Answer:
(B) ethyl-propyl-ether
Explanation:
ethyl-propyl-ether
a step by step explanation
As the compound has ether as functional group the name of the compound is ethyl propyl ether.
Functional group is defined as a substituent or group of toms or an atom which causes chemical reactions.Each functional group will react similarly regardless to the parent carbon chain to which it is attached.This helps in prediction of chemical reactions.
The reactivity of functional group can be enhanced by making modifications in the functional group .Atoms present in functional groups are linked to each other by means of covalent bonds.They are named along with organic compounds according to IUPAC nomenclature.
The compound has ether as functional group,thus the name of the compound is ethyl propyl ether.
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Between HClO3 and HIO3, which is stronger and why? Question 16 options: 1) HClO3 is stronger because chlorine is in a higher oxidation state than iodine. 2) HClO3 is stronger because chlorine is more electronegative than iodine. 3) HIO3 is stronger because iodine is in a higher oxidation state than chlorine. 4) HIO3 is stronger because iodine is less electronegative than chlorine.
Answer:
2) HClO3 is stronger because chlorine is more electronegative than iodine.
Explanation:
The more electronegative the element is the more strong or acidic it becomes.
Chlorine being more electronegative than Iodine makes it easier for it to pull the electron of hydrogen more strongly and hence has a higher tendency to release a H+ unit. Hence that makes it stronger.
HClO3 is stronger than HIO3 because chlorine is more electronegative than iodine.
Chloric acid (HClO3) is more stronger than Iodic acid (HIO3) because chlorine is more electronegative than iodine. As we go from top to bottom in the periodic table, the atomic size increases and electronegativity decreases.
Electronegativity is the ability of an atom to attract electron pair towards itself. Chlorine atom comes on the top whereas iodine is present lower than chlorine in the periodic table so the atomic size of chlorine is smaller and higher value of electronegativity as compared to iodine so we can conclude that Chloric acid (HClO3) is more stronger than Iodic acid (HIO3).
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For a pure substance, the liquid and gaseous phases can only coexist for a single value of the pressure at a given temperature. Is this also the case for an ideal solution of two volatile liquids?
Answer:
No, it is not.
Explanation:
Most solutions do not behave ideally. Designating two volatile substances as A and B, we can consider the following two cases:
Case 1: If the intermolecular forces between A and B molecules are weaker than those between A molecules and between B molecules, then there is a greater tendency for these molecules to leave the solution than in the case of an ideal solution. Consequently, the vapor pressure of the solution is greater than the sum of the vapor pressures as predicted by Raoult’s law for the same concentration. This behavior gives rise to the positive deviation.
Case 2: If A molecules attract B molecules more strongly than they do their own kind, the vapor pressure of the solution is less than the sum of the vapor pressures as predicted by Raoult’s law. Here we have a negative deviation.
The benzene/toluene system is an exception, since that solution behaves ideally.
No, in the case of an ideal solution of two volatile liquids the two substances at different state cannot coexist for a single value of pressure at a given temperature.
The ideal solution of the two volatile liquids can exist on different ranges of pressure. Their pressure can be limited to an extent at which either only a trace value of liquid remains and the pressure at which only a trace value of gas exists.Learn more about gas:
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To make use of an ionic hydrate for storing solar energy, you place 422.0 kg of sodium sulfate decahydrate on your house roof. Assuming complete reaction and 100% efficiency of heat transfer, how much heat (in kJ) is released to your house at night
Complete Question
To make use of an ionic hydrate for storing solar energy, you place 422.0 kg of sodium sulfate decahydrate on your house roof. Assuming complete reaction and 100% efficiency of heat transfer, how much heat (in kJ) is released to your house at night? Note that sodium sulfate decahydrate will transfer 354 kJ/mol.
Answer:
The amount of energy released is [tex]x = 4.63650 *10^5 KJ[/tex]
Explanation:
Number of moles is mathematically represented as
[tex]n =\frac{mass}{Molar\ Mass}[/tex]
substituting [tex]422.0kg = 422 *10^3g[/tex] for mass of sodium sulfate decahydrate([tex]Na_2 SO_4 \cdot 10H_2 O[/tex]), [tex]322.2g/mol[/tex] (This value is a constant )for the molar mass of sodium sulfate decahydrate
[tex]n= \frac{422*10^3}{322.2}[/tex]
[tex]= 1309.7 \ moles[/tex]
From the question we are told that
1 mole of sodium sulfate decahydrate generates [tex]354KJ[/tex] of energy
So 1309.7 mole would generate x
Now stating the relation mathematically
1 mol → 354KJ
1309.7 mol → x
=> [tex]x = 4.63650 *10^5 KJ[/tex]
Determine the volume (in L) of Cl2(g) required to carry out the following reaction at 794 torr and 625°C using 15.0 g of Fe. The value of R = 0.0821 L atm mol−1 K−1. 2Fe(s) + 3Cl2(g) = 2FeCl3(s)
Answer:
28.5 L of Cl
Explanation:
From PV=nRT
P= 794torr or 1.04 atm
T= 625°C or 898K
R= 0.0821 L atm mol−1 K−1
n= 3 moles
V= ???
V= nRT/P
V=3× 0.0821× 898/1.04
V= 212.7 L
From the balanced reaction equation
112g of iron reacted with 212.7L of Cl
15.0 g of iron will react with 15.0×212.7/112
= 28.5 L of Cl
The formation of ClF (chlorine monofluoride) from its elements has an equilibrium constant of 22.3 at room temperature. Which of the following statements is correct if chlorine gas and fluorine gas are mixed at room temperature?
The reaction will form products until equilibrium is established
Products are quickly formed
A negligible amound of ClF is formed
Products are slowly formed
Answer:
A the reaction will form
Explanation:
The scientist finds fossilized remains of other species in the same rock layer as the trilobite. What can the scientist conclude about
these other fossils?
The Organisms that formed them likely lived during the Paleozoic era.
Final answer:
When trilobite fossils are found alongside other species in the same rock layer, a scientist can infer that these organisms lived during the same time period and may have had similar environmental conditions. Trilobites are used as index fossils which can determine the age of the rocks they are in due to their distinct presence in the geological record from 500 to 600 million years ago.
Explanation:
When a scientist discovers fossilized remains of other species in the same rock layer as a trilobite, they can draw some important conclusions. Since trilobites were widespread marine animals that lived between 500 and 600 million years ago, any other fossils found within the same stratum are likely from the same geological period. This is due to the principle of superposition, which states that in any undisturbed sequence of rocks deposited in layers, the youngest layer is on top and the oldest on bottom, each layer being younger than the one beneath it and older than the one above it.
Furthermore, trilobites are known as index fossils because they were widespread, rapidly evolving, and limited in geological time. Therefore, they serve as indicators of the age of the rock layer in which they are found. Discovering other species in conjunction with trilobite fossils suggests that these organisms also lived during the same time period and may have shared similar environments. This can be used to infer that these species are from the same age and geological period as the trilobites.
The study of these fossils can provide invaluable insight into the biodiversity and ecological conditions of prehistoric marine environments. Moreover, these findings contribute to our understanding of evolutionary history and may help to identify patterns of mass extinction or other significant pale ontological events.
A solution is to be prepared with a sodium ion concentration of 0.513 mol/L. What mass of sodium sulfate (g) is needed to prepare 1.98 liters of such a solution? Do not enter units with your answer.
Answer:
We should weigh 72.1 of sodium sulfate
Explanation:
The solution must be made of sodium sulfate. This salt can be dissociated like this:
Na₂SO₄ → 2Na⁺ + SO₄⁻²
From this dissociation we can say that, 2 moles of sodium cation are obtained from 1 mol of salt.
Therefore 0.513 moles of sodium cation will be obtained from 0.2565 moles of salt (0.513 . 1) / 2. The thing is that this number are the moles contained in 1 L of solution, and we need to prepare such 1.98 L
Molarity = mol / Volume (L) → Molarity . volume (L) = mol
0.2565 mol/L . 1.98L = 0.508 moles
These are the moles we should weigh. Let's convert them to moles:
0.508 mol . 142.06 g / 1 mol = 72.1 g
Answer:
We need 72.1 grams of Na2SO4
Explanation:
Step 1: Data given
sodium ion concentration = 0.513 mol/L
Volume = 1.98 L
Step 2: The balanced equation
Na2SO4 → 2Na+ + SO4^2-
Step 3: Calculate moles Na+
Moles Na+ = molarity Na+ * volume
Moles Na+ = 0.513 * 1.98 L
Moles Na+ = 1.01574 moles
Step 4: Calculate moles Na2SO4
For 1 mol Na2SO4 we need 2 moles Na+ and 1 mol SO4^2-
For 1.01574 moles Na+ we'll need 1.01574/2 = 0.50787 moles Na2SO4
Step 5: Calculate moles Na2SO4
Mass Na2SO4 = moles Na2SO4 * molar mass Na2SO4
Mass Na2SO4 = 0.50787 moles * 142.04 g/mol
Mass Na2SO4 = 72.1 grams
We need 72.1 grams of Na2SO4
Predict the products of the reaction below. That is, complete the right-hand side of the chemical equation. Be sure your equation is balanced and contains state symbols after every reactant and product.
The given question is incomplete. The complete question is :
Predict the products of the reaction below. That is, complete the right-hand side of the chemical equation. Be sure your equation is balanced and contains state symbols after every reactant and product
[tex]HNO_3(aq)+H_2O(l)\rightarrow[/tex]
Answer: The complete equation is [tex]HNO_3(aq)+H_2O(l)\rightarrow NO_3^-(aq)+H_3O^+(aq)[/tex]
Explanation:
According to the Bronsted-Lowry conjugate acid-base theory, an acid is defined as a substance which looses donates protons and thus forming conjugate base and a base is defined as a substance which accepts protons and thus forming conjugate acid.
[tex]HNO_3[/tex] being a strong acid dissociates to give [tex]H^+[/tex] ions an [tex]H_2O[/tex] will act as base and accept [tex]H^+[/tex] to form [tex]H_3O^+[/tex]
Thus the complete equation is [tex]HNO_3(aq)+H_2O(l)\rightarrow NO_3^-(aq)+H_3O^+(aq)[/tex]
Nitrogen and hydrogen gases are combined at high temperatures and pressures to produce ammonia, NH3. If 101.7 g of N2 are reacted with excess H2, how many moles of NH3 will be formed
Answer:
7.26 moles of NH₃ are formed in this reaction
Explanation:
This is about the reaction for the production of ammonia
1 mol of nitrogen gas reacts to 3 moles of hydrogen in order to produce 2 moles of ammonia.
The equation is: N₂ + 3H₂ → 2NH₃
In the question, we were informed that the excess is the H₂ so the N₂ is limiting reagent. We determine the moles, that has reacted:
101.7 g / 28 g/mol = 3.63 moles
So, If 1 mol of nitrogen gas can produce 2 moles of ammonia
3.63 moles of N₂ must produce ( 2 . 3.63) / 1 = 7.26 moles of NH₃
Answer:
In this reaction, 7.26 moles of NH3 will be formed.
Explanation:
Step 1: Data given
Mass of N2 = 101.7 grams
Molar mass N2 = 28.0 g/mol
H2 is in excess
Molar mass H2 = 2.02 g/mol
Molar mass of NH3 = 17.03 g/mol
Step 2: The balanced equation
N2(g) + 3H2(g) → 2NH3(g)
Step 3: Calculate moles N2
Moles N2 = mass N2/ molar mass N2
Moles N2 = 101.7 grams / 28.0 g/mol
Moles N2 = 3.63 moles
Step 4: Calculate moles NH3
For 1 mol N2 we need 3 moles H2 to produce 2 moles NH3
For 3.63 moles N2 we'll produce2*3.63 = 7.26 moles NH3
In this reaction, 7.26 moles of NH3 will be formed.
An aqueous solution is 3.23M in tartaric acid (C4H06). The solution's density is 1.023 g/mL.
Calculate the solution's molality in tartaric acid.
Answer:
Molality = 6.0 m
Explanation:
The molecular weight of tartaric acid = 150.087 g/mol
Given that:
Density of the solution = 1.023 g/mL
Molarity = 3.23M
Density is given as : [tex]Molarity ( \frac{1}{molality } +\frac{mol.wt}{1000} )[/tex]
∴
[tex]1.023 = 3.23 (\frac{1}{molality } +\frac{150.087}{1000} )[/tex]
[tex]\frac{1}{molality } =( \frac{1.023}{3.23} - \frac{150.087}{1000} )[/tex]
[tex]\frac{1}{molality } =0.3167 - 0.1500[/tex]
[tex]\frac{1}{molality } = 0.1667[/tex]
Molality = [tex]\frac{1}{0.1667}[/tex]
Molality = 5.999 m
Molality ≅ 6.0 m
Use the reaction data in the table below to select the answer choice that best describes this reaction.
Reaction Enthalpy Change
345.7 kJ/mol
Reaction Entropy Change
-25. 3 J/molK
This reaction is never spontaneous.
This reaction is spontaneous at all temperatures.
This reaction is spontaneous at low temperatures.
This reaction is spontaneous at high temperatures
Answer: This reaction is never spontaneous
Explanation:
According to Gibbs equation:
[tex]\Delta G=\Delta H-T\Delta S[/tex]
[tex]\Delta G[/tex] = Gibb's free energy change
[tex]\Delta H[/tex] = enthalpy change
T = temperature
[tex]\Delta S[/tex] = entropy change
A reaction becomes spontaneous when [tex]\Delta G[/tex] = Gibb's free energy change is negative.
[tex]\Delta G=+ve-T(-ve)[/tex]
[tex]\Delta G=+ve+ve[/tex]
[tex]\Delta G=+ve[/tex]
Thus this reaction is never spontaneous
A student dissolves 11.1 g of potassium hydroxide (KOH) in 250. g of water in a well-insulated open cup. He then observes the temperature of the water rise from 23.0 °C to 34.0 °C over the course of 4.6 minutes.
Use this data, and any information you need from the ALEKS Data resource, to answer the questions below about this reaction:
KOH(s) â K (aq) + OH (aq)
You can make any reasonable assumptions about the physical properties of the solution. Be sure answers you calculate using measured data are rounded to the correct number of significant digits.
Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction.
Is this reaction exothermic, endothermic, or neither?
The dissolution of potassium hydroxide (KOH) in water is an exothermic process, as indicated by the increase in temperature when KOH is dissolved in water.
Explanation:The dissolution of potassium hydroxide (KOH) in water is an exothermic process. This can be determined based on the observation that the temperature of the water increased from 23.0°C to 34.0°C when 11.1 g of KOH was dissolved in 250.0 g of water. The positive change in temperature indicates that heat was released by the KOH dissolving in water, resulting in an increase in temperature.
The reaction is exothermic as the temperature of the water rises from 23.0°C to 34.0°C, indicating the release of heat.
To determine if the reaction is exothermic or endothermic, we need to look at the temperature change during the dissolution of potassium hydroxide (KOH).
Since the temperature of the water rises from 23.0 °C to 34.0 °C, which is an increase of 11.0 °C, this indicates that the solution absorbs heat.
This increase in temperature demonstrates that the reaction releases heat into the surroundings, thus it is an exothermic reaction. In an exothermic reaction, the temperature of the surroundings rises because energy is released.
Example Calculation:
Mass of water (m): 250 g
Specific heat capacity (C) of water: 4.184 J/g°C
Temperature change (ΔT): 34.0 °C - 23.0 °C = 11.0 °C
Heat (q) absorbed by the solution: q = m × C × ΔT = 250 g × 4.184 J/g°C × 11.0 °C = 11, 506 J or 11.506 kJ
Since the heat is released by the dissolution of KOH, the reaction is said to be exothermic.
Qualitative measurements involve numerical measurements while quantitative measurements record descriptions.
Question 5 options:
True
False
Which words or phrases identify the types of temperate climates? Check all that apply.
humid continental
highland
it is actually science on the subject but it doesn't have that option.
marine west coast
Mediterranean
subarctic
tropical wet-dry
Answer:
Humid Continental
Marine west coast
Mediterranean
subarctic
Explanation:
just did assignment on edge
Marine west coast and Mediterranean are the types of temperate climates, due to the dispersion of precipitation throughout the year, temperate marine climates are typically distinguished by a notable lack of dry season, hence options D and E are correct.
What is temperate climates?Temperate climates are regions with moderate annual or seasonal rainfall, intermittent drought, mild to warm summers, and cool to cold winters.
Humid subtropical, marine west coast, Mediterranean are the phrases that clearly identified with temperate marine climates.
Geographically speaking, the moderate climates of Earth are found in the middle latitudes, which are halfway between the tropics and the poles.
Therefore, options D and E are correct.
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At 500 K the reaction 2 NO(g) + Cl2(g) ⇌ 2 NOCl(g) has Kp = 51 In an equilibrium mixture at 500 K, the partial pressure of NO is 0.125 atm and Cl2 is 0.165 atm. What is the partial pressure of NOCl in the equilibrium mixture?
Answer:
p3=0.36atm (partial pressure of NOCl)
Explanation:
2 NO(g) + Cl2(g) ⇌ 2 NOCl(g) Kp = 51
lets assume the partial pressure of NO,Cl2 , and NOCl at eequilibrium are P1 , P2,and P3 respectively
[tex]Kp=\frac{[NOCl]^{2} }{[NO]^{2} [Cl_2] }[/tex]
[tex]Kp=\frac{[p3]^{2} }{[p1]^{2} [p2] }[/tex]
p1=0.125atm;
p2=0.165atm;
p3=?
Kp=51;
On solving;
p3=0.36atm (partial pressure of NOCl)
The reaction,
[tex]2 NO(g)+Cl_2(g) \rightleftharpoons 2 NOCl (g)[/tex]Given values,
Pressure,
[tex]P_1 = 0.125 \ atm[/tex][tex]P_2 = 0.165 \ atm[/tex]Value of Kp,
[tex]51[/tex]Now,
→ [tex]K_p = \frac{[NOCl]^2}{[NO]^2[Cl_2]^2}[/tex]
or,
→ [tex]K_p = \frac{[P_3]^2}{[P_1]^2[P_2]}[/tex]
By substituting the values,
[tex]51 = \frac{[P_3]^2}{[0.125]^2[0.165]}[/tex]
[tex]P_3 = 0.36 \ atm[/tex]
Thus the response above is appropriate.
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According to VSEPR theory, the molecule PF6- has how many regions of electron density around the central atom (how many electron groups?) (enter a number from 1 to 6) PF6- will have (linear, trigonal planar, tetrahedral, trigonal pyramidal, bent, trigonal bipyramidal, seesaw, T-shaped, octahedral, square pyramidal, square planar) electronic geometry, and (linear, trigonal planar, tetrahedral, trigonal pyramidal, bent, trigonal bipyramidal, seesaw, T-shaped, octahedral, square pyramidal, square planar) molecular geometry.
Answer : The electronic geometry and the molecular geometry of the molecule will be octahedral.
Explanation :
Formula used :
[tex]\text{Number of electron pair}=\frac{1}{2}[V+N-C+A][/tex]
where,
V = number of valence electrons present in central atom
N = number of monovalent atoms bonded to central atom
C = charge of cation
A = charge of anion
The given molecule is, [tex]PF_6^-[/tex]
[tex]\text{Number of electrons}=\frac{1}{2}\times [5+6+1]=6[/tex]
The number of electron pair are 6 that means the hybridization will be [tex]sp^3d^2[/tex] and the electronic geometry and the molecular geometry of the molecule will be octahedral.
The correct number of regions of electron density around the central atom in PF₆- is 6. The electronic geometry of PF6- is octahedral, and the molecular geometry is also octahedral.
To determine the number of electron regions around the central phosphorus atom in PF6-, we count the bonded atoms and any lone pairs on the central atom.
The Lewis structure of PF6- shows that the phosphorus atom is bonded to six fluorine atoms and has no lone pairs since it is surrounded by six bonding groups and has a formal charge of -1, which balances the overall charge of the ion.
Each bonded fluorine contributes one region of electron density, and there are no lone pairs on the phosphorus atom.
Therefore, there are six regions of electron density around the central phosphorus atom, which corresponds to an octahedral electronic geometry.
Since there are no lone pairs, the molecular geometry is the same as the electronic geometry, which is octahedral. This means that all six fluorine atoms are arranged around the central phosphorus atom in a way that they are at the vertices of an octahedron.
In summary, the VSEPR theory predicts that PF6- has six regions of electron density, an octahedral electronic geometry, and an octahedral molecular geometry.
The method used by Joseph Priestley to obtain oxygen made use of the thermal decomposition of mercuric oxide given below. What volume of oxygen gas, measured at 39°C and 725 torr, can be produced from the complete decomposition of 3.97 g mercuric oxide?
Answer:
The volume of the oxygen gas is 0.246 L
Explanation:
Step 1: Data given
Temperature = 39 °C = 312 K
Temperature = 725 torr = 725 / 760 atm = 0.953947 atm
Mass of mercuric oxide = 3.97 grams
Molar mass of mercuric oxide = 216.59 g/mol
Step 2: The balanced equation
2HgO → 2Hg + O2
Step 3: Calculate moles mercuric oxide
Moles = mass / molar mass
Moles HgO = 3.97 grams / 216.59 g/mol
Moles HgO = 0.0183 moles
Step 3: Calculate moles oxyen
For 2 moles HgO we'll have 2 moles Hg and 1 mol O2
For 0.0183 moles HgO we'll have 0.0183/2 = 0.00915 moles O2
Step 4: Calculate volume O2
p*V = n*R*T
⇒with p = the pressure of the gas = 0.953947 atm
⇒with V = the volume of O2 gas = TO BE DETERMINED
⇒with n = the moles of O2 = 0.00915 moles
⇒with R = the gas constant = 0.08206 L*atm/mol*K
⇒with T = the temperature = 312 K
V = (n*R*T)/p
V = (0.00915 moles * 0.08206 L*atm/mol*K * 312 K ) / 0.953947 atm
V = 0.246 L
The volume of the oxygen gas is 0.246 L
Final answer:
The complete thermal decomposition of 3.97 g of mercuric oxide (HgO) at 39 0C and 725 torr will produce 2.487 Liters of oxygen gas (O2). The calculations involve converting grams to moles using the molar mass of HgO, applying the stoichiometry of the decomposition reaction, and calculating the volume with the ideal gas law.
Explanation:
The question involves the chemical decomposition of mercuric oxide (HgO) to produce oxygen gas (O2) and uses the ideal gas law to calculate the volume of oxygen produced under specific conditions. To solve this problem, we'll use the ideal gas law PV=nRT along with stoichiometry.
Calculate the molar mass of HgO to convert grams to moles.Use stoichiometry to determine the moles of O2 produced from the thermal decomposition of HgO with the chemical equation 2HgO (s)Now, let's provide a step-by-step solution:
Molar mass of HgO = 200.59 g/mol + 15.999 g/mol = 216.589 g/mol.3.97 g HgO * (1 mol HgO / 216.589 g HgO) = 0.01832 mol HgO. According to the equation, 2 moles of HgO produce 1 mole O2, so 0.01832 mol HgO will produce 0.00916 mol O2.725 torr is equivalent to 725 torr * (1 atm / 760 torr) = 0.954 atm.Now convert the temperature to Kelvin: 39 0C + 273.15 = 312.15 K.Using the ideal gas law, PV=nRT, where R is the gas constant 0.0821 L*atm/mol*K, we solve for V: V = nRT/P = (0.00916 mol * 0.0821 L*atm/mol*K * 312.15 K) / 0.954 atm = 2.487 L.Therefore, 2.487 Liters of oxygen gas will be produced from the complete decomposition of 3.97 g of mercuric oxide at 39°C and 725 torr.
you need to prepare 250.0 mL of a 1.50 M HCl solution from a 2.00 M HCl stock solution. assuming that the accuracy of the concentration is important, which type of glassware should you use to make the solution
Answer:
I should use a volumetric flask.
Explanation:
If the accuracy of the concentration is important, we need to use a volumetric flask.
Answer:
The glassware appropriate for dilution preparation is a (250 mL) volumetric flask
Explanation:
We know that molarity or concentration of a solution is the number of moles per litres of solution, the molarity and volume of the solution in question can be used to find out how much of the stock solution to be diluted using the formula;
[tex]c = \frac{n}{v}[/tex]
Once the variables are confirmed, a 250 mL solution of 1.50M HCl can be prepared by measuring determined stock solute into a 250mL volumetric flask and the making it upto the 250mL mark. (a measuring cylinder can be used to check accuracy of volume added).
Calculate the approximate volume of a 1.50 mol sample gas at 15.0°C and a pressure at 3.75atm.
Answer:
V= 9.45L
Explanation:
P=3.75atm, V=?, n= 1.5, R= 0.082, T= 15+ 273= 288K
Applying
PV= nRT
Substitute and Simplify
3.75*V= 1.5*0.082*288
V= 9.45L
The approximate volume of a 1.50 mol sample of gas at 15.0°C and a pressure of 3.75 atm is calculated using the Ideal Gas Law to be about 9.20 liters.
To calculate the approximate volume of a 1.50 mol sample of gas at 15.0°C and a pressure of 3.75 atm, we can use the Ideal Gas Law, which is PV = nRT. First, we must convert the temperature from Celsius to Kelvin by adding 273.15 to the Celsius temperature. Then we can solve for V, the volume of the gas.
The conversion from Celsius to Kelvin: T(K) = 15.0 + 273.15 = 288.15 K
Using the Ideal Gas Law constants, R = 0.0821 L·atm/K·mol. Substituting the known values into the Ideal Gas Law equation:
PV = nRT
(3.75 atm) × V = (1.50 mol) × (0.0821 L·atm/K·mol) × (288.15 K)
V = (1.50 mol × 0.0821 L·atm/K·mol × 288.15 K) / 3.75 atm
V = 9.2029 L
Therefore, the approximate volume of the gas sample is about 9.20 liters.
The equilibrium for the indicator methyl orange is HC14H14SO3(red) + H2O C14H14SO3−(yellow) + H3O+ The reaction is exothermic.
Explain in words, what happens when this is added to an acidic solution.
Answer:
The solution will turn red.
Explanation:
HC₁₄H₁₄SO₃ + H₂O ⇌ HC₁₄H₁₄SO₃⁻ +H₃O⁺
(red) (yellow)
Methyl orange is a weak acid in which the ionized and unionized forms are distinct colours and are in equilibrium with each other,
At about pH 3.4, the two the forms are present in equal amounts, and the indicator colour is orange.
If you add more acid, you are disturbing the equilibrium.
According to Le Châtelier's Principle, when you apply a stress to a system at equilibrium, it will respond in such a way as to relieve the stress.
The system will try to get rid of the added acid, so the position of equilibrium will move to the left.
More of the unionized molecules will form, so the solution will turn red.
If you left a block of dry ice in a bowl at room temperature all day, what would happen to it?
Answer:
It would evaporate.
Explanation:
If you left it on room temperature it would evaporate.
Use scientific reasoning to explain what happens if 0.87 mol NaCl is dissolved in pure water creating 3.00 L of solution, what is its molarity of the resulting solution?
Answer : The molarity of the resulting solution is, 0.29 M
Explanation :
When NaCl dissolved in water then it dissociates to give sodium ions and chloride ions.
Given,
Moles of NaCl = 0.87 mol
Volume of solution = 3.00 L
Molarity : It is defined as the number of moles of solute present in one liter of volume of solution.
Formula used :
[tex]\text{Molarity}=\frac{\text{Moles of }NaCl}{\text{Volume of solution (in L)}}[/tex]
Now put all the given values in this formula, we get:
[tex]\text{Molarity}=\frac{0.87mol}{3.00L}=0.29mole/L=0.29M[/tex]
Therefore, the molarity of the resulting solution is, 0.29 M
The percent by mass of bicarbonate (HCO3−) in a certain Alka-Seltzer product is 32.5 percent. Calculate the volume of CO2 generated (in mL) at 37°C and 1.00 atm if a person were to accidentally ingest a 3.45-g tablet without following instructions. (Hint: The reaction occurs between HCO3− and HCl acid in the stomach.)
Answer:
The volume of carbon dioxide gas generated 468 mL.
Explanation:
The percent by mass of bicarbonate in a certain Alka-Seltzer = 32.5%
Mass of tablet = 3.45 g
Mass of bicarbonate =[tex]3.45 g\times \frac{32.5}{100}=1.121 mol[/tex]
Moles of bicarbonate ion = [tex]\frac{1.121 g/mol}{61 g/mol}=0.01840 mol[/tex]
[tex]HCO_3^{-}(aq)+HCl(aq)\rightarrow H_2O(l)+CO_2(g)+Cl^-(aq)[/tex]
According to reaction, 1 mole of bicarbonate ion gives with 1 mole of carbon dioxide gas , then 0.01840 mole of bicarbonate ion will give:
[tex]\frac{1}{1}\times 0.01840 mol=0.01840 mol[/tex] of carbon dioxide gas
Moles of carbon dioxide gas n = 0.01840 mol
Pressure of the carbon dioxide gas = P = 1.00 atm
Temperature of the carbon dioxide gas = T = 37°C = 37+273 K=310 K
Volume of the carbon dioxide gas = V
[tex]PV=nRT[/tex] (ideal gas equation)
[tex]V=\frac{nRT}{P}=\frac{0.01840 mol\times 0.0821 atm L/mol K\times 310 K}{1.00 atm}=0.468 L[/tex]
1 L = 1000 mL
0.468 L =0.468 × 1000 mL = 468 mL
The volume of carbon dioxide gas generated 468 mL.
Final answer:
The volume of CO2 generated from a 3.45-g Alka-Seltzer tablet containing 32.5% bicarbonate is approximately 469.2 mL when reacted with stomach acid at 37°C and 1.00 atm.
Explanation:
To calculate the volume of CO2 generated from the reaction of bicarbonate (HCO^{3−}) with HCl in the stomach, we can use the provided mass percent of bicarbonate in the Alka-Seltzer tablet and the reaction stoichiometry. The balanced equation for the reaction between sodium bicarbonate and hydrochloric acid is:
NaHCO3(s) + HCl(aq) → NaCl(aq) + H2O(l) + CO2(g)
Assuming the percent by mass of bicarbonate is 32.5%, a 3.45-g tablet would contain 1.12125 g of HCO3−. The molar mass of HCO^{3−} is approximately 61 g/mol, which corresponds to 0.0184 moles of HCO^{3−}. Since the reaction produces one mole of CO2 for each mole of HCO3−, we can use the ideal gas law to calculate the volume of CO2.
At STP (0°C and 1 atm), one mole of any gas occupies 22.4 L. However, we're given conditions of 37°C and 1.00 atm. To adjust for the temperature, we can use the combined gas law:
V2 = (V1 × T2 × P1) / (T1 × P2)
Where:
V1 = 22.4 LT1 = 273 K (STP temperature)T2 = 310 K (37°C in kelvin)P1 and P2 = 1 atm (pressure is constant)Thus:
V2 = (22.4 L × 310 K) / 273 K
V2 is the volume of CO2 at the new conditions, which is approximately 25.5 L/mol. Since we have 0.0184 moles of HCO^{3−}, the volume of CO2 produced would be 0.0184 moles × 25.5 L/mol = 0.4692 L or 469.2 mL.
Relate energy levels to the amount of energy their electrons have
In atoms, electrons exist on specific, discrete energy levels, which correspond to distinct values of the principal quantum number 'n'. Electricity fills these 'shells' from the lowest to the highest energy state. Transitions between energy levels require definite energy changes.
Explanation:The energy levels of electrons in an atom can be understood using the principal quantum number often denoted by 'n'. Electrons exist only on specific, discrete energy levels and not between them. This principle is known as the quantization of energy. Each energy level is associated with a specific value of 'n', with n = 1, 2, 3, and so on. The greater the 'n' value, the higher the energy level.
Each energy level or shell can be visualized as concentric circles radiating from the nucleus of the atom. Electrons fill these shells starting from the one closest to the nucleus (lowest energy state), filling up to the one furthest from the nucleus (highest energy state). This illustrates the principle of energy states in a metal as in Figure 9.13.
Furthermore, the Bohr atom model suggests that each electron orbit around the nucleus corresponds to a distinct energy level, and each transition between these levels involves a definite energy change. Therefore, the energy levels of electrons in an atom are directly related to the amount of energy possessed by the electrons.
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The decomposition of nitramide, O 2 NNH 2 , O2NNH2, in water has the chemical equation and rate law O 2 NNH 2 ( aq ) ⟶ N 2 O ( g ) + H 2 O ( l ) rate = k [ O 2 NNH 2 ] [ H + ] O2NNH2(aq)⟶N2O(g)+H2O(l)rate=k[O2NNH2][H+] A proposed mechanism for this reaction is O 2 NNH 2 ( aq ) k 1 ⇌ k − 1 O 2 NNH − ( aq ) + H + ( aq ) ( fast equilibrium ) O2NNH2(aq)⇌k−1k1O2NNH−(aq)+H+(aq)(fast equilibrium) O 2 NNH − ( aq ) k 2 −→ N 2 O ( g ) + OH − ( aq ) ( slow ) O2NNH−(aq)→k2N2O(g)+OH−(aq)(slow) H + ( aq ) + OH − ( aq ) k 3 −→ H 2 O ( l ) ( fast ) H+(aq)+OH−(aq)→k3H2O(l)(fast) What is the relationship between the observed value of k k and the rate constants for the individual steps of the mechaanism?
Answer:
Explanation:
The given overall reaction is as follows:
O 2 N N H ₂( a q ) k → N ₂O ( g ) + H ₂ O( l )
The reaction mechanism for this reaction is as follows:
O ₂ N N H ₂ ⇌ k 1 k − 1 O ₂N N H ⁻ + H ⁺ ( f a s t e q u i l i b r i u m )
O ₂ N N H − k ₂→ N ₂ O + O H ⁻ ( s l ow )
H ⁺ + O H − k ₃→ H ₂ O ( f a s t )
The rate law of the reaction is given as follows:
k = [ O ₂ N N H ₂ ] / [ H ⁺ ]
The rate law can be determined by the slow step of the mechanism.
r a t e = k ₂ [ O ₂ N N H ⁻ ] . . . ( 1 )
Since, from the equilibrium reaction
k e q = [ O ₂ N N H ⁻ ] [ H ⁺ ] /[ O ₂ N N H ₂ ] = k ₁ /k − 1
[ O ₂ N N H ⁻] = k ₁ /k − 1 × [ O ₂ N N H ₂ ] /[ H ⁺ ]. . . . ( 2 )
Substitituting the value of equation (2) in equation (1) we get.
r a t e = k ₂ k ₁/ k − 1 × [ O ₂ N N H ₂ ] /[ H ⁺ ]
Therefore, the overall rate constant is
k = k₂k₁/k-1
The observed rate constant k is related to the individual rate constants of the mechanism by the equation k = k2 (k1/k-1), where k2 is the rate constant of the rate-determining slow step and k1/k-1 is the equilibrium constant of the first fast equilibrium step.
Explanation:The relationship between the observed rate constant k (in the rate law) and the rate constants for the individual steps (k1, k-1, k2, k3) in the proposed mechanism for the decomposition of nitramide can be determined by examining the rate-determining step (RDS). In a reaction mechanism, the slowest step controls the overall reaction rate. For the given mechanism:
O2NNH2(aq) ⇌k1⇌k−1 O2NNH−(aq) + H+(aq) (fast equilibrium)O2NNH−(aq) →k2 N2O(g) + OH−(aq) (slow)H+(aq) + OH−(aq) →k3 H2O(l) (fast)the observed rate law is rate = k [O2NNH2] [H+]. Because the second step is slow, it is the RDS. The equilibrium of the first step means that the concentration of the intermediate O2NNH−(aq) can be expressed in terms of the concentrations of the reactants O2NNH2 and H+. Therefore, the observed rate constant k is a function of the rate constants of the individual steps, particularly k2 and the equilibrium constant (K = k1/k−1) from the first step. Hence, we can conclude that k is equal to k2 multiplied by the equilibrium constant of the first step, where k = k2 (k1/k−1)
Think about what you've learned about how particle motion is related to temperature.
Select all of the statements that are true.
1. The average kinetic energy of the particles in a substance determines the
substance's temperature.
2. If the particles in two pure substances have the same average speed, the
substances can have different temperatures.
3. When two substances have the same temperature, all of the particles in
both substances are moving at the same speed.
4. How fast a substance's particles are moving determines how hot or cold
the substance is.
Final answer:
The true statements about particle motion and temperature are that the average kinetic energy of the particles in a substance determines its temperature and that faster moving particles generally result in a higher temperature of the substance.
Explanation:
The relationship between particle motion and temperature is based on the kinetic-molecular theory. According to this theory, temperature is proportional to the average kinetic energy of the particles, such as molecules or atoms, in a substance. Therefore:
The average kinetic energy of the particles in a substance determines the substance's temperature.
If the particles in two pure substances have the same average speed, it does not necessarily mean they have the same temperature, since heavier particles will have more kinetic energy at the same speed, leading to different temperatures.
When two substances have the same temperature, it indicates that the average kinetic energy of the particles in both substances is the same, not that all of the particles are moving at the same speed, because particles have a range of speeds.
The speed of a substance's particles can give an indication of how hot or cold that substance is. Faster moving particles generally mean a higher temperature.
As such, the true statements are 1 and 4. Understanding that temperature is not simply a measure of particle speed, but rather the average kinetic energy involved, clarifies misconceptions about the nature of thermal energy and its measurement.
A battery charger used to recharge the NiMH batteries used in a digital camera can deliver as much as 0.35 A of current. If it takes 145 minutes to recharge one battery, how many g Ni(OH)2 are oxidized to NiO(OH)
Answer:
The amount that oxidized to NiO(OH) is = 1.46 gm
Explanation:
Given data
Current I = 0.35 A
Time taken = 145 min
We know that charge
Q = I t
Q = 0.35 × 145 × 60
Q = 3045 C
Faraday's constant = 96500 C
No. of moles of electron
[tex]N = \frac{3045}{96500}[/tex]
N = 0.03155
1 mol of [tex]NI(OH)_{2}[/tex] is oxidized by 2 moles of electrons, so no. of moles can be oxidized is
[tex]\frac{0.03155}{2}[/tex] = 0.015775 moles
Now convert this moles into gm by multiplying 92.708 [tex]\frac{gm}{mol}[/tex]
0.015775 × 92.708 = 1.46 gm
Therefore the amount that oxidized to NiO(OH) is = 1.46 gm
Which process is an example of a physical change?
burning
rusting
flattening
ripening
Answer:
The answer is flattening
Explanation:
A physical change is generally something that affects the shape of form of the matter and a chemical change results from a chemical reaction. Flames are caused by chemical reactions, as is rust, and the process of a fruit becoming ripe. Thus, the answer is “flattening”.
In the realm of chemistry, only flattening out of the listed options is considered a physical change as it alters the condition of a substance without modifying its underlying chemical structure.
Explanation:In the context of Chemistry, physical changes are processes that change the form or appearance of a substance, but not its chemical composition. Of the processes you listed: burning, rusting, flattening, and ripening, flattening is an example of a physical change. For instance, if you have a piece of aluminum foil and you flatten it, it is still aluminum foil - no new substance is created. On the other hand, burning, rusting, and ripening are chemical changes because they result in new substances being formed.
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Consider the following reaction NaOH (s) --> Na+ (aq) + OH- (aq)
Is the reactant an __________.
Answer:
base and it's in solution
Explanation:
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Which statements describes why ethyl methyl ether (b.p. 7.9°C) and 1-propanol (b.p. 97.2°C) have such different boiling points despite identical molar masses? A) Ethyl methyl ether has more hydrogen bonding than 1-propanol. B) 1-propanol has more hydrogen bonding than ethyl methyl ether. C) Ethyl methyl ether has greater dispersion forces than 1-propanol. D) 1-propanol has greater dispersion forces than ethyl methyl ether. E) Ethyl methyl ether has greater molecular volume than 1-propanol.
Answer:
B) 1-propanol has more hydrogen bonding than ethyl methyl ether.
Explanation:
1-propanol and ethyl methyl ether look very similar but have very different boiling points. They both have three carbon atoms but ethyl methyl ether has an oxygen atom.
Ethyl methyl ether has both London dispersion forces and dipole-dipole interactions.
1-Propanol has London dispersion forces, dipole-dipole interactions and hydrogen bonding.
1-propanol has more hydrogen bonding than ethyl methyl ether which explains why they both have different boiling points.