equation of continuity states that the mass flow rate into a volume has to equal the mass flow rate out of the volume. In this case, the tank is well-mixed and completely full, so the flow in equals the flow out. We can use this equation to calculate the consistency of the pulp stock in the tank as a function of time.

Step 1: Calculate the flow rate

The flow rate can be calculated by multiplying the input flow rate (15 ft/hr) by the cross-sectional area of the tank (10 ft2). This gives us a flow rate of 150 ft3/hr.

Step 2: Calculate the density

The density of the pulp stock is given as 1% consistency. To convert this to density, we need to know the density of water, which is 62.4 lb/ft3. The density of the pulp stock can then be calculated as (0.01)(62.4 lb/ft3).

Step 3: Calculate the mass flow rate

The mass flow rate can be calculated by multiplying the flow rate by the density. This gives us a mass flow rate of (150 ft3/hr)(0.01)(62.4 lb/ft3).

Step 4: Calculate the consistency

The consistency is the mass of fiber in the tank divided by the mass of the pulp stock in the tank. Since all of the fiber is kept in the tank, the consistency is equal to the mass of fiber divided by the mass flow rate. This can be calculated as 100 ft (the height of the tank) divided by the mass flow rate calculated in step 3.

Step 5: Plot the consistency as a function of time

To plot the consistency as a function of time, you can create a table with time intervals and calculate the consistency at each interval using the formula calculated in step 4. Then, plot the time intervals on the x-axis and the consistency values on the y-axis.

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The highest temperature recorded in the same city during the past year was 304.89 K. What was the temperature in degrees Celsius?

Answers

Final answer:

The temperature of 304.89 Kelvin is equivalent to 31.74°C when converted using the formula C = K - 273.15.

Explanation:

The student has asked about converting the highest temperature recorded in a certain city from Kelvin to degrees Celsius. The formula for converting Kelvin to Celsius is: C = K - 273.15, where C is the temperature in Celsius and K is the temperature in Kelvin. Applying this formula to the given temperature (304.89 K), we get:

C = 304.89 K - 273.15

C = 31.74°C

Hence, the temperature of 304.89 K is equivalent to 31.74°C.

A technician tares a 100.0 mL volumetric flask at 150.00 g. After adding sodium chloride to the flask it then weighs 158.84 g. Assuming an error of 0.2 mL in the volumetric volume and 0.005 g in the weight, calculate the molar concentration of sodium chloride and its associated standard deviation.

Answers

Final answer:

To find the molar concentration of NaCl, subtract the tare weight from the total weight to get the mass of NaCl, calculate moles of NaCl, and divide by the solution volume. To estimate the standard deviation, propagate the errors from the mass and volume measurements according to the rules of error propagation. Specific numerical values for the standard deviation cannot be provided without exact formulas.

Explanation:

The question pertains to calculating the molar concentration of sodium chloride (NaCl) in a solution, and its associated standard deviation, given certain experimental measurements and potential error margins. First, the mass of NaCl added to the solution is found by subtracting the tare weight of the volumetric flask from the total weight after NaCl was added, yielding 8.84 g of NaCl. The molecular weight of NaCl is 58.44 g/mol, which allows determination of the moles of NaCl present.

To find the molar concentration, divide the moles of NaCl by the volume of the solution in liters (assuming the 100.0 mL flask volume as ideal, the error in volume would be considered in calculating the standard deviation, not the concentration itself). Then, to address the error margins, propagate the errors from the mass and volume measurements to estimate the standard deviation of the calculated concentration.

Note: Without specific formulas for error propagation and the exact calculation method for standard deviation provided in the question, a detailed numerical solution including the standard deviation calculation cannot be accurately presented. However, this process typically involves the square root of the sum of squared fractional uncertainties of the measurements involved.

Name two "Storage Polysaccharides" and two "Structural Polysaccharides"

Answers

Answer:

Examples of storage polysaccharides - starch and glycogen and structural polysaccharides - cellulose and chitin

Explanation:

Polysaccharides are the complex carbohydrate polymers, composed of monosaccharide units that are joined together by glycosidic bond.

In other words, polysaccharides are the carbohydrate molecules that give monosaccharides or oligosaccharides on hydrolysis.

The examples of storage polysaccharides are starch and glycogen. The examples of structural polysaccharides are cellulose and chitin.

write and the integrated rate laws hor zeroth-first- second-order rate laws.

Answers

Explanation:

The integrated rate law for the zeroth order reaction is:

[tex][A]=-kt+[A]_0[/tex]

The integrated rate law for the first order reaction is:

[tex][A]=[A]_0e^{-kt}[/tex]

The integrated rate law for the second order reaction is:

[tex]\frac{1}{[A]}=kt+\frac{1}{[A]_0}[/tex]

Where,

[tex][A][/tex] is the active concentration of A at time t

[tex][A]_0[/tex] is the active initial concentration of A

t is the time

k is the rate constant

Answer:

- 0th: [tex]C_A=C_{A0}-kt[/tex]

- 1st: [tex]C_A=C_{A0}exp(-kt)[/tex]

- 2nd: [tex]\frac{1}{C_A}=kt+\frac{1}{C_{A0}}[/tex]

Explanation:

Hello,

For the ideal reaction A→B:

- Zeroth order rate law: in this case, we assume that the concentration of the reactants is not included in the rate law, therefore the integrated rate law is:

[tex]\frac{dC_A}{dt}=-k\\ \int\limits^{C_A}_{C_{A0}} {} \ dC_A= \int\limits^{t}_{0} {-k} \ dt\\C_A-C_{A0}=-kt\\C_A=C_{A0}-kt[/tex]

- First order rate law: in this case, we assume that the concentration of the reactant is included lineally in the rate law, therefore the integrated rate law is:

[tex]\frac{dC_A}{dt}=-kC_A\\ \int\limits^{C_A}_{C_{A0}} {\frac{1}{C_A} } \ dC_A= \int\limits^{t}_{0} {-k} \ dt\\ln(\frac{C_{A}}{C_{A0}} )=-kt\\C_A=C_{A0}exp(-kt)[/tex]

- Second order rate law: in this case, we assume that the concentration of the reactant is squared in the rate law, therefore the integrated rate law is

[tex]\frac{dC_A}{dt}=-kC_A^{2} \\ \int\limits^{C_A}_{C_{A0}} {\frac{1}{C_A^{2} } } \ dC_A= \int\limits^{t}_{0} {-k} \ dt\\-\frac{1}{C_A}+\frac{1}{C_{A0}}=-kt\\\frac{1}{C_A}=kt+\frac{1}{C_{A0}}[/tex]

Best regards.

Calculate: (a) the weight (in lbf) of a 30.0 lbm object. (b) the mass in kg of an object that weighs 44N. (c) the weight in dynes of a 15-ton object (not metric tons)

Answers

Answer:

a) 965,1 lbf

b) 4,5 kg

c) 1,33 * 10^6 dynes

Explanation:

Mass of an object refers to the amount of mattter it cotains, it can be expressed it gr, kg, lbm, ton, etc.

Weight of an object refers to a force, and is the measurement of the pull of gravitiy on an object. It may be definide as the mass times the acceleration of gravity.

                                        w=mg

In Planet Earth, the nominal "average" value for gravity is 9,8 m/s² (in the International  System) or 32,17 ft/s² (in the FPS system).

To solve this problem we'll use the following conversion factors:

1 lbf = 1 lbm*ft/s²

1 N = 1 kg*m/s²

1 dyne = 1 gr*cm/s²   and 1 N =10^5 dynes

1 ton = 907,18 kg

1 k = 1000 gr

a) m = 30 lbm

[tex]w = 30 lbm * 32,17 ft/s^{2} = 965, 1 \frac{lmb*ft}{s^{2} } = 965,1 lbf[/tex]

b) w = 44 N

First, we clear m of the weight equation and then we replace our data.

[tex]m = \frac{w}{g} = \frac{44 N}{9,8 \frac{m}{{s}^{2}} } = 4,5 kg[/tex]

c) m = 15 ton

[tex]m=15 ton * \frac{907,18 kg}{1 ton} = 13607,7 kg \\ w = mg = 13607,7 kg * 9,8 m/s2 = 133355,5 N * \frac{10^{5} dynes }{1 N} = 1,33 * 10^{6}dynes [/tex]

Final answer:

The weight of a 30 lbm object is 966 lbf. The mass of an object weighing 44N is 4.49 kg. And, the weight of a 15-ton object is 1.34 x 10¹² dynes.

Explanation:

To Calculate: (a) the weight (in lbf) of a 30.0 lbm object we need to use the fact that 1 lbm equals 32.2 lb force (lbf). Therefore, a 30.0 lbm object weight would be 30 lbm * 32.2 = 966 lbf.

In (b), the mass in kg of an object that weighs 44N can be calculated by dividing the weight by Earth's gravity (approximately 9.8m/s²). 44N / 9.8m/s² = 4.49 kg.

Lastly, in (c), to find the weight in dynes of a 15-ton object we first convert the weight to pounds since 1 ton equals 2000 lbs. Then we convert pounds to Newtons (1 lb = 4.44822 N) and finally Newtons to dynes (1 N = 1,000,000 dynes). So, 15 ton * 2000 = 30000lb * 4.44822 N/lb * 1,000,000 dynes/N = 1.34 x 10¹² dynes.

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To find the formula of a compound composed of iron and carbon monoxide, Fex(CO)y, the compound is burned in pure oxygen, an reaction that proceeds according to the following unbalanced equation.

Fex(CO)y + O2 --> Fe2O3 + CO2

If you burn 1.959 g. of Fex(CO)y and obtain 0.799 g. of Fe2O3 and 2.200 g. of CO2, what is the empirical formula of Fex(CO)y?

Answers

Answer:

The empirical formula is: Fe(CO)₅

Explanation:

According the global reaction:

Feₓ(CO)y + O₂ → Fe₂O₃ + CO₂

You should calculate Fe₂O₃ and CO₂ moles, thus:

0,799 Fe₂O₃ grams  × [tex]\frac{1 mole}{159.69 Fe2O3 g}[/tex] = 5,00×10⁻³ Fe₂O₃ moles

2,200 CO₂ grams  × [tex]\frac{1 mole}{44,01 CO2 g}[/tex] = 5,00×10⁻²CO₂ moles

The ratio between Fe₂O₃ moles and CO₂ moles is 1:10. Thus ratio between x and y must be 1:5 because Fe₂O₃ has 2 irons but CO₂ has just one carbon.

Assuming the formula is Fe₁(CO)₅ the molecular weight is 195,9 g/mol. Thus:

1,959 Fe(CO)₅ grams  × [tex]\frac{1 mole}{195,9 Fe(CO)5 g}[/tex] = 1,00×10⁻² Fe(CO)₅ moles

Thus, assuming 1,00×10⁻² moles as basis for calculation, the global reaction is:

1 Fe(CO)₅ + ¹³/₂O₂ → ¹/₂ Fe₂O₃ + 5 CO₂

With this balanced equation the moles produced have sense, thus, the empirical formula is: Fe(CO)₅

I hope it helps!

Final answer:

The empirical formula of the compound Fex(CO)y, formed from 1.959 g of the substance producing 0.799 g of Fe²O³ and 2.200 g of CO², is Fe(CO)⁵.

Explanation:

To determine the empirical formula of the compound Fex(CO)y, we must first find the moles of iron (Fe) and carbon monoxide (CO) in the compound. Given that 0.799 g of Fe²O³ and 2.200 g of CO² were produced, we can calculate the number of moles of Fe and C using their molar masses (Fe: 55.85 g/mol, C: 12.01 g/mol, O: 16.00 g/mol).

From Fe²O³, the mass of Fe is 0.799 g x (2 mol Fe / 159.69 g Fe²O³) = 0.0100 mol Fe.
From CO², the mass of C is 2.200 g x (1 mol C / 44.01 g CO²) = 0.0500 mol C.

To find the mole ratio, we use the smallest number of moles as a divisor. Here, it is 0.0100 mol Fe. The ratio of Fe to C in the compound is 0.0100 mol Fe / 0.0100 mol = 1 Fe to 0.0500 mol C / 0.0100 mol = 5 CO.

Therefore, the empirical formula of the compound is Fe(CO)5.

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Konvert the following temperatures from °F to PC: Ta 86°F, (b) -22°F, (C) 50°F, (d) -40°F, (e) 32°F, (f) -459.67°F. Convert each temperature to K.

Answers

Answer:

The answers are:

a) 30°C; 303.15K

b) -30°C; 243.15K

c) 50°C; 323.15K

d) -40°C; 233.15K

e) 0°C; 273.15K

f) -273.15 °C ; 0K

Explanation:

To convert the temperature from ° F to ° C we use the following expression:

[tex]C=(F-32)\frac{5}{9}[/tex]

where C es temperature en °C and F is temperature in °F

To obtain the temperature in K we need to add 273.15 to each Celcius temperature

[tex]K=C+273.15[/tex]

Two solutions of sodium acetate are prepared, one having a concentration of 0.1 M and the other having a concentration of 0.01 M. Calculate the pH values when the following concentrations of HCl have been added to each of these solutions: 0.0025 M, 0.005 M, 0.01 M, and 0.05 M.

Answers

Answer:

For 0.1 M sodium acetate solution

if concentration of acid is 0.0025 then pH will  6.075

if concentration of acid is 0.005 then pH will  5.775

if concentration of acid is 0.01 then pH will  5.475

if concentration of acid is 0.05 then pH will  4.775

For 0.01 M sodium acetate solution

if concentration of acid is 0.0025 then pH will  5.075

if concentration of acid is 0.005 then pH will  4.775

if concentration of acid is 0.01 then pH will  4.475

if concentration of acid is 0.05 then pH will  3.775

Explanation:

to calculate the pH of a buffer solution we use the following formula

pH = pKa + log [B]/[A] ------------- eq (1)

[B] = concentration of base

[A] = concentration of acid

Given data

[B] = 0.1 M , 0.01M

[A] = 0.0025 M , 0.005 M, 0.01 M, 0.05 M

pKa value for sodium acetate is 4.75

1. First we will calculate the pH values for 0.1 M acetate solution.

If the concentration of acid is 0.0025, then:

[B] = 0.1 M

[A] = 0.0025 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.1]/[0.0025]

pH = 4.75 + log [40]

pH = 4.475 + 1.6

pH = 6.075

If the concentration of acid is 0.005 M, then:

[B] = 0.1 M

[A] = 0.005 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.1]/[0.005]

pH = 4.75 + log [20]

pH = 4.475 + 1.3

pH = 5.775

If the concentration of acid is 0.01, then:

[B] = 0.1 M

[A] = 0.01 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.1]/[0.01]

pH = 4.75 + log [10]

pH = 4.475 + 1

pH = 5.475

If the concentration of acid is 0.05, then:

[B] = 0.1 M

[A] = 0.05 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.1]/[0.05]

pH = 4.75 + log [2]

pH = 4.475 + 0.3

pH = 4.775

2. Now we will calculate the pH values for 0.01 M acetate solution.

If the concentration of acid is 0.0025, then:

[B] = 0.01 M

[A] = 0.0025 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.01]/[0.0025]

pH = 4.75 + log [4]

pH = 4.475 + 0.6

pH = 5.075

If the concentration of acid is 0.005 M, then:

[B] = 0.01 M

[A] = 0.005 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.01]/[0.005]

pH = 4.75 + log [2]

pH = 4.475 + 0.3

pH = 4.775

If the concentration of acid is 0.01 M, then:

[B] = 0.01 M

[A] = 0.01 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.01]/[0.01]

pH = 4.75 + log [1]

pH = 4.475 + 0

pH = 4.475

If the concentration of acid is 0.05 M, then:

[B] = 0.01 M

[A] = 0.05 M

put these values in eq 1. which is:

pH = pKa + log [B]/[A]

pH = 4.75 + log [0.01]/[0.05]

pH = 4.75 + log [0.2]

pH = 4.475 + (-0.7)

pH = 4.475 - 0.7

pH = 3.775

Answer:

a) pH = 4.71

b) pH = 4.704

c) pH = 4.57

d) No buffer here, the pH will be between 2-3

Explanation:

Applying Henderson Hasselbach equation:

pH = pKa + log([A]/[HA])

a) For 0.0025 M:

[A] = 0.1/2 = 0.05 M

[HA] = 0.05 M

After add 0.0025 M of acid:

[A] = 0.05 - 0.0025 = 0.0475 M

[HA] = 0.05 + 0.0025 = 0.0525 M

[tex]pH=4.75+log(\frac{0.0475}{0.0525} )=4.71[/tex]

b) For 0.005 M:

[A] = 0.1/2 = 0.05 M

[HA] = 0.05 M

After add 0.005 M of acid:

[A] = 0.05 - 0.005 = 0.0495 M

[HA] = 0.05 + 0.005 = 0.055 M

[tex]pH=4.75+log(\frac{0.0495}{0.055} )=4.704[/tex]

c) For 0.01 M:

[A] = 0.1/2 = 0.05 M

[HA] = 0.05 M

After add 0.01 M of acid:

[A] = 0.05 - 0.01 = 0.04 M

[HA] = 0.05 + 0.01 = 0.06 M

[tex]pH=4.75+log(\frac{0.04}{0.06} )=4.57[/tex]

d) For 0.05 M:

[A] = 0.1/2 = 0.05 M

[HA] = 0.05 M

After add 0.05 M of acid:

[A] = 0.05 - 0.05 = 0

[HA] = 0.05 + 0.05 = 0.1 M

No buffer here, the pH will be between 2-3

What are the names of the following compounds: FeCl HNO NaSO SO

Answers

Answer:

FeCl: Ferric Chloride (also called iron chloride), comes from Fe (ferrum, or iron), and Cl (Chlorine)

HNO: Nitroxyl, from N (Nitrogen), and the acidic nature of a radical ending in -yl.

NaSO:  Sodium sulfate, Na (Sodium), S (Sulfur), O (Oxygen).

SO: Sulfur monoxide (Mono-One), O (Oxygen) and S (Sulfur).

Find the percent by mass of tin in the original sample, assuming that it contains no other reducing agents. A sample of impure tin of mass 0.528 g is dissolved in strong acid to give a solution of Sn2+. The solution is then titrated with a 0.0448 M solution of NO3−, which is reduced to NO(g). The equivalence point is reached upon the addition of 4.03×10−2 L of the NO3− solution.

Answers

Final answer:

To find the mass percent of chloride in the original dry sample, you can use the formula: Mass percent of chloride = (mass of chloride / mass of original sample) x 100%. Use the volume of AgNO3 solution used in the titration, the solution's molarity, and the molar mass of chloride to calculate the mass of chloride.

Explanation:

The percent by mass of chloride in the original dry sample can be calculated using the following formula:

Mass percent of chloride = (mass of chloride / mass of original sample) x 100%

In this case, the mass of chloride can be determined by multiplying the volume of AgNO3 solution used in the titration (28 mL) by the molarity of the solution (0.1 M) and the molar mass of chloride (35.453 g/mol).

Then, using the mass of chloride and the mass of the original sample (0.200 g), the percent by mass of chloride in the original dry sample can be calculated.

A 36.5 lb child has a Streptococcus infection. Amoxicillin is prescribed at a dosage of 25 mg per kg of body weight b.id What is the meaning of the Latin abbreviation b.i.d.? O every other day O as needed O twice daily O once daily How many hours should pass between each administration? number of hours: 413 How many milligrams of amoxicillin should be given at each administration? mass of amoxicillin: 413 Amoxicillin should be stored between 0 °C and 20 °C. Should the amoxicillin be stored in the freezer or the refrigerator?

Answers

Answer:

a) b.i.d: twice daily.

b) 12 hour between each administration.

c) mg amoxicilin/administration = 413.9 mg/administration.

d) should be stored in the refrigerator

Explanation:

mass child = 36.5 Lb * ( 453.592 g/Lb ) =  16556.11 g = 16.556 Kgdosage: 25mg/kg body b.i.d.

∴ b.i.d. : refer to twice a day; so 12 hours will pass between each administration of the medication.

⇒ mg amoxicilin/administration = 25 mg/ kg * 16.556 Kg = 413.9 mg amoxicilin.

Amoxicillin should be stored in the refrigerator, since in this section the temperature is kept within the storage range

Green plants use light from the Sun to drive photosynthesis, a chemical reaction in which liquid water and carbon dioxide gas from aqueous glucose and oxygen gas. Calculate the moles of glucose produced by the reaction of 2.40 moles of water. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.

Answers

Answer: 0.4 moles of glucose are produced by the reaction of 2.40 moles of water.

Explanation:

Photosynthesis is a phenomenon in which green plants containing chlorophyll use sunlight as a source of energy to convert carbon dioxide and water to form glucose and oxygen.

The balanced chemical equation is:

[tex]6CO_2+6H_2O\overset{sunlight}\rightarrow C_6H_{12}O_6+6O_2[/tex]

According to stoichiometry:

6 moles of water produces = 1 mole of glucose

2.40 moles of water produces = [tex]\frac{1}{6}\times 2.4=0.4[/tex] moles of glucose

Thus 0.4 moles of glucose are produced by the reaction of 2.40 moles of water.

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