Answer:
36.5 mol
Explanation:
The vapor pressure of a solution of a non volatile solute in water is given by Raoult´s law:
P H₂O = χ H₂O x P⁰ H₂O
where χ H₂O is the mole fraction of water in the solution and P⁰ H₂O
In the turn the mole fraction is given by
χ H₂O = mol H₂O / total # moles = mol H₂O /ntot
Thus
P H₂O = mole H₂O / n tot x P⁰ H₂0
now the mol of H₂O is equal n tot - 6 mol solute
Plugging the values given in the question and solving the resultant equation
19.8 torr = ( ntot - 6 ) x 23.7 torr / n tot
19.8 ntot = 23.7 ntot - 142.2
ntot = 36.5 ( rounded to 3 significant figures )
The half-equivalence point of a titration occurs halfway to the equivalence point, where half of the analyte has reacted to form its conjugate, and the other half still remains unreacted. If 0.300 moles of a monoprotic weak acid ( Ka=3.6×10−5 M) is titrated with NaOH , what is the pH of the solution at the half-equivalence point?
Answer:
pH=pKa
pH=4.44
Explanation:
Since the titration occur between a weak acid and a strong base.
then at half -equivalence point, the pH of the solution is equals to the pKa of the weak acid.
Therefore, pH=pKa
Ka of weak acid=3.6×10^−5
To calculate the pKa of the weak acid using the express below;
pKa =- log(Ka)
pKa=−log(3.6×10−5)=4.44
From the question, the pKa of the solution is at half -equivalence point
Then,
pH=pKa
pH=4.44
The question says that the titration occurred between a weak acid and a
strong base at half-equivalence point. Then we can deduce that the pH of
the solution is equal to the pKa of the weak acid.
pH=pKa
Ka of monoprotic weak acid=3.6×10⁻⁵
The pKa of the monoprotic weak acid will be calculated by :
pKa = - log(Ka)
pKa = −log(3.6×10⁻⁵) = 4.44
Since the pKa of the solution is at half -equivalence point
pH=pKa
pH=4.44
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Addition of AgNO3 to aqueous solutions of the complex results in a cloudy white precipitate, presumably AgCl. You dissolve 0.1000 g of the complex in H2O and perform a precipitation titration with 0.0500 M AgNO3 as the titrant. Using an electrode that is sensitive to [Ag ], you reach the endpoint after 9.00 mL of titrant is added. How many grams of chloride ion were present in the 0.1000-g sample
Answer:
0.016 grams of chloride ion were present in the 0.1000 grams of sample.
Explanation:
According to question, 9.00 mL of titrant was added to solution with 0.1000 grams of complex to reach the end point.
Molarity of the silver nitrate solution = 0.0500 M
Volume of the silver nitrate solution = V = 9.00 mL = 0.009 L
1 mL = 1000 L
Moles of silver nitrate = n
[tex]Molarity=\frac{Moles}{Volume (L)}[/tex]
[tex]0.0500 M=\frac{n}{0.009 L}[/tex]
n = 0.00045 mol
[tex]Cl^-+AgNO_3\rightarrow AgCl+NO_3^{-}[/tex]
According to 1 mole of silver nitrate reacts with 1 mol of chloride ion, then 0.00045 moles of silver nitrate will :
[tex]\frac{1}{1}\times 0.00045 mol=0.00045 mol[/tex] of chloride ions
Mass of chloride ions :
0.00045 mol × 35.5 g/mol = 0.016 g
0.016 grams of chloride ion were present in the 0.1000 grams of sample.
Calculate the amount of heat released to convert 150.0 g of to water to ice at 0ºC.
-50100 J
-339,000 J
-627 J
-307.5 J
Answer:
There correct answer is option 1 (-50100 J)
Explanation:
Step 1: Data given
Mass of water = 150.0 grams
ΔHfus = 334 J/g
Temperature = 0°C
ΔHfus = the amount of energy needed to change phase of 1 mol water to ice
Step 2: Calculate the amount of heat required
Q = m*ΔHfus
⇒Q = the amount of heat reuired = TO BE DETERMINED
⇒m =the mass of water = 150.0 grams
⇒ΔHfus = 334 J/g
Q = 150.0 grams * 334 J/g
Q = 50100 J of heat required
Step 3: Calculate heat released
Qrequired = -Q released
Qreleased = -50100 J
There correct answer is option 1 (-50100 J)
Answer:
The answer is -50100 J
Explanation:
I just took the test as I'm in GCA as well (11th grade). My teacher walked us through each formula and gave us multiple practice questions in Jigsaw.
Honestly, all you need to be aware of is the fusion formula which is:
q = m*Hfusion
q = amount of energy
m = mass in grams
Hfusion = 334 J/g (it will not change)
Write down what we're given and what we're looking for:
q = ?
m = 150
Hfusion = 334 J/g
Set up the equation:
q = 150 * 334
Multiply 150 by 334 to get 50100.
You must keep in mind that we're finding how much heat is released which means the energy will be negative.
Add the negative sign to the number to get -50100 Joules
I don't know why that chart is there, it doesn't do anything for this equation. Disregard it for this problem.
Hope I helped! :D
The human body can get energy by metabolizing proteins, carbohydrates or fatty acids, depending on the circumstances. Roughly speaking, the energy it gets comes mostly from allowing all the carbon atoms in the food molecules to become oxidized to carbon dioxide by reaction with oxygen from the atmosphere. Hence the energy content of food is roughly proportional to the carbon content. Let's consider stearic acid , a fatty acid from which fats are made, and fructose , one of the simplest carbohydrates. Using the idea above about energy content, calculate the ratio of the energy the body gets metabolizing each gram of stearic acid to the energy the body gets metabolizing each gram of fructose. Round your answer to the correct number of significant digits.
The ratio of energy obtained from metabolizing stearic acid to fructose is 3:1.
Explanation:To calculate the ratio of the energy the body gets metabolizing stearic acid to the energy the body gets metabolizing fructose, we need to compare their carbon content. The molecular formula of stearic acid is C18H36O2, which means it has 18 carbon atoms. The molecular formula of fructose is C6H12O6, which means it has 6 carbon atoms. Since the energy content of food is roughly proportional to the carbon content, we can calculate the ratio by dividing the number of carbon atoms in stearic acid (18) by the number of carbon atoms in fructose (6). This gives us a ratio of 3:1.
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The energy ratio of metabolizing one gram of stearic acid (a fatty acid) to one gram of fructose (a carbohydrate) is 2.25, with stearic acid providing 9 kcal/g and fructose providing 4 kcal/g of energy.
The question asks to calculate the ratio of the energy the body gets metabolizing each gram of stearic acid to the energy the body gets metabolizing each gram of fructose. Stearic acid is a fatty acid, and fructose is a simple carbohydrate. According to the data provided, each gram of carbohydrates yields approximately 4 kcal of energy, while each gram of fat yields about 9 kcal. Therefore, the ratio of energy from fats to carbohydrates is 9 kcal/g to 4 kcal/g.
To calculate the ratio of energy from stearic acid to fructose:
Identify the energy values: 9 kcal/g for stearic acid and 4 kcal/g for fructose.
Divide the energy value of stearic acid by the energy value of fructose: 9 kcal/g \/ 4 kcal/g = 2.25.
This means that metabolizing one gram of stearic acid yields 2.25 times the energy compared to metabolizing one gram of fructose.
Which of the following statements concerning gas pressure is/are correct? (1) Gas pressure arises from gas molecules sticking to the wall of the container holding the gas. (2) The force exerted on the inside walls of a gas-filled container is inversely proportional to the number of gas molecules within the container. (3) As the temperature of a gas increases, gas molecules exert more force on the walls of their container.
Answer:
As the temperature of a gas increases, gas molecules exert more force on the walls of their container.
Explanation:
Pressure is the force exerted by a substance per unit area on another substance. The pressure of a gas is the force that the gas exerts on the walls of its container.
Gases collide frequently with each other and the walls of the container. This pressure of the gas increases with increase in temperature since increase in temperature increases the kinetic energy of gas molecules. They now collide more frequently with the walls of the container hence the answer.
The gas pressure is defined as the force exerted by the gas particles when they collide with the walls of the container. It is the pressure exerted per unit area.
The correct option is:
Option C. As the temperature of a gas increases, gas molecules exert more force on the walls of their container.
The correct explanation can be given as:
The gas molecules are in random motions, and continuously exert pressure on the walls of the container. As the temperature rises, the kinetic energy of the particles is also increased, which causes a faster collision. Thus, the gas pressure is increased as the temperature is increased.
Therefore, option C is correct.
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The decomposition reaction 2 NOCl → 2 NO + Cl_2 has a rate law that is second order with respect to [NOCl], where k = 3.2 M^{-1}s^{-1} at a certain temperature. If the initial concentration of NOCl is 0.076 M, how many seconds will it take for [NOCl] to decrease to 0.042 M at this temperature? Do not enter units with your numerical answer.
For the second-order reaction 2 NOCl → 2 NO + Cl2, it will take 3.32 seconds for the concentration of NOCl to decrease from 0.076 M to 0.042 M.
Explanation:The reaction 2 NOCl → 2 NO + Cl2 is second order with respect to [NOCl], meaning the rate law can be written as rate = k[NOCl]2. Given that k = 3.2 M−1s−1, we can use the integrated rate law for second-order reactions to find the time it takes for the concentration of NOCl to change from 0.076 M to 0.042 M. The integrated rate law for second-order reactions is ¼¾ ϑ¾ = k(t-t0), with t as the time elapsed, t0 as the initial time, and ϑ and ϑ0 as the final and initial concentrations, respectively. Solving for t gives us
t = ¼¾ [ϑ0^{-1} - ϑ^{-1}] / k
Substituting the given values we get:
t = ( ¼¾ [0.076−1 - 0.042−1] ) / 3.2
t = ( ¼¾ [13.16 - 23.81] ) / 3.2
t = ( ¼¾ [-10.65] ) / 3.2
t = 3.32 seconds
Can convection occur in both liquids and
gases? Suggest a reason for your answer
using the particle theory.
Answer:
Yes, Convection can occur in both liquids and gases
Explanation:
The Particle Theory suggests that Particles are always moving. Convection occurs in the breeze you feel, when the warm particles quickly move upwards resulting in cold air quickly sinking and creating a breeze. Convection also occurs when you boil water, the molecules of warm water quickly move to the top and cold water quickly moves to the bottom resulting in a circle the constantly keeps the water circulating, making it boil.
Convert 10 liter into m3.
10 litres = 0.01 cubic meter
what is the molecule OH- called?
Answer:
it hydroxide ion
Hope it will help you
The molecule OH- is termed as a hydroxide ion. It comprises one hydrogen ion and one oxygen ion and holds a negative charge. Hydroxide ions are observed in water-based solutions and play a crucial role in chemical reactions such as hydrolysis; they also impact the pH levels in solutions.
Explanation:The molecule OH- is called a hydroxide ion. This comes from the fact that it consists of one hydrogen ion (H) and one oxygen ion (O). An ion is an atom or molecule that carries a charge, in this case, the charge of the hydroxide ion is -1 because it has gained one electron. Hydroxide ions are found in solutions resulting from the ionization of water.
The molecule OH- plays an important role in various chemical reactions. For example, in hydrolysis, a molecule of water disrupts a compound; the water splits into H and OH. One part of the divided compound bonds with the hydrogen atom, and the other part bonds with the hydroxide group. The presence of hydroxide ions also has a significant effect in determining the pH of a solution; the higher the concentration of hydroxide ions, the more basic or alkaline the solution is.
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Problem 19.24a Using the reagents below, list in order (by letter, no period) those necessary to convert the starting material into the given product: Note: More than 1 mole of the starting material may be used. Not all spaces provided may be needed. Type "na" in any space where you have no reagent. a. heat, -CO2 b. NaOEt c. (CH3CH2)2CuLi d. CH2Cl2, PCC e. C3H7C(O)CH(C2H5)C(O)C2H5 f. CH3CH2Li g. CH3C(O)Cl, AlCl3 h. NBS, ROOR i. H2NC(O)NH2 j. HN(CH3)2 k. OH-, H2O, heat then H3O l. H3O
Answer:
Step 1: The answer is option (b) NaOEt
Step 2: The answer is option (k) OH-, H2O, heat then H3O
Step 3: The answer is option (a) heat, -CO2
Step 4: na (no reagent)
Explanation:
See the attached file for the explanation.
Propose a mechanism for the formation of the monobrominated product. Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges where needed. Electron flow arrows should start on the electron(s) of an
Answer:
The mechanism is SN2
Explanation:
See mechanism of monobromination of alkane attached
Answer:
Explanation:
find the solution below
Gasoline is a remarkably interesting soup of hydrocarbons of various sorts, with bits of this and that added, but the average chemistry is not too far from being carbon and hydrogen, with two hydrogen atoms for each carbon. Burning involves combining gasoline with oxygen to make water and carbon dioxide. (Other things that are made in small quantities, such as carbon monoxide, are not as nice.) The chemical formula for burning gasoline can then be written something like: CH2+1.5 O2 --> CO2+H2O (If you don’t like having one-and-a-half oxygen molecules, you can think of two hydrocarbons plus three oxygens making two carbon dioxides and two waters; it is the same thing, really.) In burning, each carbon atom, C, in gasoline eliminates two hydrogens and replaces them with two oxygens each carbon atom weighs 12 atomic mass units each hydrogen weighs 1 each oxygen weighs 16; So, CH2 starts out weighing 14 (12 from carbon and 2 from hydrogen), and CO2 ends up weighing 44 (12 from carbon and 32 from oxygen)—the weight has more than tripled. Rounding that off a little, the total weight of CO2 put out by a typical U.S. driver is three times larger than the weight of gasoline burned. To get the number of pounds of CO2 per year from a typical car, then, multiply your answer from the previous question by 3.
Answer:GASOLINE IS NOT FUYKING SOUP IF YOU EAT IT YOULL DIE
Explanation:
Just a fair warning
This answer explains that during the combustion of gasoline, each carbon atom forms carbon dioxide (CO₂) and each hydrogen atom forms water (H₂O). This process increases the total mass due to the addition of oxygen atoms, resulting in CO₂ emissions being roughly three times the weight of the gasoline burned.
In this question, we explore the combustion of gasoline, a complex mixture of hydrocarbons. The main reaction for burning gasoline can be approximated by the equation:
CH₂ + 1.5 O₂ → CO₂ + H₂O
This indicates that each carbon atom in the gasoline molecule combines with oxygen to form carbon dioxide (CO₂), while each hydrogen atom combines with oxygen to form water (H₂O). The average chemical formula for gasoline is close to CH₂; thus, if you burn hydrocarbons, the products will primarily be CO₂ and H₂O.
For example, burning gasoline with the empirical formula CH₂ involves replacing two hydrogen atoms with oxygen, resulting in carbon dioxide and water. Here's a more balanced version of the reaction:
2 CH₂ + 3 O₂ → 2 CO₂ + 2 H₂O
This reaction results in a mass increase as the products (CO₂ and H₂O) weigh more than the original reactants (CH₂ and O₂). Specifically, for each carbon atom (12 atomic mass units) and two hydrogen atoms (2 atomic mass units) in the gasoline, the resulting CO₂ and H₂O (carbon dioxide: 44 AMU; water: 18 AMU) demonstrate an overall tripling of mass due to the addition of oxygen atoms.
By understanding this principle, one can estimate that the weight of CO₂ released by burning gasoline is roughly three times the weight of the gasoline itself. This is why a typical car emits a substantially larger mass of CO₂ relative to the fuel it consumes.
In the equation KClO3 -> KCl + O2, how many moles of oxygen are produced when 3.0 mol of KClO3 decomposes completely?
Answer:
4.5
Hope this helps!
In the given chemical equation according to stoichiometry, 4.5 moles of oxygen are produced when 3.0 mole of KClO₃ decomposes completely.
What is stoichiometry?Stoichiometry is the determination of proportions of elements or compounds in a chemical reaction. The related relations are based on law of conservation of mass and law of combining weights and volumes.
Stoichiometry is used in quantitative analysis for measuring concentrations of substances present in the sample. It is important while making solutions and balancing chemical equations.In the given balanced chemical equation, 2 moles of KClO₃ gives 3 moles of oxygen , thus 3 mole of KClO₃ will give 3×3/2=4.5 moles.
Thus, 4.5 moles of oxygen are produced when 3.0 mole of KClO₃ decomposes completely.
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Be sure to answer all parts.
(a) How many atoms are directly bonded to the central atom in a trigonal planar molecule?
i. two
ii. three
iii. six
iv. eight
(b) How many atoms are directly bonded to the central atom in a trigonal bipyramidal molecule?
i. three
ii. four
iii. five
iv. six
(c) How many atoms are directly bonded to the central atom in an octahedral molecule?
i. three
ii. four
iii. six
iv. eight
Answer:
a) ii
b)iii
c)iii
Explanation:
three atoms directly bonded then only it is possible to achieve trigonal planar
trigonal bipyramidal means five atoms should attach to central atom
for octahedral six atoms must directly connected to central atom
Pure platinum is too soft to be used in jewelry because it scratches easily. To increase the hardness so that it can be used in jewelry, platinum is combined with other metals to form an alloy. To determine the amount of platinum in an alloy, a 8.528 g sample of an alloy containing platinum and cobalt is reacted with excess nitric acid to form 2.49 g of cobalt(II) nitrate. Calculate the mass percent of platinum in the alloy.
Answer:
percentage mass of platinum in the alloy ≈ 90.60 %
Explanation:
The alloy is 8.528 g sample of an alloy containing platinum and cobalt . The alloy react with excess nitric acid to form cobalt(ii) nitrate . Platinum is resistant to acid so it will definitely not react with the acid only the cobalt metal in the alloy will react with the acid.
The chemical reaction can be represented as follows:
Co (s) + HNO₃ (aq) → Co(NO₃)₂ (aq) + NO₂ (l) + H₂O (l)
The balanced equation
Co (s) + 4HNO₃ (aq) → Co(NO₃)₂(aq) + 2NO₂ (l) + 2H₂O (l)
Cobalt is the limiting reactant
atomic mass of cobalt = 58.933 g/mol
Molar mass of Co(NO₃)₂ = 58.933 + 14 × 2 + 16 × 6 = 58.933 + 28 + 96 = 182.933 g
58.933 g of cobalt produce 182.933 g of Co(NO₃)₂
? gram of cobalt will produce 2.49 g of Co(NO₃)₂
cross multiply
grams of cobalt that will react = (58.933 × 2.49)/182.933
grams of cobalt that will react = 146.74317000/182.933
grams of cobalt that will react= 0.8021689362 g
grams of cobalt that will react = 0.802 g
mass of platinum in the alloy = 8.528 g - 0.802 g = 7.726 g
percentage mass of platinum in the alloy = 7.726/8.528 × 100 = 772.600/8.528 = 90 .595 %
percentage mass of platinum in the alloy ≈ 90.60 %
besides the ocean where else is water on Earth? Is it always in liquid form?
Answer:
water is everywhere, its in the air and the clouds, in the earth too!
it isnt always liquid form. like when it snows or hails.
Explanation:
Which reaction is an example of heterogeneous catalysis?
Answer:
Explanation:
Industrial examples
Process Reactants, Product(s)
Ammonia synthesis (Haber–Bosch process) N2 + H2, NH3
Nitric acid synthesis (Ostwald process) NH3 + O2, HNO3
Hydrogen production by Steam reforming CH4 + H2O, H2 + CO2
Ethylene oxide synthesis C2H4 + O2, C2H4O
Answer:
The answer is A - Ethene gas reacts with hydrogen gas by using a nickel catalyst.
Explanation:
just did on Edge
g Which compounds are bases in aqueous solution according to Brønsted–Lowry theory?A chain of four carbon atoms connected by single bonds. Single bonds connect the first carbon atom to 3 hydrogen atoms. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom. The single bonded oxygen atom is connected to a hydrogen atom by a single bond. Both oxygen atoms have 2 lone pairs.A chain of 4 carbon atoms connected by single bonds. The first carbon atom is connected to 3 hydrogen atoms by single bonds. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom with 2 lone pairs, and single bonded to 1 oxygen atom with 3 lone pairs. The oxygen atom with 3 lone pairs is marked with a minus sign.
Answer:
A chain of four carbon atoms connected by single bonds. Single bonds connect the first carbon atom to 3 hydrogen atoms. The second and third carbons are each connected to 2 hydrogen atoms by single bonds. The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom. The single bonded oxygen atom is connected to a hydrogen atom by a single bond. Both oxygen atoms have 2 lone pairs.
Explanation:
In the Brownstead-Lowry definition of a base; a base is any substance that accepts a proton. Hence, a base must have available lone pairs to accept a proton and possess a plus sign afterwards. Only the bonding situation described in the answer meets this description.
The description in the second option should be a Brownstead-Lowry acid because it will rather donate a proton.
The compounds that are bases in aqueous solution according to Bronsted-Lowry theory is ; ( A , B, C, D and E ).
A chain of four carbon atoms connected by single bonds.Single bonds connect the first carbon atom to 3 hydrogen atomsThe second and third carbons are each connected to 2 hydrogen atoms by single bonds.The fourth carbon atom is double bonded to 1 oxygen atom and single bonded to 1 oxygen atom.The single bonded oxygen atom is connected to a hydrogen atom by a single bond.Both oxygen atoms have 2 lone pairs.Bronsted-Lowry theory states that a compound which is capable of accepting protons from another compound is a base while a compound that transfers protons to other compounds is categorised as an acid. The compounds listed in the answer are capable of accepting protons because of the availability of lone pairs of protons.
Hence we can conclude that the compounds that re bases in aqueous solutions are as listed above.
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An alkyne with the molecular formula C6H10 was treated with ozone followed by water to produce only one type of carboxylic acid. Draw the structure of the starting alkyne and the product of ozonolysis.
The starting alkyne is 3-hexyne, and after the ozonolysis process and treatment with water, the resulted product is hexanoic acid.
Explanation:In the given question, an alkyne with the molecular formula C6H10 is treated with ozone followed by water, to produce one type of carboxylic acid via the process of ozonolysis. The starting alkyne for this reaction probably is 3-hexyne. During ozonolysis, the alkyne triple bond is cleaved, forming two equivalent aldehydes. But these aldehydes are further oxidized into carboxylic acids when water is used as second reagent. The produced product, hence, is hexanoic acid.
Remember, in the process of ozonolysis, alkynes are oxidized and cleaved into smaller molecules. These molecules usually have carbonyl groups such as aldehydes and ketones. But in this scenario, because of the hydration step, we end up with a carboxylic acid.
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The compound most likely to be ionic is: carbon tetrachloride, potassium fluoride, carbon dioxide, or iodine monochloride?
Answer:
Potassium fluoride
Explanation:
Because potassium is strongly electropositive combined ionically with Fluorine which is highly electronegative this has the greatest tendency of been ionic
You are given 25.00 mL of an acetic acid solution of unknown concentration. You find it requires 35.75 mL of a 0.1950 M NaOH solution to exactly neutralize this sample (phenolphthalein was used as an indicator). What is the molarity of the acetic acid solution? What is the percentage of acetic acid in the solution?
Answer:
0.2788 M
1.674 %(m/V)
Explanation:
Step 1: Write the balanced equation
NaOH + CH₃COOH → CH₃COONa + H₂O
Step 2: Calculate the reacting moles of NaOH
[tex]0.03575 L \times \frac{0.1950mol}{L} = 6.971 \times 10^{-3} mol[/tex]
Step 3: Calculate the reacting moles of CH₃COOH
The molar ratio of NaOH to CH₃COOH is 1:1.
[tex]6.971 \times 10^{-3} molNaOH \times \frac{1molCH_3COOH}{1molNaOH} = 6.971 \times 10^{-3} molCH_3COOH[/tex]
Step 4: Calculate the molarity of the acetic acid solution
[tex]M = \frac{6.971 \times 10^{-3} mol}{0.02500L} =0.2788 M[/tex]
Step 5: Calculate the mass of acetic acid
The molar mass of acetic acid is 60.05 g/mol.
[tex]6.971 \times 10^{-3} mol \times \frac{60.05g}{mol} =0.4186 g[/tex]
Step 6: Calculate the percentage of acetic acid in the solution
[tex]\frac{0.4186g}{25.00mL} \times 100\% = 1.674 \%(m/V)[/tex]
Answer:
Concentration acetic acid = 0.27885 M
% acetic acid = 0.69%
Explanation:
You are given 25.00 mL of an acetic acid solution of unknown concentration. You find it requires 35.75 mL of a 0.1950 M NaOH solution to exactly neutralize this sample (phenolphthalein was used as an indicator). What is the molarity of the acetic acid solution?
what is the percentage of acetic acid in the solution? Assume the density of the solution is 1 g/ml.
Step 1: Data given
Volume of acetic acid = 25.00 mL = 0.025 L
Volume of NaOH = 35.75 mL = 0.03575 L
Molarity of NaOH = 0.1950 M
Step 2: The balanced equation
CH3COOH + NaOH → CH3COONa + H2O
Step 3: Calculate moles
Moles = molarity * volume
Moles NaOH = 0.1950 M * 0.03575 L
Moles NaOH = 0.00697125 moles
Step 4: Calculate concentration of acetic acid
We need 0.00697125 moles of acetic acid to neutralize NaOH
Concentration = moles / volume
Concentration = 0.00697125 moles / 0.025 L
Concentration = 0.27885 M
Step 5: Calculate mass of acetic acid
Mass acetic acid = moles * molar mass
Mass acetic acid = 0.00697125 moles * 60.05g/mol
Mass acetic acid = 0.4186 grams
Step 6: Calculate mass of sample
Total volume = 60.75 mL = 0.06075 L
Mass of sample 60.75 mL * 1g/mL = 60.75 grams
Step 7: Calculate the percentage of acetic acid in the solution
% acetic acid = (0.4186 grams / 60.75 grams ) * 100 %
% acetic acid = 0.69%
What will be the pH of 1.0 mol dm-3 of NH4OH, which is 1% dissociated
The pH of this solution is 12.
We can solve this question knowing that the ammonium hydroxide, NH₄OH, dissociates in water as follows:
NH₄OH(aq) ⇄ NH₄⁺(aq) + OH⁻(aq)
Based on the reaction, 1 mole of NH₄OH produces 1 mole of OH⁻
With this molarity and the 1% dissociated we can find the molarity of OH⁻. With molarity of OH⁻ we can find pOH (pOH = -log[OH⁻]) and pH (pH = 14-pOH) as follows:
Molarity OH⁻:
A solution 1.0mol dm⁻³ = 1M of NH₄OH produce 1% of OH⁻ ions because only 1% is dissociate, that is:
[tex]1M NH_4OH*(\frac{1MOH^-}{100MNH_4OH}) = 0.01M OH^-[/tex]
Now, we can find pOH as follows:
pOH:
pOH = -log [OH⁻] = 2
And pH:
pH:
pH = 14 - pOH
pH = 12
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The copper(I) ion forms a chloride salt (CuCl) that has Ksp = 1.2 x 10-6. Copper(I) also forms a complex ion with Cl-:Cu+ (aq) + 2Cl- (aq) ⇄ CuCl2- (aq) K = 8.7 x 104(a) Calculate the solubility of CuCl in pure water. (Ignore CuCl2- formation for part a).(b) Calculate the solubility of CuCl in 0.100 M NaCl solution.
Answer: (a) The solubility of CuCl in pure water is [tex]1.1 \times 10^{-3} M[/tex].
(b) The solubility of CuCl in 0.1 M NaCl is [tex]9.5 \times 10^{-3} M[/tex].
Explanation:
(a) Chemical equation for the given reaction in pure water is as follows.
[tex]CuCl(s) \rightarrow Cu^{+}(aq) + Cl^{-}(aq)[/tex]
Initial: 0 0
Change: +x +x
Equilibm: x x
[tex]K_{sp} = 1.2 \times 10^{-6}[/tex]
And, equilibrium expression is as follows.
[tex]K_{sp} = [Cu^{+}][Cl^{-}][/tex]
[tex]1.2 \times 10^{-6} = x \times x[/tex]
x = [tex]1.1 \times 10^{-3} M[/tex]
Hence, the solubility of CuCl in pure water is [tex]1.1 \times 10^{-3} M[/tex].
(b) When NaCl is 0.1 M,
[tex]CuCl(s) \rightarrow Cu^{+}(aq) + Cl^{-}(aq)[/tex], [tex]K_{sp} = 1.2 \times 10^{-6}[/tex]
[tex]Cu^{+}(aq) + 2Cl^{-}(aq) \rightleftharpoons CuCl_{2}(aq)[/tex], [tex]K = 8.7 \times 10^{4}[/tex]
Net equation: [tex]CuCl(s) + Cl^{-}(aq) \rightarrow CuCl_{2}(aq)[/tex]
[tex]K' = K_{sp} \times K[/tex]
= 0.1044
So for, [tex]CuCl(s) + Cl^{-}(aq) \rightarrow CuCl_{2}(aq)[/tex]
Initial: 0.1 0
Change: -x +x
Equilibm: 0.1 - x x
Now, the equilibrium expression is as follows.
K' = [tex]\frac{CuCl_{2}}{Cl^{-}}[/tex]
0.1044 = [tex]\frac{x}{0.1 - x}[/tex]
x = [tex]9.5 \times 10^{-3} M[/tex]
Therefore, the solubility of CuCl in 0.1 M NaCl is [tex]9.5 \times 10^{-3} M[/tex].
Final answer:
The solubility of CuCl in pure water and in 0.100 M NaCl solution both turn out to be 1.1 x 10^-3 M when formation of CuCl2- is ignored, determined using the provided Ksp.
Explanation:
To calculate the solubility of CuCl in pure water, we can use the solubility product constant (Ksp). The dissociation of CuCl can be represented as:
CuCl(s) ⇌ Cu+(aq) + Cl-(aq)
Let the solubility of CuCl be 's' moles per liter. At equilibrium, the concentration of Cu+ and Cl- ions will both be 's' M. So, the Ksp expression for CuCl is:
Ksp = [Cu+][Cl-] = (s)(s) = s²
Giving us:
s = √(1.2 x 10^-6) = 1.1 x 10^-3 M
This is the solubility of CuCl in pure water.
For the solubility of CuCl in 0.100 M NaCl solution, we have to consider the common ion effect. In this case, Cl- is the common ion. With the presence of 0.100 M NaCl, the concentration of Cl- ions at equilibrium will be higher. However, since we ignore the formation of CuCl2-, the solubility will still be governed by the Ksp of CuCl. The calculation will remain the same as in pure water, due to the assumption of ignoring CuCl2- formation:
s = 1.1 x 10^-3 M
Therefore, the presence of NaCl does not affect the solubility under the given conditions for this specific case.
A mixture of compounds containing diethylamine, phenol, ammonia, and acetic acid is separated using liquid-liquid extraction as follows: Step 1: Concentrated HCl is added followed by draining the aqueous layer. Step 2: Dilute NaOH is added to the organic layer followed by draining the aqueous layer. Step 3: Concentrated NaOH is added to the organic layer followed by draining the aqueous layer. Which compound would you expect to be extracted into the aqueous layer after the addition of dilute NaOH, step 2?
Answer:
I would expect to extract the acetic acid.
Explanation:
In the first step, since we are adding a concentrated acid, it will react with the bases present in the mixture (diethylamine and ammonia) forming salts, which are soluble in water. Therefore, after draining the aqueous layer, we will have phenol and acetic acid left in the organic layer.
In the second step, we are adding a diluted base, so it will react with a strong acid. This compound is acetic acid, and its salt will be present in the aqueous layer. Phenol will be left on the organic layer.
what do you think could be happening to the sand eels
Answer:
is there like a passage to answer this question?
Explanation:
Answer:
Increasing fishing for them is thought to be causing problems for some of their natural predators, especially the auks which take them in deeper water. They are also tied as flies to catch fish. An instance of this was the RSPB report linking a population crash of seabirds in the North Sea to fishing for sand eels.
Explanation:
A chemist fills a reaction vessel with 9.20 atm nitrogen monoxide (NO) gas, 9.15 atm chlorine (CI) gas, and 7.70 atm nitrosyl chloride (NOCI) gas at a temperature of 25.0°C. Under these conditions, calculate the reaction free energy AG for the following chemical reaction: 2NO(g) +CI (8) - 2NOCI (8) Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoule
Answer:
The reactions free energy [tex]\Delta G = -49.36 kJ[/tex]
Explanation:
From the question we are told that
The pressure of (NO) is [tex]P_{NO} = 9.20 \ atm[/tex]
The pressure of (Cl) gas is [tex]P_{Cl} = 9.15 \ atm[/tex]
The pressure of nitrosly chloride (NOCl) is [tex]P_{(NOCl)} = 7.70 \ atm[/tex]
The reaction is
[tex]2NO_{(g)} + Cl_2 (g)[/tex] ⇆ [tex]2 NOCl_{(g)}[/tex]
From the reaction we can mathematically evaluate the [tex]\Delta G^o[/tex] (Standard state free energy ) as
[tex]\Delta G^o = 2 \Delta G^o _{NOCl} - \Delta G^o _{Cl_2} - 2 \Delta G^o _{NO}[/tex]
The Standard state free energy for NO is constant with a value
[tex]\Delta G^o _{NO} = 86.55 kJ/mol[/tex]
The Standard state free energy for [tex]Cl_2[/tex] is constant with a value
[tex]\Delta G^o _{Cl_2} = 0kJ/mol[/tex]
The Standard state free energy for [tex]NOCl[/tex] is constant with a value
[tex]\Delta G^o _{NOCl} =66.1kJ/mol[/tex]
Now substituting this into the equation
[tex]\Delta G^o = 2 * 66.1 - 0 - 2 * 87.6[/tex]
[tex]= -43 kJ/mol[/tex]
The pressure constant is evaluated as
[tex]Q = \frac{Pressure \ of \ product }{ Pressure \ of \ reactant }[/tex]
Substituting values
[tex]Q = \frac{(7.7)^2 }{(9.2)^2 (9.15) } = \frac{59.29}{774.456}[/tex]
[tex]= 0.0765[/tex]
The free energy for this reaction is evaluated as
[tex]\Delta G = \Delta G^o + RT ln Q[/tex]
Where R is gas constant with a value of [tex]R = 8.314 J / K \cdot mol[/tex]
T is temperature in K with a given value of [tex]T = 25+273 = 298 K[/tex]
Substituting value
[tex]\Delta G = -43 *10^{3} + 8.314 *298 * ln [0.0765][/tex]
[tex]= -43-6.36[/tex]
[tex]\Delta G = -49.36 kJ[/tex]
1) Analysis subquestions (7 points): (a) Draw the mechanism of the reaction - remember, there are two main parts to the aldol condensation, the addition step, followed by the elimination. (b) Explain why your reaction forms the enone product, rather than the hydroxyketone intermediate. 2) Critical analysis (7 points): a) You have been given a 1H NMR spectrum of your product. Fully assign this spectrum (i.e. determine which peaks in the 1H NMR correspond to which hydrogens in the product). The peaks have been labeled 1-8 on the spectrum, and the relevant hydrogens Ha-Hh below. b) Calculate the coupling constant between He and Hf. Explain how can this can help determine the stereochemistry (i.e. cis vs. trans) of the double bond. (7) Acetone is a symmetrical molecule, so there are two positions that can react. Draw the product you would expect to obtain if you used two molar equivalents of vanillin rather than one. c) Acetone is a symmetrical molecule, so there are two positions that can react. Draw the product you would expect to obtain if you used two molar equivalents of vanillin rather than one.
Find the attachments
A 25.888 g sample of aqueous waste leaving a fertilizer manufacturer contains ammonia. The sample is diluted with 73.464 g of water. A 10.762 g aliquot of this solution is then titrated with 0.1039 M HCl . It required 31.89 mL of the HCl solution to reach the methyl red endpoint. Calculate the weight percent NH3 in the aqueous waste.
Answer:
Weight % of NH₃ in the aqueous waste = 2.001 %
Explanation:
The chemical equation for the reaction
[tex]\\\\NH_3} + HCl -----> NH_4Cl[/tex]
Moles of HCl = Molarity × Volume
= 0.1039 × 31.89 mL × [tex]\frac{1 \ L}{1000 \ mL}[/tex]
= 0.0033 mole
Total mass of original sample = 25.888 g + 73.464 g
= 99.352 g
Total HCl taken for assay = [tex]\frac{10.762 \ g}{99.352 \ g}[/tex]
= 0.1083 g
Moles of NH₃ = [tex]\frac{0.0033 \ mol}{0.1083}[/tex]
= 0.03047 moles
Mass of NH₃ = number of moles × molar mass
Mass of NH₃ = 0.03047 moles × 17 g
Mass of NH₃ = 0.51799
Weight % of NH₃ = [tex]\frac{0.51799 \ g}{25.888 \ g} * 100%[/tex]%
Weight % of NH₃ in the aqueous waste = 2.001 %
Conceptual Checkpoint 18.13 When 1,3-dinitrobenzene is treated with nitric acid and sulfuric acid at elevated temperature, the product is 1,3,5-trinitrobenzene. Draw the sigma complex for each possible pathway to compare the relative stability of each sigma complex. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph.
Using sulfuric acid in the nitration of benzene generates a more reactive nitronium ion, which then reacts with benzene. The detailed mechanisms of nitration and sulfonation involve sigma complexes with resonance stabilization. An energy diagram for nitration shows intermediates and activation energy.
The importance of using sulfuric acid in the nitration of benzene by nitric acid is to activate the HNO₃, creating a more reactive electrophile, the nitronium ion (NO₂+). This ion then reacts with benzene to form nitrobenzene. In the mechanism of the sulfonation of benzene, sulfur trioxide (SO₃) acts as the electrophile, which is generated from sulfuric acid. The detailed mechanisms for both reactions involve the formation of a sigma complex with resonance forms and the restoration of aromaticity through deprotonation.
For the nitration of benzene, an energy diagram shows the activation energy and intermediates formed. The sigma complex for 1,3-dinitrobenzene undergoing further nitration to form 1,3,5-trinitrobenzene illustrates how the meta position stabilizes the complex by avoiding the creation of high-energy intermediates with adjacent positive charges, as seen in ortho and para substitution.
The equations representing the nitration and sulfonation of benzene are as follows:
Nitration: C₆H₆ + HNO₃ -> C₆H₅NO₂ + H₂OSulfonation: C₆H₆ + SO₃/H₂SO₄ -> C₆H₅SO₃H + H₂OYou have two beakers. One beaker contains 100 mL of NaOH (a strong base); the other contains 100 mL of aqueous Na3PO4 (a weak base). You test the pH of each solution. Which of the following statements is true ?
Answer:
D. If the pH of NaOH is 12, then that of Na₃PO₄ solution has to be lesser than 12.
Explanation:
In this problem, we are comparing the pH of a strong base to a weak base. A strong base is one that ionizes completely in aqueous solutions where as a weak base ionizes slightly.
The pH scale is good tool for measuring the acidity and alkalinity of various substances. It ranges from 1 - 14;
1 7 14
← →
increasing acidity increasing alkalinity
neutrality
Strong bases have their pH value close to 14 and weak bases are close to 7.
Since Na₃PO₄ is a weak base, it will have lesser pH value compared to a strong base such as NaOH
The question lack options, that are as follows"
a. The Na3PO4 has a higher pH because it has more sodium ions than NaOH. NaOH(aq- Na3PO4(aq)b. It is possible for the solutions in each beaker to have the same pHC. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be greater than 12.00.d. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be less than 12.00.The following statements are true in the given question:
d. If the pH of the NaOH solution is 12.00, the pH of the Na3PO4 solution has to be less than 12.00.We know that:
NaOH is a strong base and Na3PO4 is a weak base. As the strength of OH- in 100ml NaOH and that of OH- in 100ml Na3PO4 is different. They have different pH values. As we know that pH is inversely proportional to H+ ion concentration. This means the higher the pH value lower is H+ ion concentration.Again,
PH +POH =14
From the above equation,
the higher the PH value of a solution less will be its value of POH vice versa. Hence greater is the OH- ion concentration.So,
the pH of a solution is directly proportional to OH-ion concentration.Thus, If pH NaOH = 12.00, NaOH is a strong base and Na3PO4 is a weak base. For the solution, the weak base OH-ion concentration is less. Clearly, the pH of Na3PO4 is less than 12.00.
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