From the Henderson-Hasselbalch equation, explain how the ratio [Al/[HA] changes with changing pH

Answers

Answer 1

Answer:

The ratio [A-]/[HA] increase when the pH increase and the ratio decrease when the pH decrease.

Explanation:

Every weak acid or base is at equilibrium with its conjugate base or acid respectively when it is dissolved in water.

[tex]HA + H_{2}O[/tex] ⇄ [tex]A^{-} + H_{3}O^{+}[/tex]

This equilibrium depends on the molecule and it acidic constant (Ka). The Henderson-Hasselbalch equation,

[tex]pH = pKa + Log \frac{[A^{-}]}{[HA]}[/tex]

shows the dependency between the pH of the solution, the pKa and the concentration of the species. If the pH decreases the concentration of protons will increase and the ratio between A- and AH will decrease. Instead, if the pH increases the concentration of protons will decreases and the ratio between A- and AH will increase.

Answer 2

Final answer:

The ratio [A-]/[HA] changes with changing pH according to the Henderson-Hasselbalch equation.

Explanation:

The Henderson-Hasselbalch equation, pH = pKa + log([A-]/[HA]), shows how the ratio [A-]/[HA] changes with changing pH. In this equation, [A-] represents the concentration of the conjugate base and [HA] represents the concentration of the weak acid. As the pH increases, the concentration of [A-] increases relative to [HA], resulting in a higher value for the ratio [A-]/[HA]. Conversely, as the pH decreases, the concentration of [A-] decreases relative to [HA], leading to a lower value for the ratio [A-]/[HA].


Related Questions

pre: 772/2900 Convert 9.23 um to inches. Given that: 1in = 2.54cm. 9.23 um = about us careen privacy policy terms of use

Answers

Answer:

9.23 μm = 0.000363 in

Explanation:

In order to convert 9.23 μm into inches, we need to keep in mind two conversion factors:

1 in = 2.54 cm1 cm = 10000 μm

Now we proceed to calculate, keeping in the denominator the unit we want to convert, and in the numerator the unit that we wish to convert to:

[tex]9.23um*\frac{1cm}{10000um}*\frac{1in}{2.54cm}  =0.0363 in[/tex]

Thus 9.23 μm are equal to 0.000363 inches.

What is the formula for magnesium sulfite ?

Answers

Answer: The chemical formula for magnesium sulfite is [tex]MgSO_3[/tex]

Explanation:

The given compound is formed by the combination of magnesium and sulfite ions. This is an ionic compound.

Magnesium is the 12th element of periodic table having electronic configuration of [tex][Ne]3s^2[/tex].

To form [tex]Mg^{2+}[/tex] ion, this element will loose 2 electrons.

Sulfite ion is a polyatomic ion having chemical formula of [tex]SO_3^{2-}[/tex]

By criss-cross method, the oxidation state of the ions gets exchanged and they form the subscripts of the other ions. This results in the formation of a neutral compound.

So, the chemical formula for magnesium sulfite is [tex]MgSO_3[/tex]

Answer:

MgSO3

Explanation:

Explain why the diffusion of an interstitial atom (such as C, N, O, etc.) is faster when diffusing through iron with a BCC crystal structure rather than an FCC crystal structure.

Answers

Answer and Explanation:

Interstitial diffusion allows the purity atom like (C, O, H) to occupy the interstitial sites in the atom which are abundantly present as a result of weaker bond formation with the surrounding atom.

The interstitial diffusion of iron in Body Centered Cubic (BCC) crystal lattice is faster than Face Centered Cubic (FCC) and the reason being that BCC structure is more open with more interstitial spaces than FCC structure.

Also the packing fraction of BCC lattice is less than that of FCC lattice.

For BCC is 0.68 whereas for FCC, it is 0.74

What is the percent s character in an sp^2 hybridized orbital? 25% 33% 50% 67% 75%

Answers

Answer:

The correct option is: B. 33%

Explanation:

Orbital hybridisation refers to the mixing of atomic orbitals of the atoms in order to form new hybrid orbitals. The concept of orbital hybridization is used to explain the structure of a molecule.

The sp² hybrid orbitals are formed by the hybridization of one 2s orbital and two 2p orbitals. The three sp² hybrid orbitals formed have 33% s character and 67% p character.

Answer:

It's B. 33%

Explanation:

Because it refers to the mixing of atomic orbitals of the atoms in order to form new hybrid orbitals. The concept of orbital hybridization is used to explain the structure of a molecule.

Also, the sp² hybrid orbitals are formed by the hybridization of one 2s orbital and two 2p orbitals. Then the three sp² hybrid orbitals formed have 33% s character and 67% p character.

A solution contains 0.45 M hydrofluoric acid (HF; KA = 6.8 X 10−4). Write the dissociation reaction. Determine the degree of ionization and the pH of the solution

Answers

Answer:

Degree of ionization = 0.0377

pH of the solution = 1.769

Explanation:

Initial concentration of HF = 0.45 M

[tex]K_a = 6.8 \times 10^{-4}[/tex]

                     [tex]HF \leftrightharpoons  H^+ + F^-[/tex]

Initial        0.45                             0          0

At equi      0.45 - x                      x           x

Equilibrium constant = [tex]\frac{[H^+][F^-]}{HF}[/tex]

                   [tex]6.8 \times 10^{-4}= \frac{[x][x]}{0.45 - x}[/tex]

           [tex]x^2 + 6.8 \times 10^{-4} x -  6.8 \times 10^{-4} \times 4.5 = 0[/tex]

x = 0.017 M

x = Cα

α = Degree of ionization

C = Concentration

Degree of ionization = [tex]\frac{0.017}{0.45} = 0.0377[/tex]

[tex]pH = -log[H^+][/tex]

[H^+]=0.017 M

[tex]pH = -log[0.017][/tex]

             = 1.769

Final answer:

The acid dissociation reaction for hydrofluoric acid in water is [tex]HF (aq) + H_2O (l)[/tex] ⇌ [tex]H_3O^+ (aq) + F- (aq)[/tex]. The concentration of a 0.1 L solution containing 0.05 g of HF is 0.025 M. To find the pH for such a solution using the given Ka, the ICE table method can be utilized.

Explanation:

To answer your questions regarding hydrofluoric acid (HF) and its properties, we can proceed as follows:

a) Write out the acid dissociation reaction for hydrofluoric acid. Label the conjugate acid/base pairs.

Hydrofluoric acid dissociates in water as follows:

[tex]HF (aq) + H_2O (l)[/tex] ⇌ [tex]H_3O^+ (aq) + F- (aq)[/tex]

In this reaction, HF is the conjugate acid and F- is the conjugate base.

b) What is the concentration (M) of a solution containing 0.05 g of HF in 0.1 L H2O?

The molecular weight of HF is approximately 20.01 g/mol. To find the molarity, first convert grams to moles:

0.05 g HF × (1 mol HF/20.01 g HF) = 0.0025 mol HF

Then, divide the moles of HF by the volume of the solution in liters:

0.0025 mol HF / 0.1 L = 0.025 M

c) Using the given Ka value, calculate the pH of the solution from part b

Since HF is a weak acid, and given that Ka = 7.2 × [tex]10^-^4[/tex], you can use the ICE table method to find the concentration of H3O+ and then calculate the pH.

Two mercury manometers, one open-end and the other sealed-end, are attached to an air duct. The reading on the open-end manometer is 25 [mm] and that on the sealed-end manometer is 800 [mm]. Determine the absolute pressure in the duct, the gauge pressure in the duct, and the atmospheric pressure, all in (mm Hg).

Answers

Answer:

Pressure in duct = 799.75 mmHg

Atmospheric pressure = 774.75 mmHg

Gauge pressure = 24.99 mmHg

Explanation:

First of all, it is needed to set a pressure balance (taking in account that diameter of manometer is constant) in the interface between the air of the duct and the fluid mercury.

From the balance in the sealed-end manometer, we have the pressure of air duct as:

[tex]P = \rho g h_1[/tex]

We have that ρ is density of mercury and g is the gravity

[tex]\rho = 13600 kg/m^{3}[/tex]

[tex]g = 9.8 m/s^{2}[/tex]

So, replace in the equation:

[tex]P = (13600 kg/m^{3} )(9.8 m/s^{2})(800 mmHg)(\frac{1 mHg}{1000 mmHg})[/tex]

[tex]P = 106624.0 \frac{kg}{s^{2}} = 106624.0 Pa[/tex]

Transforming from Pa to mmHg

[tex]P =  106624.0 Pa (\frac{760 mmHg}{101325 Pa}) = 799.7 mmHg[/tex]

From the balance in the open-end manometer, we have the pressure of air duct as:

[tex]P = \rho g h_2 + P_atm[/tex]

Isolate [tex]P_atm[/tex]:

[tex]P_atm = P - \rho g h_2[/tex]

Calculating:

[tex]P_atm = 799.75 mmHg - (13600 kg/m^{3} )(9.8 m/s^{2})(25 mmHg)(\frac{1 mHg}{1000 mmHg})(\frac{760 mmHg}{101325 Pa} )[/tex]

[tex]P_atm = 774.75 mmHg[/tex]

Finally, gauge pressure is the difference between duct pressure and atmospheric pressure, so:

[tex]P_gau = P - Patm[/tex]

[tex]P_gau = 799.75 mmHg - 774.75 mmHg[/tex]

[tex]P_gau = 24.99 mmHg[/tex]

End.

What is the sum of the coefficient when the following equation is balanced:

__ H2SO4 + __ NaOH → __ H2O + __ Na2SO4

a. 4
b. 5
c. 6
d. no right answer

Answers

Answer:

The sum of the coefficient is: 1 + 2 +2 + 1 = 6 ( option c)

Explanation:

First we will balance on both sides Na

On the right side we have 2x Na but on the left side we have only 1x Na. So we have to multiply NaOH on the left side by 2.

This will give us:

H2SO4 + 2 NaOH → H2O + Na2SO4

Now we have on both sides 2x Na

We see that on the left side we have 4x H ( 2x H of H2SO4 and 2x H of NaOH), but on the right side we only have 2x H. So, we have to multiply H2O on the right side by 2.

This will give us:

H2SO4 + 2 NaOH → 2 H2O + Na2SO4

Now we have on both sides 2x Na and 4x H.

Also the number of O is on both sides equal, due to this. ( Both sides have 6x O).

Finally, we have this reaction:   H2SO4 + 2 NaOH → 2 H2O + Na2SO4

The sum of the coefficient is: 1 + 2 +2 + 1 = 6 ( option c)

Final answer:

The sum of the coefficients when the equation H2SO4 + NaOH → H2O + Na2SO4 is balanced is 6. The balanced equation is 1 H2SO4 + 2 NaOH → 2 H2O + 1 Na2SO4.

Explanation:

The sum of the coefficients when the chemical equation H2SO4 + NaOH → H2O + Na2SO4 is balanced is the total of the numbers that are used to balance the equation.

To balance the equation, we need to ensure that there is the same number of each type of atom on both the reactant and product sides of the equation. In this case, we balance the equation as follows: 1 H2SO4 (aq) + 2 NaOH (aq) → 2 H2O (l) + 1 Na2SO4 (aq). So, the coefficients in the balanced equation are 1, 2, 2, and 1 respectively.

Adding these coefficients, we get:

1 (for H2SO4) + 2 (for NaOH) + 2 (for H2O) + 1 (for Na2SO4) = 6.

The answer is option c: 6.

Round 51.32975248 to the requested number of significant figure a. 2 significant figures 5 c. 6 significant figures b. S significant figures d. 7 significant figures

Answers

a) 51 b) 51.330 c) 51.3298 d) 51.32975

Answer:

a) 51.00000000 c) 51.32980000 d) 51.32975000

Explanation:

your welcome :)

Write a balanced equation for the neutralization of potassium hydroxide by phosphoric acid. Use the smallest possible integer coefficients. Submit Answer & Next

Answers

Explanation:

Neutralization reaction -

The reaction of an acid and base to yield a salt and water , is a type of neutralization reaction .

The reaction of  potassium hydroxide and phosphoric acid  is a type of neutralization reaction ,

Hence , the reaction is as follows -

KOH (aq) + H₃PO₄ (aq) ----> K₃PO₄ (aq) + 3H₂O (l)

The reaction after balancing the atoms on the reactant side and on the product side is -

3 KOH (aq) + H₃PO₄ (aq) ----> K₃PO₄ (aq) + 3H₂O (l)

A runner wants to run 10.4 km . She knows that her running pace is 7.6 mi/h .

How many minutes must she run? Hint: Use 7.6 mi/h as a conversion factor between distance and time. Express your answer using two significant figures.

Answers

Answer:

The runner should run 51 minutes.

Explanation:

Distance wished by runner to cover = d = 10.4 km

Time taken by the runner to cover 10.4 km = T

Speed of the runner  = 7.6 mile/hour

1 mile = 1.60934 km

1 hour = 60 min

[tex]7.6 mile/Hour=\frac{7.6\times 1.60934 km}{1\times 60 min}=0.2038 km/min[/tex]

[tex]Speed=\frac{Distance}{Time}[/tex]

[tex]T=\frac{10.4 km}{0.2038 km/min}=51.0179 min\approx 51 minutes[/tex]

The runner should run 51 minutes.

The mass flow rate of gasoline leaving a refinery is 1610 kg/min. The specific gravity of a gasoline is 0.700.

A retail gasoline pump is able to fill a 20.0 gallon automobile tank in 1.80 minutes. What is the mass flow rate deliverd by the gasoline pump in lbm/min?

Answers

Answer:

mass flow = 64.9086 Lbm/min

Explanation:

SG = 0.700 = ρ gas / ρ H2O

∴ ρ H2O = 1000 Kg/m³

⇒ ρ gas = 700 Kg/m³

∴ F auto tank = 20.0 gal / 1.8 min = 11.11 gal/min * ( m³/264.172 gal)

⇒ F auto = 0.042 m³/min

⇒ mass flow = 0.042 m³/min * (700 Kg/m³) * ( 2.20462 Lbm/ Kg )

⇒ mass flow =  64.9086 Lbm/min

The partial pressure of CO2 gas above the liquid in a carbonated drink is 0.71 atm. Assuming that the Henry's law constant for CO2 in the drink is that same as that in water, 3.7 x 10-2 mol/L atm, calculate the solubility of carbon dioxide in this drink. Give your answer to 3 decimal places.

Answers

Answer: The molar solubility of carbon dioxide gas is 0.003 M

Explanation:

Henry's law states that the amount of gas dissolved or molar solubility of gas is directly proportional to the partial pressure of the liquid.

To calculate the molar solubility, we use the equation given by Henry's law, which is:

[tex]C_{CO_2}=K_H\times p_{liquid}[/tex]

where,

[tex]K_H[/tex] = Henry's constant = [tex]3.7\times 10^{-2}mol/L.atm[/tex]

[tex]p_{CO_2}[/tex] = partial pressure of carbonated drink = 0.71 atm

Putting values in above equation, we get:

[tex]C_{CO_2}=3.7\times 10^{-2}mol/L.atm\times 0.71atm\\\\C_{CO_2}=2.637\times 10^{-2}mol/L=0.003M[/tex]

Hence, the molar solubility of carbon dioxide gas is 0.003 M

Answer: The molar solubility of carbon dioxide is [tex]2.63\times 10^{-2}M[/tex]

Explanation:

To calculate the molar solubility, we use the equation given by Henry's law, which is:

[tex]C_{CO_2}=K_H\times p_{CO_2}[/tex]

where,

[tex]K_H[/tex] = Henry's constant = [tex]3.7\times 10^{-2}mol/L.atm[/tex]

[tex]C_{CO_2}[/tex] = molar solubility of carbon dioxide gas = ?

[tex]p_{CO_2}[/tex]  = partial pressure of carbon dioxide gas = 0.71 atm

Putting values in above equation, we get:

[tex]C_{CO_2}=3.7\times 10^{-2}mol/L.atm\times 0.71atm\\\\C_{CO_2}=2.63\times 10^{-2}M[/tex]

Hence, the molar solubility of carbon dioxide is [tex]2.63\times 10^{-2}M[/tex]

Explain what the horizontal and vertical lines of a Fischer Projection indicate about the structure of the molecule

Answers

Explanation:

Fischer Projections allow to represent the three dimensional molecular structures in two dimensional environment without the change in the properties or the structural integrity of the compound. It consists of horizontal as well as vertical lines both, where horizontal lines represent atoms which are pointed toward viewer while vertical line represents atoms which are pointed away from viewer. The point of the intersection between horizontal and vertical lines represents central carbon.

Tritium H) is an isotope of hydrogen that is sometimes used to make the hands of watches glow in the dark. The half-life of tritium is 123 years. If you start with 1 milligram of trition and wait 49 years, approximately how much of the original tritium remains? O a.6.25 Ob.3.12% O c.25 O d. 506 O e 12.5%

Answers

Answer:

Percentage of the isotope left is 75.87 %.

Explanation:

Initial mass of the isotope = 1 mg

Time taken by the sample, t = [tex]t_{\frac{1}{2}}=123 years[/tex]

Formula used :

[tex]N=N_o\times e^{-\lambda t}\\\\\lambda =\frac{0.693}{t_{\frac{1}{2}}}[/tex]

where,

[tex]N_o[/tex] = initial mass of isotope

N = mass of the parent isotope left after the time, (t)

[tex]t_{\frac{1}{2}}[/tex] = half life of the isotope

[tex]\lambda[/tex] = rate constant

[tex]\lambda =\frac{0.693}{123 year}=0.005635 year^{-1}[/tex]

[tex]N=N_o\times e^{-\lambda \times t}[/tex]

Now put all the given values in this formula, we get

[tex]N=1 mg\times e^{-0.005634 year^{-1}\times 49 years}[/tex]

[tex]N=0.7587 mg[/tex]

Percentage of the isotope left:

[tex]\frac{N}{N_o}\times 100[/tex]

=[tex]\frac{0.7587 mg}{1 mg}\times 100[/tex]

Percentage of the isotope left is 75.87 %.

A chemist adds 0.45 L of a 1.08 * 10M zinc oxalate (ZnC,0) solution to a reaction flask. Calculate the mass in milligrams of incolate the chemist has added to the flask. Be sure your answer has the correct number of significant digits.

Answers

Answer: The mass of zinc oxalate, the chemist has added is [tex]7.6\times 10^5mg[/tex]

Explanation:

To calculate the mass of solute, we use the equation used to calculate the molarity of solution:

[tex]\text{Molarity of the solution}=\frac{\text{Mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}[/tex]

We are given:

Molarity of solution = [tex]1.08\times 10M=10.8M[/tex]

Molar mass of zinc oxalate = 155.4 g

/mol

Volume of solution = 0.45 L

Putting values in above equation, we get:

[tex]10.8M=\frac{\text{Mass of zinc oxalate}}{155.4g/mol\times 0.45L}\\\\\text{Mass of zinc oxalate}=(10.8mol/L\times 155.4g/mol\times 0.45L)=7.6\times 10^2g[/tex]

To convert the calculated mass into milligrams, we use the conversion factor:

1 g = 1000 mg

So, [tex]7.6\times 10^2g\times \frac{1000mg}{1g}=7.6\times 10^5mg[/tex]

Hence, the mass of zinc oxalate, the chemist has added is [tex]7.6\times 10^5mg[/tex]

If the density of alcohol is 0.79 g/mL, what is the mass in grams of 1.0 L of alcohol?

Answers

Answer: The mass of alcohol is 790 grams.

Explanation:

To calculate the mass of alcohol, we use the equation:

[tex]\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}[/tex]

Volume of alcohol = 1.0 L = 1000 mL    (Conversion factor:  1 L = 1000 mL)

Density of alcohol = 0.79 g/mL

Putting values in above equation, we get:

[tex]0.79g/mL=\frac{\text{Mass of alcohol}}{1000mL}\\\\\text{Mass of alcohol}=790g[/tex]

Hence, the mass of alcohol is 790 grams.

Final answer:

The mass of 1.0 L of alcohol is 790 grams.

Explanation:

To calculate the mass in grams of 1.0 L of alcohol, you can use the density of alcohol.

The given density is 0.79 g/mL.

This means that for every 1 mL of alcohol, there is a mass of 0.79 grams.

Since 1 L is equal to 1000 mL, you can multiply the density by the volume to find the mass: 0.79 g/mL × 1000 mL = 790 grams of alcohol.

List some of the important biological functions of carbohydrates

Answers

Answer:

Carbohydrates are the biological molecules having a general emperical formula [tex]C_{m} (H_{2} O)_{n}[/tex].  

There are various important biological functions of carbohydrates. Carbohydrates serve as structural components, component of coenzymes, and backbone of RNA. Carbohydrates provide and store energy, and also plays important role in blood clotting, development, immune system, and preventing pathogenesis.

Calculate the amount of CO2 (in kg) released when 1 kg of coal is burned. Assume that carbon content of the coal is 50% by mass.

Answers

Burning 1 kg of coal with a 50% carbon content produces 1.833 kg of CO2 after performing a stoichiometric calculation based on the molar masses of carbon and CO2.

To calculate the amount of CO2 released when 1 kg of coal is burned, we first consider that the coal is 50% carbon by mass. This means that 0.5 kg (or 500 g) of that coal is carbon. Using the stoichiometry of the combustion reaction (C + O2 -> CO2), we find that each 12 grams of carbon (C) will produce 44 grams of CO2 (since the molar mass of carbon is 12 g/mol, and the molar mass of CO2 is 44 g/mol).

Therefore, to find out how much CO2 is produced from the carbon in coal, you can use the ratio (44 g CO2 / 12 g C). Calculating the amount of CO2 produced from 500 g of carbon:

500 g C x (44 g CO2 / 12 g C) = 1833.33 g CO2

Converting this to kilograms:

1833.33 g CO2 x (1 kg / 1000 g) = 1.833 kg CO2

A slug is the mass of an object that will accelerate at a rate of 1 ft/s^2 when subjected to 1 lbf (pound force). 1 lb, f = 1 slug*ft/(s^2) Calculate the mass in slugs of an 246 lb,m object

Answers

Answer:

Mass of 246 lb object is 7.646 slugs.

Explanation:

Mass of the object = m

Weight of the object = W = 246 lb

Acceleration due to gravity= g = [tex]32.174 ft/s^2[/tex]

[tex] Weight=mass \times g[/tex]

[tex]W=mg[/tex]

[tex]1 lb=slugs\times 1 ft/s^2[/tex]

[tex]1 slugs=\frac{lb\times s^2}{ft}[/tex]

[tex]m=\frac{W}{g}=\frac{246 lb}{32.174 ft/s^2}=7.646 lb s^2/ft=7.646 slugs[/tex]

Mass of 246 lb object is 7.646 slugs.

calculate the molarity of sodium ion in a solution made
bymixing 3.58 ml of 0.288 M sodium chloride with 500 ml of 6.51
times1/1000 M sodium sulfate ( assume volumes are additive ).

Answers

To determine the amount of sodium ions [tex]\rm (Na^+)[/tex]in the final solution, we need to take into account the contribution of sodium ions from both sodium chloride (NaCl) and sodium sulfate ([tex]\rm Na_2SO_4[/tex]). The volumes can be considered as individual contributions and then added together because they are additive.

Sodium chloride (NaCl):

Given volume of NaCl solution = 3.58 ml

Molarity of NaCl = 0.288 M

Number of moles of NaCl = Molarity × Volume (in liters)

So, the number of moles of NaCl = 0.288 M × (3.58 / 1000) L = 0.00082704 moles

The amount of sodium ions from NaCl is also 0.00082704 moles because each molecule of sodium chloride dissociates into one sodium ion ([tex]\rm Na^+[/tex]).

Sodium sulfate (Na₂SO₄):

Given volume of Na₂SO₄ solution = 500 ml

Molarity of Na₂SO₄ = 6.51 * 1/1000 M = 0.00651 M

Number of moles of Na₂SO₄ = Molarity × Volume (in liters)

So, the number of moles of Na₂SO₄ = 0.00651 M × (500 / 1000) L = 0.003255 moles

Since [tex]\rm Na_2SO_4[/tex] gives 2 sodium ions ([tex]\rm Na^+[/tex]) per formula unit, the amount of sodium ions from [tex]\rm Na_2SO_4[/tex] is 2 * 0.003255 = 0.00651 moles.

Adding the moles of sodium ions from both sources:

Total moles of sodium ions = Moles from NaCl + Moles from Na₂SO₄

Total moles of sodium ions = 0.00082704 + 0.00651 = 0.00733704 moles

So, the molarity of sodium ions in the final solution:

Molarity of sodium ions = Total moles of sodium ions / Total volume (in liters)

Molarity of sodium ions = 0.00733704 moles / (500 / 1000 + 3.58 / 1000) L ≈ 0.0162 M

Therefore, the molarity of sodium ions in the final solution is approximately 0.0162 M.

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Final answer:

The molarity of sodium ions in the solution made by mixing 3.58 mL of 0.288 M sodium chloride and 500 mL of 6.51/1000 M sodium sulfate is 0.00851 M.

Explanation:

To calculate the molarity of sodium ions in the mixture, we need first to calculate the moles of sodium in each solution and then sum those up. This can then be divided by the total volume of the mixture in liters.

For sodium chloride:

moles = Molarity * volume = 0.288 mol/L * 3.58 mL * (1 L/1000 mL) = 0.00103 mol

For sodium sulfate:

moles = Molarity * volume = 6.51/1000 mol/L * 500 mL * (1 L/1000 mL) = 0.00326 mol

Total moles of sodium ions = moles from sodium chloride + moles from sodium sulfate = 0.00103 mol + 0.00326 mol = 0.00429 mol

Total volume = volume of sodium chloride + volume of sodium sulfate = 3.58 mL + 500 mL = 503.58 mL = 0.50358 L

Therefore, molarity = moles / volume = 0.00429 mol / 0.50358 L = 0.00851 M

So, the molarity of sodium ions in the solution is 0.00851 M.

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1.00 kg of ice at -10 °C is heated using a Bunsen burner flame until all the ice melts and the temperature reaches 95 °C. A) How much energy in kJ is required to effect this transformation?

Answers

Answer : The energy required is, 574.2055 KJ

Solution :

The conversions involved in this process are :

[tex](1):H_2O(s)(-10^oC)\rightarrow H_2O(s)(0^oC)\\\\(2):H_2O(s)(0^oC)\rightarrow H_2O(l)(0^oC)\\\\(3):H_2O(l)(0^oC)\rightarrow H_2O(l)(95^oC)[/tex]

Now we have to calculate the enthalpy change or energy.

[tex]\Delta H=[m\times c_{p,s}\times (T_{final}-T_{initial})]+n\times \Delta H_{fusion}+[m\times c_{p,l}\times (T_{final}-T_{initial})][/tex]

where,

[tex]\Delta H[/tex] = energy required = ?

m = mass of ice = 1 kg  = 1000 g

[tex]c_{p,s}[/tex] = specific heat of solid water = [tex]2.09J/g^oC[/tex]

[tex]c_{p,l}[/tex] = specific heat of liquid water = [tex]4.18J/g^oC[/tex]

n = number of moles of ice = [tex]\frac{\text{Mass of ice}}{\text{Molar mass of ice}}=\frac{1000g}{18g/mole}=55.55mole[/tex]

[tex]\Delta H_{fusion}[/tex] = enthalpy change for fusion = 6.01 KJ/mole = 6010 J/mole

Now put all the given values in the above expression, we get

[tex]\Delta H=[1000g\times 4.18J/gK\times (0-(-10))^oC]+55.55mole\times 6010J/mole+[1000g\times 2.09J/gK\times (95-0)^oC][/tex]

[tex]\Delta H=574205.5J=574.2055kJ[/tex]     (1 KJ = 1000 J)

Therefore, the energy required is, 574.2055 KJ

A solution is made by mixing equal masses of methanol, CH4O, and ethanol, C2H6O. Determine the mole fraction of each component to at least three signA solution is made by mixing equal masses of methanol, CH4O, and ethanol, C2H6O. Determine the mole fraction of each component to at least three significant figures.ificant figures.

Answers

Answer: mole fraction of methanol = 0.590

mole fraction of ethanol = 0.410

Explanation:

We are given:

Equal masses of methanol [tex]CH_4O[/tex] and ethanol [tex]C_2H_6O[/tex] are mixed.

let the mass be x g.

Calculating the moles of methanol in the solution, by using the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}=\frac{xg}{32.04g/mol}[/tex]

Calculating the moles of ethanol in the solution, by using the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}=\frac{xg}{46.07g/mol}[/tex]

To calculate the mole fraction of methanol, we use the equation:

[tex]\chi_{methanol}=\frac{n_{methanol}}{n_{methaol}+n_{ethanol}}[/tex]

[tex]\chi_{methanol}=\frac{\frac{xg}{32.04g/mol}}{\frac{xg}{32.04g/mol}+\frac{xg}{46.07g/mol}}=0.590[/tex]

To calculate the mole fraction of ethanol, we use the equation:

[tex]\chi_{ethanol}=\frac{n_{ethanol}}{n_{methaol}+n_{ethanol}}[/tex]

[tex]\chi_{ethanol}=\frac{\frac{xg}{46.07g/mol}}{\frac{xg}{32.04g/mol}+\frac{xg}{46.07g/mol}}=0.410[/tex]

Thus mole fraction of methanol is 0.590 and mole fraction of ethanol 0.410 in three significant figures.

Final answer:

To compute the mole fractions, first calculate the number of moles of each component by dividing mass by molar mass. The mole fraction is then calculated as each component's moles divided by the total moles. The mole fractions of methanol and ethanol are approximately 0.591 and 0.409 respectively.

Explanation:

To determine the mole fraction of methanol (CH4O) and ethanol (C2H6O) in a solution where equal masses of both are mixed, we first need to calculate the number of moles of each component. The number of moles is determined by the formula: moles = mass/molar mass. The molar mass of methanol is approximately 32.04 g/mol, and the molar mass of ethanol is approximately 46.07 g/mol.

Let's say that we've mixed 50g of each component. The moles of methanol would be 50g/32.04 g/mol which is approximately 1.56 moles. For ethanol, it would be 50g/46.07g/mol, approximately 1.08 moles.

Next, we calculate the total moles in the solution, which is the sum of moles of methanol and ethanol, or 1.56 moles methanol + 1.08 moles ethanol = 2.64 moles.

The mole fraction is then calculated as the number of moles of each component divided by the total moles. So, the mole fraction of methanol would be 1.56 moles methanol / 2.64 total moles = 0.591 to three significant figures. For ethanol, the mole fraction would be 1.08 moles ethanol / 2.64 total moles = 0.409 to three significant figures.

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II. Binding Forces A. Write a brief, one or two sentence, description of each binding force listed below. 1. London dispersion forces (a.k.a. van der Waals or induced dipoles) 2. Dipole-dipole forces 3. Hydrogen bonding 4. Electrostatic interactions (Ionic bonds) 5. Hydrophobic interactions (effect) 6. Covalent bonds

Answers

Answer:

All description is given in explanation.

Explanation:

Van der Waals forces:

It is the general term used to describe the attraction or repulsion between the molecules. Vander waals force consist of two types of forces:

1.  London dispersion forces

2.  Dipole-dipole forces

1. London dispersion forces:

These are the weakest intermolecular forces. These are the temporary because when the electrons of atoms come close together they create temporary dipole, one end of an atom where the electronic density is high is create negative pole while the other becomes positive . These forces are also called induce dipole- induce dipole interaction.

2.  Dipole-dipole forces:

These are attractive forces , present between the molecules that are permanently polar. They are present between the positive end of one polar molecules and the negative end of the other polar molecule.

Hydrogen bonding:

It is the electrostatic attraction present between the atoms which are chemically bonded. The one atom is hydrogen while the other electronegative atoms are oxygen, nitrogen or flourine. This is weaker than covalent and ionic bond.

Ionic bond or electrostatic attraction:

It is the electrostatic attraction present between the oppositely charged ions. This is formed when an atom loses its electron and create positive charge and other atom accept its electron and create negative charge.

Hydrophobic interaction:

It is the interaction between the water and hydrophobic material. The hydrophobic materials are long chain carbon containing compound. These or insoluble in water.

Covalent bond:

These compounds are formed by the sharing of electrons between the atoms of same elements are between the different element's atoms. The covalent bond is less stronger than ionic bond so require less energy to break as compared to the energy require to break the ionic bond.

Reaction Rates

Part A

For the arbitrary reaction,

A + B ? C + D

The following initial rates were measured given the initial concentrations of A and B. Determine the rate order for both A and B.

[A]o [B]o Initial Rate (M/s)
0.12 0.22 0.00639
0.24 0.22 0.0128
0.12 0.11 0.00639

Part B

-0th order in A and 1st order in B
-2nd order in A and 0th order in B
-1st order in A and 1st order in B
-1st order in A and 0th order in B
The following arbitrary reaction is exothermic:

A + B ? C + D

Predict what will happen to the rate of the reaction if the temperature is increased.

-The reaction rate will decrease.
-Equilibrium is shifted to the left.
-The reaction rate increases.
-There will be no change in rate.

Answers

Answer:

PART A 1st order in A and 0th order in B

Part B The reaction rate increases

Explanation:

PART A

The rate law of the arbitrary chemical reaction is given by

[tex]-r_A=k\times\left[A\right]^\alpha\times\left[B\right]^\beta\bigm[/tex]

Replacing for the data

Expression 1 [tex]0.00639=k\times{0.12}^\alpha\times{0.22}^\beta[/tex]

Expression 2 [tex]0.01280=k\times{0.24}^\alpha\times{0.22}^\beta[/tex]

Expression 3 [tex]0.00639=k\times{0.12}^\alpha\times{0.11}^\beta[/tex]

Making the quotient between the fist two expressions

[tex]\frac{0.00639}{0.01280}=\left(\frac{0.12}{0.24}\right)^\alpha[/tex]

Then the expression for [tex]\alpha[/tex]

[tex]\alpha=\frac{ln\frac{0.00639}{0.01280}}{ln\frac{0.12}{0.24}}=1\bigm[/tex]

Doing the same between the expressions 1 and 3  

[tex]\frac{0.00639}{0.00639}=\left(\frac{0.22}{0.11}\right)^\beta[/tex]

Then

[tex]\beta=\frac{ln\frac{0.00639}{0.00639}}{ln\frac{0.22}{0.11}}=0\bigm[/tex]

This means that the reaction is 1st order respect to A and 0th order respect to B .

PART B

By the molecular kinetics theory, if an increment in the temperature occurs, the molecules will have greater kinetic energy and, consequently, will move faster. Thus, the possibility of colliding with another molecule increases. These collisions are necessary for the reaction. Therefore, an increase in temperature necessarily produces an increase in the reaction rate.

A chemist prepares a solution of potassium permanganate (KMnO4) by measuring out 3.8 umol of potassium permanganate into a 100 mL volumetric flask and filling the flask to the mark with water. Calculate the concentration in mol/L of the chemist's potassium permanganate solution. Round your answer to 2 significant digits. x 5 ? Explanation Check

Answers

Answer:

3,8×10⁻⁵ mol/L of potassium permanganate solution

Explanation:

To calculate concentration in mol/L you must convert the 3,8 umol to moles and 100 mL to liters, knowing 1 umol are 1×10⁻⁶mol and 1L are 1000 mL.

3,8 umol × (1×10⁻⁶mol / 1 umol ) = 3,8×10⁻⁶mol of potassium permanganate.

100 mL × ( 1L / 1000 mL) = 0,100 L

Thus, concentration in mol/L is:

3,8×10⁻⁶mol / 0,100 L = 3,8×10⁻⁵ mol/L of potassium permanganate solution

I hope it helps!

Final answer:

The concentration of the potassium permanganate solution is 3.8 x 10⁻⁵ M when rounded to two significant digits.

Explanation:

The concentration of a solution is calculated by dividing the number of moles of the solute by the volume of the solution in liters. To calculate the concentration of potassium permanganate (KMnO₄) in the chemist's solution, you need to use the equation:

C = n / V

where C is the molarity (concentration) in moles per liter (mol/L), n is the number of moles of KMnO₄, and V is the volume of the solution in liters.

In this case, the student already has 3.8 μmol (or 3.8 x 10⁻⁶ mol) of KMnO₄ and the total volume is 100 mL, which is equivalent to 0.1 L. Therefore, the molarity (C) of the solution is:

C = 3.8 x 10⁻⁶ mol / 0.1 L = 3.8 x 10⁻⁵ M

Thus, the concentration of the potassium permanganate solution is 3.8 x 10⁻⁵ M, which can be rounded to two significant digits as 3.8 x 10⁻⁵ M.

The vapour pressure of pyridine is 50.0kPa at 365.7K and the
normal boiling point is 388.4 K. What is theenthalpy of
vaporization of pyridine?

Answers

Final answer:

The enthalpy of vaporization for pyridine can be calculated using the Clausius-Clapeyron equation. Given that the vapor pressure of pyridine is 50.0 kPa at 365.7 K, and its boiling point is 388.4K, we can substitute these values into the equation to find the enthalpy of vaporization.

Explanation:

The question is asking for the enthalpy of vaporization of pyridine. We first need to apply the Clausius-Clapeyron equation which is

ln(P2/P1) = -ΔHvap/R *(1/T1 - 1/T2), where P2 is the vapor pressure at the boiling point (1.00 atm or 101.3 kPa), P1 is the given vapor pressure (50.0 kPa), ΔHvap is the enthalpy of vaporization which we want to find, R is the gas constant (8.314 J/K.mol), T1 is 365.7 K, and T2 is the boiling point (388.4 K). By rearranging and substituting the values into the equation, one can solve for ΔHvap to find its value. Remember always to convert the pressure units into the same, in this case we used kilopascal.

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Explain why propanol is more soluble in water than propane

Answers

Explanation:

Propanol is [tex]CH_3CH_2CH_2OH[/tex] , whereas propane is [tex]CH_3CH_2CH_3[/tex].

There is a presence of hydroxyl group in propanol which leads to the formation of hydrogen bonds with water and thus become soluble in water. Such bonding do not exists in propane.

Hydrogen bonding is a special type of the dipole-dipole interaction and it occurs between hydrogen atom that is bonded to highly electronegative atom which is either fluorine, oxygen or nitrogen atom.

Partially positive end of the hydrogen atom is attracted to partially negative end of these atoms which is present in another molecule. It is strong force of attraction between the molecules.

Final answer:

Propanol is more soluble in water than propane due to the presence of the hydroxyl (OH) group in propanol. The hydroxyl group allows propanol to engage in hydrogen bonding with water molecules, making it more soluble.

Explanation:

Propanol is more soluble in water than propane due to the presence of the hydroxyl (OH) group in propanol. The hydroxyl group allows propanol to engage in hydrogen bonding with water molecules, making it more soluble. On the other hand, propane lacks a hydroxyl group and therefore cannot form hydrogen bonds with water, resulting in lower solubility in water.

A species that is formed when a base gains conjugate base. b. conjugate acid. a proton is a c. strong base d. strong acid.

Answers

Answer:

The correct option is: conjugate acid

Explanation:

Bases are the chemical substances that are proton acceptors and electron-pair donors. Therefore, when a base accepts a hydrogen proton from an acid it forms a conjugate acid.

Therefore, conjugate acids are formed when a base accepts a hydrogen proton from an acid. Also, if the base is a weak base then its conjugate acid is strong. Whereas, if the base is a strong base then the conjugate acid is weak.

Final answer:

A species that forms when a base gains a proton is called a conjugate acid. This concept is a part of acid-base reactions involving conjugate acid-base pairs, where the strength of conjugates is inversely related to their parent compounds.

Explanation:

When a base accepts a proton (H+), it becomes a conjugate acid. This process can be observed in acid-base reactions where a conjugate acid-base pair is formed; the base gains a proton to become the conjugate acid. Conversely, when an acid donates a proton, what remains is known as the conjugate base of that acid. The strength of these conjugate species is inversely related to their parent compounds. Notably, a conjugate base arises from a weak acid, and as such, may exhibit significant strength as a base itself, such as the acetate ion which is capable of accepting a hydrogen ion from water to produce acetic acid and a hydroxide ion.

A gas mixture has a total pressure of 0.51 atm and consists of He and Ne. If the partial pressure of He in the mixture is 0.32 atm, what is the partial pressure of the Ne in the mixture? Enter your answer in the provided box. atm

Answers

Final answer:

The concept at hand is Dalton's Law of Partial Pressures, stating that the total pressure of a mixture of gases is the sum of their individual partial pressures. Knowing the total pressure and the partial pressure of He, you can calculate the partial pressure of Ne as 0.19 atm.

Explanation:

The question revolves around the concept known as Dalton's Law of Partial Pressures. In a mixture of non-reactive gasses, Dalton's Law states that the total pressure exerted by the mixture of gases is the sum of the partial pressures of each component gas. In simpler terms, total pressure is the sum of the pressures of each individual gas.

If the total pressure of a gas mixture consisting of He (Helium) and Ne (Neon) is given as 0.51 atm, and we know the partial pressure of He is 0.32 atm, then we can calculate the partial pressure of Ne. Since the partial pressure of any given gas in a mixture is part of the total pressure, subtracting the known He partial pressure from the total will provide the Ne partial pressure:

Total pressure - He partial pressure = Ne partial pressure

So, 0.51 atm (total) - 0.32 atm (He) = 0.19 atm (Ne).

Hence, the partial pressure of the Ne in the mixture is 0.19 atm.

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Specify the functional groups by letters (A to G) as given in the list below. Use only one letter per box. If there are fewer than three functional groups, leave the appropriate number of answer boxes empty. If a functional group is present MORE than once, provide ONLY ONE entry for these groups.)

CH3-HC(NH2)-CO-OH

(a) hydroxyl group in alcohol
(b) amino group
(c) aldehyde group
(d) ketone group
(e) carboxyl group
(f) ester group
(g) amide group

Answers

Answer:

(b) amino group

e) carboxyl group

Explanation:

The functional group in an organic compound distinguishes it from other compounds. It is usually the site where chemical reactions takes place.

       CH₃-HC(NH₂)-COOH

There are two functional groups in this organic compoud:

The NH₂ group is called the amino groupThe COOH is a carboxyl group

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