The thiocyanate polyatomic ion, SCN-, is commanly called a pseudohalogen because it acts very much like halide ions. For example, we know that pure halogens consists of diatiomic molecules, such as C12. Thiocanate ions form similar molecules in the following reaction2NaSCN +2H2SO4 + MnO2 -> (SCN)2 + 2H2O + MnSO4 + Na2SO4A) Write a conversion factor that could be used to convert between moles of NaSCN and moles of (SCN)2B) How many moles of (SCN)2 form when 0.05 moles of NaSCN react completely?C) What is the maximum number of moles of (SCN)2 that could form in the combination of 4 moles of NaSCN and 3 moles of MnSO4?D) Write a convertion factor that could be used to convert between moles of sulfuric acid, H2SO4 and moles manganese (II) sulfate, MnSO4.E) What is the minimum number of moles of H2SO4 that must react to form 1.7752 moles of manganese (II) sulfate?

Answer:

2- propanol treated with metal base NaH followed by hydrogen bromide to form 2- propoxypropane.

Explanation:

Formation of secondary halide:

Firstly propene reacts with sulfuric acid or water to form 2- Propanol.

Formation of primary halide:

Also, according to the Anti markovinikov rule propene undergoes addition to the hydrogen bromide in the presence of peroxide to form 1- bromopropane.

The secondary halide i.e,  2- propanol treated with metal base NaH to form  sodium isopropoxide. Further treated with hydrogen bromide to form 2- Propoxypropane. This reaction follows [tex]S_{N}2[/tex] mechanism.

The overall reaction is as follows.

The preferred pathway for the synthesis of 2-propoxypropane from propene in the Williamson synthesis involves the reaction of propene with an alkyl halide and an alkoxide ion.

The preferred pathway for the synthesis of 2-propoxypropane from propene in the Williamson synthesis involves the reaction of propene with an alkyl halide and an alkoxide ion. The alkoxide ion is formed by treating an alcohol with a strong base, such as sodium hydride (NaH). The alkyl halide is then added to the alkoxide ion, resulting in the formation of the desired product, 2-propoxypropane.

Alcohol + Strong Base (NaH) → Alkoxide Ion

Alkoxide Ion + Alkyl Halide → 2-Propoxypropane

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Answer:

The entropy decreases.

Explanation:

The change in the standard entropy of a reaction (ΔS°rxn) is related to the change in the number of gaseous moles (Δngas), where

Δngas = n(gaseous products) - n(gaseous reactants)

Let's consider the following reaction.

2 H₂(g) + O₂(g) ⟶ 2 H₂O(l)

Δngas = 0 - 3 = -3, so the entropy decreases.

Answer:

40%

Explanation:

The efficiency of a plant is determined by

[tex]eff=\frac{E_{produced}}{E_{in}}[/tex]

Our produced energy is

[tex]500 \ MW[/tex]

While the input energy can be calculated

[tex]E_{in}=number\ of \ coal \ in \ * energy\ per\ coal\ unit\\ =\frac{225000}{3600}coal/ s\ *20\ MJ/coal\\ = 1250\ MW[/tex]

So, the efficiency of plant is

[tex]eff=\frac{500}{1250}}\\ 0.4[/tex]

or 40% efficient

Final answer:

The efficiency of the coal-burning power plant in question is 40%, calculated by comparing the electrical energy output to the energy input from burning coal.

Explanation:

To determine the efficiency of the coal-burning power plant, we compare the energy output in the form of electricity to the energy input from burning coal. First, calculate the total energy input per hour by multiplying the amount of coal burned by the average energy content of the coal. Then, convert the electrical energy output from megawatts to joules per hour. Finally, calculate efficiency using the formula: Efficiency (%) = (Energy output / Energy input) × 100.

Here are the calculations:

Thus, the efficiency of the power plant is 40%.

Answer:

ΔH of solution is expected to be close to zero.

Explanation:

When we mix two non polar organic liquids like hexane and heptane,the resulting mixture formed is an ideal solution.An ideal solution is formed when the force of attraction between the molecules of the two liquids is equal to the force of attraction between the molecules of the same type.

For instance if liquids A and B are mixed,

[tex]F_{A-A}[/tex] = [tex]F_{B-B}[/tex] = [tex]F_{A-B}[/tex]

Hence the condition before and after mixing remains unchanged.

Since enthalpy change is associated with inter molecular force of attraction the enthalpy change for ideal solution is zero.

More examples of ideal solutions are:

1. Ethanol and Methanol

2. Benzene and Toluene

3. Ethyl bromide and Ethyl iodide

Answer:

1) The mass of water lost = 7.7892 grams

2) Z = 3: Cu(NO3)2*3H2O

Explanation:

Step 1: Data given

Mass of copper (II) nitrate hydrate, Cu(NO3)2•zH2O = 34.8243 grams

Mass of substance after heating = 27.0351 grams

Molar mass of Cu(NO3)2 = 187.56 g/mol

Molar mass of H2O = 18.02 g/mol

Step 2: Calculate mass of water

The mass of water is the mass lost after heating.

Mass water = 34.8243 - 27.0351 = 7.7892 grams of water

Step 3: Calculate moles of Cu(NO3)2

Moles Cu(NO3)2 = Mass Cu(NO3)2 / Molar mass Cu(NO3)2

Moles Cu(NO3)2 = 27.0351 grams / 187.56 g/mol

Moles Cu(NO3)2 = 0.144 moles

Step 4: Calculate moles of H2O

Moles H2O = 7.7892 grams / 18.02 g/mol

Moles H2O = 0.432 moles

Step 5: Calculate Z

z = moles H2O / moles Cu(NO3)2

Z = 0.432/0.144

Z = 3

This means we have 3 water molecules in the formula. This makes the formula ofthe hydrate: Cu(NO3)2*3H2O

Final answer:

To find the percent water in the hydrate, subtract the final mass after heating from the initial mass of the hydrate, then divide by the initial mass and multiply by 100. The mass of water lost is 7.7892g, and the percent water is 22.36%. To determine the value of z, calculate the moles of water and anhydrous Cu(NO3)2 to find z equals 3, making the formula Cu(NO3)2•3H2O.

Explanation:

The question involves determining the percent water in a hydrate, the mass of water lost during heating, and the value of z in the formula Cu(NO3)2•zH2O. Firstly, to calculate the mass of water lost, subtract the final mass after heating from the initial mass of the copper (II) nitrate hydrate. Then, to find the percent water, the mass of water lost is divided by the initial mass of the hydrate, multiplied by 100. Lastly, to determine the value of z, the moles of water lost are divided by the moles of anhydrous Cu(NO3)2.

To calculate the mass of water lost: 34.8243g (initial mass) - 27.0351g (final mass) = 7.7892g (mass of water lost).

To calculate the percent water in the hydrate: (7.7892g / 34.8243g) x 100 = 22.36%.

To find z, the number of waters, you need the molar mass of Cu(NO3)2 and H2O. Assume the molar mass of Cu(NO3)2 is approximately 187.55 g/mol. The mass of Cu(NO3)2 after heating is 27.0351g, which corresponds to 27.0351g / 187.55g/mol = 0.1441 mol. The moles of water lost is 7.7892g / 18.015g/mol = 0.4323 mol. Hence, z = 0.4323 mol / 0.1441 mol = 3, indicating the formula is Cu(NO3)2•3H2O.

Explanation:

So, we need to break the bonds of liquid substance in order to convert it into vapor state. And, energy is absorbed for breaking of bonds which means that evaporation is an endothermic process.

Hence, the statement evaporation of water is an exothermic process is false.

A combustion reaction will always release heat energy. Hence, combustion reaction is exothermic in nature.

Hence, for an exothermic process value of [tex]\Delta H[/tex] is negative.

Thus, we can conclude that statements which are true are as follows.

Answer:

[tex]\large \boxed{\text{B.) 2.8 atm}}[/tex]

Explanation:

The volume and amount are constant, so we can use Gay-Lussac’s Law:

At constant volume, the pressure exerted by a gas is directly proportional to its temperature.

[tex]\dfrac{p_{1}}{T_{1}} = \dfrac{p_{2}}{T_{2}}[/tex]

Data:

p₁ = 1520 Torr; T₁ =   27 °C

p₂ = ?;               T₂ = 150 °C

Calculations:

(a) Convert the temperatures to kelvins

T₁ = (  27 + 273.15) K = 300.15 K

T₂ = (150 + 273.15) K = 423.15 K

(b) Calculate the new pressure

[tex]\begin{array}{rcl}\dfrac{1520}{300.15} & = & \dfrac{p_{2}}{423.15}\\\\5.064 & = & \dfrac{p_{2}}{423.15}\\\\5.064\times423.15&=&p_{2}\\p_{2} & = & \text{2143 Torr}\end{array}\\[/tex]

(c) Convert the pressure to atmospheres

[tex]p = \text{2143 Torr} \times \dfrac{\text{1 atm}}{\text{760 Torr}} = \textbf{2.8 atm}\\\\\text{The new pressure reading will be $\large \boxed{\textbf{2.8 atm}}$}[/tex]

Answer:

The minimum mass of acetaminophen that the new system must be able to detect is 0.02 milligrams.

Explanation:

Range of the equipment to detect acetaminophen in blood = 10.0  to 30.0 μg/mL

Minimum amount of acetaminophen that can be detected= 10.0 μg/mL

Volume of blood sample = 2 mL

Amount of acetaminophen in 2 ml sample of blood =

[tex]2 mL\times 10.0 \mu g/mL=20.0 \mu g[/tex]

20.0 μg = 0.02 mg (1 μg = 0.001 mg)

The minimum mass of acetaminophen that the new system must be able to detect is 0.02 milligrams.

Answer : The correct expression will be:

[tex]K=(K_1)^2\times K_2[/tex]

Explanation :

The chemical reactions are :

(1) [tex]\frac{1}{2}N_2(g)+\frac{1}{2}O_2(g)\rightleftharpoons NO(g)[/tex] [tex]K_1[/tex]

(2) [tex]2NO(g)+O_2(g)\rightleftharpoons N_2O_4(g)[/tex] [tex]K_2[/tex]

The final chemical reaction is :

[tex]N_2(g)+2O_2(g)\rightleftharpoons N_2O_4[/tex] [tex]K=?[/tex]

Now we have to calculate the value of [tex]K[/tex] for the final reaction.

Now equation 1 is multiply by 2 and then add both the reaction we get the value of 'K'.

If the equation is multiplied by a factor of '2', the equilibrium constant will be the square of the equilibrium constant of initial reaction.

If the two equations are added then equilibrium constant will be multiplied.

Thus, the value of 'K' will be:

[tex]K=(K_1)^2\times K_2[/tex]

Answer:

A. Limiting reactant is A.

B. Limiting reactant is A.

C. Limiting reactant is B.

D. Limiting reactant is B.

Explanation:

It is possible to find the limiting reactant for a reaction taking the moles of a reactant that will react and using the chemical equation find the moles of the other reactant you will need.

For the reaction:

2A + 4B → 3C

A. 2 moles A requires:

2molA×[tex]\frac{4molB}{2molA}[/tex]= 4moles of B

As you have 5 moles of B, limiting reactant is A.

B. 1,8 moles A requires:

1,8 molA×[tex]\frac{4molB}{2molA}[/tex]= 3,6 moles of B

As you have 4 moles of B, limiting reactant is A.

C. 3 moles A requires:

3 molA×[tex]\frac{4molB}{2molA}[/tex]= 6 moles of B

As you have just 4 moles of B, limiting reactant is B.

D. 22 moles A requires:

22 molA×[tex]\frac{4molB}{2molA}[/tex]= 44moles of B

As you have just 40 moles of B, limiting reactant is B.

I hope it helps!

For each scenario, the limiting reactant is determined by comparing the moles used according to the stoichiometry of the reaction. In Parts A, B, and D, A is the limiting reactant; in Part C, B is limiting.

To determine the limiting reactant, compare the moles of each reactant to the stoichiometric coefficients in the balanced equation (2A + 4B → 3C).

1. Part A (2 mol A; 5 mol B):

  - Moles of A used = 2 (coefficient in front of A)

  - Moles of B used = [tex]\frac{5}{2}[/tex] (coefficient in front of B divided by 2)

  - Since Moles of B used > Moles of A used, A is the limiting reactant.

2. Part B (1.8 mol A; 4 mol B):

  - Moles of A used = 1.8 (coefficient in front of A)

  - Moles of B used = [tex]\frac{4}{4}[/tex] (coefficient in front of B divided by 4)

  - Since Moles of A used < Moles of B used, A is the limiting reactant.

3. Part C (3 mol A; 4 mol B):

  - Moles of A used = 3 (coefficient in front of A)

  - Moles of B used = [tex]\frac{4}{2}[/tex] (coefficient in front of B divided by 2)

  - Since Moles of B used < Moles of A used, B is the limiting reactant.

4. Part D (22 mol A; 40 mol B):

  - [tex]\( \text{Moles of A used} = \frac{22}{2} \)[/tex] (coefficient in front of A divided by 2)

  - Moles of B used = 40 (coefficient in front of B)

  - Since Moles of A used < Moles of B used, A is the limiting reactant.

In summary:

- Part A: Limiting reactant is A.

- Part B: Limiting reactant is A.

- Part C: Limiting reactant is B.

- Part D: Limiting reactant is A.

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Answer:

a. 5Cl₂ + 10e⁻  → 10Cl⁻

b. 4H₂O + Mn²⁺ → MnO₄⁻ + 5e⁻ + 8H⁺

Explanation:

5Cl2(g)+2Mn+2(aq)+8H2O(l)→ 10Cl−(aq)+2MnO4-(aq)+16H+(aq)

First of all, think in all the oxidation numbers for each compound. That's the way, you can notice the half reaction.

When the oxidation number, decrease, you have reduction. Compound is wining electrons.

When the oxidation number increase, you have oxidation. Compound is losing electrons.

Cl2(g) - Atoms in ground state, has 0 as oxidation number. In products side, you have the anion chloride which act with -1, so chlorine has been reduced.

Mn2+ - The manganese ion is already telling you with 2, that is its oxidation number. On the side products, the element was transformed into the permanganate anion; how oxygen acts with -2 and there are 4 atoms, it has -8 as oxidation state but since the general charge is -1 the Mn is acting with +7.  From + 2 it went to +7, which means that it increased, so it has oxidized.

5Cl₂ + 10e⁻  → 10Cl⁻  - REDUCTION

The chlorine had to gain 1 electron to go from 0 to -1, but being a diatomic molecule were 2 electrons, but finally so that the charges are balanced and because there are 5 moles, it ends up gaining 10 electrons.

Mn²⁺ → MnO₄⁻ - OXIDATION

Look that in main reaction we have H⁺, that is the clue to notice us, that we are in acidic medium. So if we have 4 O, in MnO₄⁻, we have to complete with 4H₂O in the other side of O. And to ballance the protons, we have to add 8H⁺ in product side

4H₂O + Mn²⁺ → MnO₄⁻ + 5e⁻ + 8H⁺ OXIDATION

How do u finish this?. You have to multipply .2, the oxidation one to balance the e⁻ so, they can be cancelled.

5Cl₂ + 10e⁻  → 10Cl⁻

(4H₂O + Mn²⁺ → MnO₄⁻ + 5e⁻ + 8H⁺ ).2

8H₂O + 2Mn²⁺ → 2MnO₄⁻ + 10e⁻ + 16H⁺

5Cl₂ + 10e⁻ + 8H₂O + 2Mn²⁺ → 10Cl⁻ + 2MnO₄⁻ + 10e⁻ + 16H⁺

5Cl₂  + 8H₂O + 2Mn²⁺ → 10Cl⁻ + 2MnO₄⁻  + 16H⁺

The half-reactions for the given redox reaction includes the reduction of Mn2+(aq) to MnO4-(aq) with the addition of 5 electrons and 8 hydrogen ions and the oxidation of Cl2(g) to 10 Cl-(aq), losing 10 electrons in the process.

The redox reaction is related to the process of reduction and oxidation which often takes place in electrochemical cells. This process includes half-reactions, which separately represent the oxidation and reduction in the redox reaction. For the given equation, the oxidation and reduction half-reactions are as follows:

a. Reduction: Mn2+(aq) + 5e- + 8H+(aq) → MnO4-(aq) + 4H2O(l).

b. Oxidation: Cl2(g) → 10e- + 10Cl-(aq).

These equations represent the transformation of Mn2+ and Cl2 in the given redox reaction where Mn2+ is being reduced and Cl2 is being oxidized.

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A system that is giving off 65.0 kJ of heat and is performing 855 J of work on the surroundings has a change in the internal energy of -65.9 kJ.

According to the First Law of Thermodynamics, we can calculate the change in the internal energy (ΔE) of the system using the following expression.

[tex]\Delta E = Q + W = (-65.0 kJ) + (-0.855 kJ) = -65.9 kJ[/tex]

A system that is giving off 65.0 kJ of heat and is performing 855 J of work on the surroundings has a change in the internal energy of -65.9 kJ.

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Answer:

67

Explanation:

Question 1: The solution at 75 degrees Celsius was likely saturated.

Question 2: The reason for choosing "saturated" is that the sugar was completely dissolved in water at 75 degrees Celsius, forming a clear and colorless solution.

In a saturated solution, the maximum amount of solute (sugar, in this case) that can dissolve at that temperature has already dissolved. When the solution is clear and colorless at that temperature, it suggests that the solution contains as much sugar as it can hold under those conditions.

If it were unsaturated, there would still be room for more sugar to dissolve, and if it were supersaturated, it would become unstable and potentially precipitate out excess solute when the temperature was lowered.

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Answer:

Theoretical yield = 3.51 g

Explanation:

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

For [tex]CH_4[/tex]  :-

Mass of [tex]CH_4[/tex]  = 1.28 g

Molar mass of [tex]CH_4[/tex]  = 16.04 g/mol

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

Thus,

[tex]Moles= \frac{1.28\ g}{16.04\ g/mol}[/tex]

[tex]Moles_{CH_4}= 0.0798\ mol[/tex]

For [tex]O_2[/tex]  :-

Mass of [tex]O_2[/tex]  = 10.1 g

Molar mass of [tex]O_2[/tex]  = 31.998 g/mol

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

Thus,

[tex]Moles= \frac{10.1\ g}{31.998\ g/mol}[/tex]

[tex]Moles_{O_2}= 0.3156\ mol[/tex]

According to the given reaction:

[tex]CH_4+2O_2\rightarrow CO_2+2H_2O[/tex]

1 mole of methane gas reacts with 2 moles of oxygen gas

0.0798 mole of methane gas reacts with 2*0.0798 moles of oxygen gas

Moles of oxygen gas = 0.1596 moles

Available moles of oxygen gas = 0.3156 moles

Limiting reagent is the one which is present in small amount. Thus, [tex]CH_4[/tex] is limiting reagent.

The formation of the product is governed by the limiting reagent. So,

1 mole of methane gas on reaction produces 1 mole of carbon dioxide.

0.0798 mole of methane gas on reaction produces 0.0798 mole of carbon dioxide.

Mole of carbon dioxide = 0.0798 mole

Molar mass of carbon dioxide = 44.01 g/mol

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

Thus,

[tex]0.0798\ moles= \frac{Mass}{44.01\ g/mol}[/tex]

Mass of [tex]CO_2[/tex] = 3.51 g

Theoretical yield = 3.51 g

The theoretical yield of carbon dioxide formed from the reaction of 1.28 g of methane and 10.1 g of oxygen gas is 3.51 g.

The balanced equation for the reaction between methane (CH4) and oxygen gas (O2) to produce carbon dioxide (CO2) and water (H2O) is:

CH4 + 2O2 → CO2 + 2H2O

To find the theoretical yield of carbon dioxide, we need to calculate the moles of methane and oxygen and use the stoichiometry of the balanced equation.

Given: Mass of methane (CH4) = 1.28 g

Mass of oxygen gas (O2) = 10.1 g

Step 1: Calculate the moles of methane and oxygen using their molar masses:

Moles of CH4 = mass / molar mass = 1.28 g / 16.04 g/mol = 0.0798 mol

Moles of O2 = mass / molar mass = 10.1 g / 32.00 g/mol = 0.3156 mol

Step 2: Determine the limiting reactant (the reactant that is completely consumed first) by comparing the mole ratios of CH4 and O2 in the balanced equation. From the equation, for every 1 mol of CH4 there are 2 moles of O2 needed. Therefore, the mole ratio of CH4 to O2 is 1:2.

Since the mole ratio of CH4 to O2 is 1:2, and there are fewer moles of CH4 (0.0798 mol) compared to the moles of O2 (0.3156 mol), CH4 is the limiting reactant.

Step 3: Calculate the moles of CO2 produced using the mole ratio from the balanced equation:

Moles of CO2 = moles of CH4 x (1 mol of CO2 / 1 mol of CH4) = 0.0798 mol x (1 mol / 1 mol) = 0.0798 mol

Step 4: Convert the moles of CO2 to grams using the molar mass of CO2:

Mass of CO2 = moles x molar mass = 0.0798 mol x 44.01 g/mol = 3.51 g

Therefore, the theoretical yield of carbon dioxide formed from the reaction of 1.28 g of methane and 10.1 g of oxygen gas is 3.51 g (to the correct number of significant digits).

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Answer:

Part-A:

Anode is Nickel and Cathode is copper.

Part -B:

[tex]E^{0}_{cell}[/tex] of the reaction is 0.567V.

Explanation:

Nickel-Copper cell electrodes are "Ni" and "Cu" rod.

Nickel electrode is dipped in [tex]Ni^{+2}[/tex] solution.

Copper electrode dipped in [tex]Cu^{+2}[/tex] solution.

Part -A:

Anode:

At anode oxidation takes place

[tex]Ni(s) \rightarrow Ni^{+2}(aq)+2e^{-}[/tex]

Hence, anode is Nickel.

Cathode:

At cathode reduction takes place.

[tex]Cu^{+2}+2e^{-} \rightarrow Cu(s)[/tex]

Hence, Cathode is copper.

Part-B:

[tex]E^{0}_{cell}=E^{0}_{cathode}-E^{0}_{anode}[/tex]

[tex]=0.337-(-0.230)=0.567V[/tex]

Hence, [tex]E^{0}_{cell}[/tex] of the reaction is 0.567V.

Anodes and cathodes are the electrodes where oxidation and reduction take place.

Electrochemical cells have two electrodes which is called anode and cathode. The anode is the electrode where oxidation occurs while the other hand, cathode is the electrode where reduction takes place so we can conclude that anodes and cathodes are the electrodes where oxidation and reduction take place.

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Answer:

a)

[tex]C(s)+O_{2}(g) \rightarrow CO_{2}(g)[/tex]

[tex]S(s)+O_{2}(g) \rightarrow SO_{2}(g)[/tex]

b)

Sulphurdioxide

c)

[tex]SO_{2}(g) + H_{2}O(l) \rightarrow H_{2}SO_{3}(l)[/tex]

[tex]SO_{2}(g) + \frac{1}{2}O_{2} \rightarrow SO_{3}(g)[/tex]

d)  

Incomplete combustion produce harmful gases.

Explanation:

a)

Carbon reacts with atmospheric oxygen to form carbondioxide as well as sulphur dioxide.

The chemical equations are as follows.

[tex]C(s)+O_{2}(g) \rightarrow CO_{2}(g)[/tex]

[tex]S(s)+O_{2}(g) \rightarrow SO_{2}(g)[/tex]

b)

Sulfur dioxide is very harmful to the environment to cause acid rains.

This harmful gas mix with rain water to form  sulphuric acid.

c)

The balanced chemical equation for the reaction that produces harmful environmental effects is as follows.

[tex]SO_{2}(g) + H_{2}O(l) \rightarrow H_{2}SO_{3}(l)[/tex]

[tex]SO_{2}(g) + \frac{1}{2}O_{2} \rightarrow SO_{3}(g)[/tex]

[tex]SO_{3}(g) +H_{2}O(l) \rightarrow H_{2}SO_{4}(l)[/tex]

d)

In the absence of proper amount of oxygen required for combustion, incomplete combustion will take place which will result in formation of more carbondioxide an other harmful gases.

Answer:

∆H°rxn in kJ/mol AgCl = - 59.61 kJ/mol

Explanation:

To solve this question we need to calculate the heat absorbed by the cup calorimeter and by the water in the solutions. We will also need to calculate the amount in moles produced by the reaction since we want to know the ∆H°rxn in kJ/mol AgCl .

mol AgNO₃ = 100 mL x 1L/1000 mL x 0.100 mol/L = 0.01 mol

mol NaCl = 100 mL x 1L/1000 mL x 0.200 mol/L = 0.02 mol

Therefore our limiting reagent is the 0.01 mol AgNO₃ and 0.01 mol AgCl will be produced according to the stoichiometry of the reaction:

AgNO₃ + NaCl ⇒ AgCl + NaNO₃

Heat absorbed by the water:

qw = m(H₂O) x c x ΔT where  m (H₂O) = 200 g ( the density of final solution is  1  g/ml)

c = specific heat of water = 4.18 J/gºC

ΔT = change in temperature =  (25.30 - 24.60 ) ºC = 0.7ºC

qw = 200 g x 4.18 J/gºC x 0.7 ºC = 585.20 J

Heat Absorbed by the calorimeter :

q cal = C cal x  ΔT  = 15.5 J/ºC x 0.7ºC = 10.85 J

Total Heat released by the combustion = qw + qcal = 585.20 J +10.85 J

=  596.05 J

We have to change the sign to this quantity since it is an exotermic reaction  ( ΔT is positive ) and have the ∆Hrxn

∆H rxn  = -596.05 J  

but this  is not what we are being asked since this heat was released by the formation of  0.0100 mol of AgCl so finally  

∆H°rxn = -596.05 J /0.01 mol  = -59,605 J/mol x 1 kJ/1000J = -59.61 kJ/mol

Answer:

There are 29.4 grams of oxygen in the container

Explanation:

Step 1: Data given

Volume = 20.0 L

Pressure = 845 mmHg

Temperature = 22.0 °C

Molar mass of O2 = 32 g/mol

Step 2: Ideal gas law

p*V = n*R*T

⇒ p = the pressure of the gas = 845 mmHg = 1.11184

⇒ V = the volume of the gas = 20.0 L

⇒ n = the number of moles = TO BE DETERMINED

⇒R = the gasconstant = 0.08206 L*atm/K*mol

⇒ T = the temperature = 22°C + 273 = 295 Kelvin

n = (p*V)/(R*T)

n = (1.11184*20.0)/(0.08206*295)

n = 0.9186 moles

Step 3: Calculate mass of NO2

Mass of O2 = Moles O2 * Molar mass O2

Mass of O2 = 0.9186 moles * 32 g/mol

Mass of O2 = 29.4 grams

There are 29.4 grams of oxygen in the container

Answer:

total mass will be =  = 1.207g

Explanation:

First what is given  

Pressure P= 0.988 atm                  Room TemperatureT = 23.5°C= 296.5 K

Volume V= 1.042 L

Nitrogen in air is 80 % (moles number) = 0.8                

Ideal gas constant R = 0.0821 L atmmol-1K-1

Given mass of N = 14.01 g/mol

Given mass of oxygen O = 16.00 g/mol

Total number of moles = ?

So first we have to find the total number of moles by using formula  

Total number of moles  

n = PV/ RT  

adding the values  

moles n= 0.988atm x 1.042L / (0.0821L-atm/mole-K x 296.6K)  

  = 1.0294 / 24.35

= 0.042 moles (total number of moles)

So by using Nitrogen percentage  

Moles of nitrogen = total moles x 80/100

                            = 0.042moles x 0.8  

So moles of O2= Total moles – moles of N2  

                       =   0.042moles - 0.034moles

    Moles of O2 = 0.008moles

Now for finding the mass of the N2 and oxygen  

Mass of Nitrogen N2 = no of moles x molar mass

                           = 0.034 x 28

                           = 0.952 g

Mass of oxygen O2 = no of moles x molar mass

                           = 0.008 x 32

                           =  0.256 g

total mass will be = Mass of Nitrogen N2 + Mass of oxygen O2  

                             =0.952 g  + 0.256 g

                               =1.207g

The mass of air in the flask = 1.207g

Given:

Pressure, P= 0.988 atm                  

Room Temperature, T = 23.5°C= 296.5 K

Volume, V= 1.042 L

Nitrogen in air is 80 % (moles number) = 0.8                

Ideal gas constant R = 0.0821 L atm [tex]mol^{-1}K^{-1}[/tex]

Molar mass of N = 14.01 g/mol

Molar mass of oxygen O = 16.00 g/mol

To find:

Total number of moles = ?

From ideal gas law:

n = PV/ RT  

n= 0.988atm * 1.042L / (0.0821 L atm [tex]mol^{-1}K^{-1}[/tex] * 296.6K)  

n  = 1.0294 / 24.35

n= 0.042 moles

Using mol fraction we will calculate moles for nitrogen and oxygen:

Moles of nitrogen = total moles * 80/100

Moles of nitrogen = 0.042moles * 0.8 = 0.034 moles

So, Moles of O₂ = Total moles – moles of N₂  

Moles of O₂ =   0.042 moles - 0.034 moles

Moles of O₂ = 0.008 moles

Calculation for mass:

Mass of Nitrogen N₂ = no of moles x molar mass

= 0.034 x 28

= 0.952 g

Mass of oxygen O₂ = no of moles x molar mass

= 0.008 * 32

=  0.256 g

Total mass will be = Mass of Nitrogen N₂ + Mass of oxygen O₂

=0.952 g  + 0.256 g

Total mass = 1.207g

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Answer:

The initial volume of the system: V₁ = 53.06 L

Explanation:

Given: heat absorbed by system: q =  50.5 J, Pressure: P = 0.491 atm, Final volume: V₂ = 56.2 L, The change in the internal energy: ΔE = -106.0 J

Initial volume: V₁ = ? L

According to the First Law of Thermodynamics:

ΔE = q - PΔV

⇒ PΔV = q - ΔE = 50.5 J - (-106.0 J) = 156.5 J

As, 1 L∙atm = 101.3 J  ⇒   1 J = (1 ÷ 101.3) L∙atm

⇒ PΔV = 156.5 J = (156.5 ÷ 101.3) L∙atm = 1.54 L∙atm

So,

ΔV = 1.54 L∙atm ÷ P = 1.54 L∙atm ÷ 0.491 atm = 3.14 L

∵ ΔV = V₂ - V₁ = 3.14 L

⇒ V₁ = V₂ -  3.14 L = 56.2 L -  3.14 L = 53.06 L

Therefore, the initial volume of the system: V₁ = 53.06 L

Answer:

The four quantum number for each electron will be:

[tex]1s^{2}[/tex]

[tex]n=1;l=0;m=0;s=+\frac{1}{2}/-\frac{1}{2}[/tex]

[tex]2s^{2}[/tex]

[tex]n=2;l=0;m=0;s=+\frac{1}{2}/-\frac{1}{2}[/tex]

[tex]2p^{6}[/tex]

[tex]n=1;l=1;\\m=+1,0.-1 \\s=+\frac{1}{2}/-\frac{1}{2}[/tex]

[tex]3s^{2}[/tex]

[tex]n=3;l=0;m=0;s=+\frac{1}{2}/-\frac{1}{2}[/tex]

Explanation:

As the element is neutral, the number of protons will be equal to number of electrons which will be the atomic number of the element.

Number of electrons =12

Atomic number = 12

Element : Magnesium

The principal shell is represented by "n"

i) For "s" subshell the value of l =0 (azimuthal quantum number) thus m (magnetic quantum number)= 0

The two electrons in s subshell will have either plus half or minus half spin quantum number

ii) for "p" subshell the value for l =1

thus m = 0 or +1 or -1

The two electrons in each orbital will have either plus half or minus half spin quantum number

Final answer:

The complete set of quantum numbers for each electron in the given electron configuration, which corresponds to the element magnesium (Mg), is derived from the configuration 1s²2s²2p⁶3s², by stating the values for the principal, angular momentum, magnetic, and spin quantum numbers for each electron.

Explanation:

The electron configuration of a neutral atom is 1s22s22p63s2. To write a complete set of quantum numbers for each of the electrons, we can consider the principles of quantum mechanics. Each electron in an atom is described by four quantum numbers: the principal quantum number (n), angular momentum quantum number (l), magnetic quantum number (ml), and spin quantum number (ms).

For the 1s subshell (2 electrons), the quantum numbers for each electron are (1, 0, 0, +1/2) and (1, 0, 0, -1/2). For the 2s subshell (2 electrons), the quantum numbers are similar, with the principal quantum number being 2: (2, 0, 0, +1/2) and (2, 0, 0, -1/2). For the 2p subshell (6 electrons), there are three magnetic quantum numbers (-1, 0, +1), and two spin states. Thus, the six sets of quantum numbers are (2, 1, -1, +1/2), (2, 1, -1, -1/2), (2, 1, 0, +1/2), (2, 1, 0, -1/2), (2, 1, +1, +1/2), and (2, 1, +1, -1/2). For the 3s subshell (2 electrons), the quantum numbers are (3, 0, 0, +1/2) and (3, 0, 0, -1/2).

Based on this configuration, the neutral atom would be magnesium (Mg), which has an atomic number of 12, corresponding to the 12 electrons described.

Answer:

Mass = 12.82 g

Explanation:

Given data:

Mass of oxygen = 8.5 g

Mass of H₂S = 10.0 g

Mass of SO₂ = ?

Solution:

Chemical equation;

2H₂S + 3O₂ →  2SO₂ + 2H₂O

Number of moles of H₂S:

Number of moles = mass/ molar mass

Number of moles = 10.0 g / 34 g/mol

Number of moles =0.3 mol

Number of moles of oxygen:

Number of moles = mass/ molar mass

Number of moles = 8.5 g / 32 g/mol

Number of moles = 0.3 mol

Now we will compare the moles of SO2 with oxygen and hydrogen sulfide.

                         O₂             :         SO₂

                           3             :            2

                           0.3          :            2/3×0.3=0.2 mol

                         H₂S           :            SO₂

                           2              :            2

                         0.3             :           0.3

The number of moles of SO₂  produced by oxygen are less so it will limiting reactant.

Mass of SO₂:

Mass = number of moles × molar mass

Mass = 0.2 mol × 64.1 g/mol

Mass = 12.82 g

The chemical equation for the neutralization of hydroxide ion by HClO is:

A buffer is a solution which resists changes to its pH when a small quantity of strong acid or base is added to it.

A solution of weak acid such as hypochlorous acid (HClO) and its basic salt that is sodium hypochlorite (NaClO) forms a buffer solution

When a strong base is added to the buffer, the excess hydroxide ion will be neutralized by hydrogen ions from the acid, HClO.

The chemical equation for the neutralization of hydroxide ion with acid follows:

Therefore, the balanced chemical equation is such that the excess OH- is neutralized.

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Answer:

Explanation:

2NO₂(g) → N₂O₄(g)   Kc=4.7

The definition of equilibrium is when the forward rate and the reverse rate are equal.

Because in the initial state there's only NO₂, there's no possibility for the reverse reaction (from N₂O₄ to NO₂). Thus the forward rate will be larger than the reverse rate.

Answer:

The percentage  by mass of water in magnesium sulfate heptahydrate is 51.2 %

Explanation:

Step 1: Data given

Molar mass of MgSO4*7H2O = 246.5 g/mol

Molar mass of H2O = 18.02 g/mol

Molar massof MgSO4 = 120.37 g/mol

Step 2: Calculate % water in magnesium sulfate heptahydrate

Since we have 7 molecules of water in the heptahydrate, we will divide the molar mass of 7 molecules water by the molar mass of the heptahydrate.

m%(H2O) = (7*18.02)/ 246.5

m%(H2O) = (126.14 /246.5)*100%

m%(H2O) = 51.2 %

To controle this we will calculate the mass % of MgSO4

m%(MgSO4) = (120.37/ 246.50)*100%

m%(MgSO4) = 48.8%

51.2 + 48.8 = 100%

The percentage  by mass of water in magnesium sulfate heptahydrate is 51.2 %

Answer:from reffered dfn of %by mass

%by M=mass of component particular/total mass

But mass directly proportional to Molar mass

% by M=molar mass of H2O cpn/total M

%by M=7((1×2)+16)/(7((1×2)+16)+(24+(16×4)+32))

=0.573

Answer:

c. 8, product side

Explanation:

In order to balance a redox reaction we use the ion-electron method, which has the following steps:

Step 1: identify oxidation and reduction half-reaction.

Oxidation: MnO₄⁻(aq) → Mn²⁺(aq)

Reduction: Br⁻(aq) → Br₂(l)

Step 2: perform the mass balance adding H⁺ and H₂O where necessary

8 H⁺(aq) + MnO₄⁻(aq) → Mn²⁺(aq) + 4 H₂O(l)

2 Br⁻(aq) → Br₂(l)

Step 3: perform the electrical balance adding electrons where necessary.

8 H⁺(aq) + MnO₄⁻(aq) + 5 e⁻ → Mn²⁺(aq) + 4 H₂O(l)

2 Br⁻(aq) → Br₂(l) + 2 e⁻

Step 4: multiply both half-reactions by numbers that secure that the number of electrons gained and lost are the same.

2 × (8 H⁺(aq) + MnO₄⁻(aq) + 5 e⁻ → Mn²⁺(aq) + 4 H₂O(l))

5 × (2 Br⁻(aq) → Br₂(l) + 2 e⁻)

Step 5: add both half-reactions side to side.

16 H⁺(aq) + 2 MnO₄⁻(aq) + 10 e⁻ + 10 Br⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 Br₂(l) + 10 e⁻

16 H⁺(aq) + 2 MnO₄⁻(aq) + 10 Br⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 Br₂(l)

Answer:

Hydrogen spectrum

Explanation:

Balmer series - Observed in the visible region

Brackett series - Observed in the infrared region

Paschen series - Observed in the infrared region

Lyman series - Observe in the Ultraviolet region.

There are four sets of lines seen in the hydrogen emission spectra are Lyman series in the UV region, Balmer in the visible region and bracket and paschen in the IR region.

Emission spectrum is set of radiations emitted by an atom in the order of increasing frequency or decreasing wavelengths. Electrons in atoms transit between various energy levels.

Electrons excites from the lower energy level to the higher energy level by the absorption of light and return back to the ground state by emitting a complementary light.

The lyman series in the hydrogen emission spectrum is starting from the energy level n= 1. It is seen in the UV-region. Balmer series is found in visible region and their n value starts from n = 2.

Similarly Bracket starts from n= 3 and paschen series starts from n= 4. Both are overlapping lines together and they are seen in IR region.

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Answer:

(a) [Noble gas] ns² np⁵: Number of unpaired electron is 1 and belongs to group 17 i.e. halogen group of the periodic table.

(b) [noble gas] ns² (n-1)d²: Number of unpaired electron is 2 and belongs to group 4 of the periodic table.

(c) [noble gas] ns² (n-1)d¹⁰ np¹: Number of unpaired electron is 1 and belongs to group 13 of the periodic table.

(d)[noble gas] ns² (n-2)f⁶ : Number of unpaired electron is 6 and belongs to group 8 of the periodic table.

Explanation:

In the Periodic table, the chemical elements are arranged in 7 rows, called periods and 18 columns, called groups. They are organized in increasing order of atomic numbers.

(a) [Noble gas] ns² np⁵

As the total number of electrons in the p-orbital is 5. Therefore, the number of unpaired electron is 1.

This element has 2 electrons in ns orbital and 5 electrons in np orbital. So there are 7 valence electrons.

Therefore, this element belongs to the group 17 i.e. halogen group of the periodic table.

(b) [noble gas] ns² (n-1)d²

As the total number of electrons in the d-orbital is 2. Therefore, the number of unpaired electrons is 2.

This element has 2 electrons in ns orbital and 2 electrons in (n-1)d orbital. So there are 4 valence electrons.

Therefore, this element belongs to the group 4 of the periodic table.

(c) [noble gas] ns² (n-1)d¹⁰ np¹

As the total number of electrons in the p-orbital is 1. Therefore, the number of unpaired electron is 1.

This element has 2 electrons in ns orbital and 1 electron in np orbital. So there are 3 valence electrons.

Therefore, this element belongs to the group 13 of the periodic table.

(d)[noble gas] ns² (n-2)f⁶

As the total number of electrons in the f-orbital is 6. Therefore, the number of unpaired electron is 6.

This element has 2 electrons in ns orbital and 6 electrons in (n-2)f orbital. So there are 8 valence electrons.

Therefore, this element belongs to the group 8 of the periodic table.

The group of elements that corresponds to each of the following are:

(a) [Noble gas] ns² np⁵: Number of unpaired electron is 1 and belongs to group 17.

(b) [noble gas] ns² (n-1)d²: Number of unpaired electron is 2 and belongs to group 4.

(c) [noble gas] ns² (n-1)d¹⁰ np¹:Number of unpaired electron is 1 and belongs to group 13.

(d) [noble gas] ns² (n-2)f⁶ : Number of unpaired electron is 6 and belongs to group 8.

Periods are horizontal rows (across) the periodic table, while groups are vertical columns (down) the table. The elements are arranged in increasing order of their atomic number.

Group 17 is known as Halogen group, it has only on unpaired electron that means it needs one electron more to complete its octet or attain noble gas configuration. Group 4 is the second group of transition metals in the periodic table. Group 13, is also known as Boron group and it lies in p block elements. Group 8, is also known as Iron family.

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Answer:

68 g

Explanation:

Molar mass (C10H16) = 10*12.0 g/mol + 16*1.0 g/mol = (120+16)g/mol =

= 136 g/mol

m (C10H16) = n(C10H16)*M(C10H16) = 0.5 mol*136 g/mol = 68 g

n(C10H16) - number of moles of C10H16

M(C10H16) - molar mass of C10H16

The detailed answer provides the balanced chemical equation for the oxidation of Cl2 by Cu3+ in an acidic solution, with states of matter indicated.

The balanced chemical equation describing the oxidation of Cl2 gas by Cu3+ to form chlorate ion (ClO3-) and Cu2+ in an acidic aqueous solution is:

3Cu^3+(aq) + 6Cl¯(aq) + 18H^+(aq) + Cl2(g) → 3Cu^2+(aq) + ClO3^-(aq) + 9H2O(l)

States of matter: (s) solid, (l) liquid, (g) gas, (aq) aqueous solution.

The oxidation of [tex]Cl_2[/tex] gas by [tex]Cu^{3+}[/tex] to form chlorate ion and [tex]Cu^{2+}[/tex] in an acidic aqueous solution is represented by the balanced chemical equation provided.

The given question concerns the concept of balancing chemical equations in chemistry and deriving correct chemical reactions for the mentioned reactants and products. Also, oxidation is mentioned which refers to addition of oxygen to an entity or removal of hydrogen from entity. The balanced chemical equation for the oxidation of [tex]Cl_2[/tex] gas by [tex]Cu^{3+}[/tex] in an acidic aqueous solution is:

[tex]2Cl_2(g) + 2Cu^{3+} (aq) + 4H^+ (aq) \rightarrow 2ClO^{3-} (aq) + 2Cu^{2+} (aq) + 2H_2O (l)[/tex]

This reaction results in the formation of chlorate ion ([tex]ClO^{3-}[/tex]) and [tex]Cu^{2+}[/tex] in the solution. The states of matter as gas, aqueous, and liquid are indicated in the equation.