Which acid is the best choice to create a buffer with ph= 7.66?

Answers

Answer 1
The best choice is hypochlorous acid (HClO) because it has the nearest value of pK to the desired pH.

pKa of hypochlorous acid is 7.54 

If we know pKa and pH values,  we can calculate the required ratio of conjugate base (ClO⁻) to acid (HClO) from the following equation:

pH=pKa + log(conc. of base)/( conc. of acid)

7.66=7.54 + log(conc. of base)/( conc. of acid)

7.66 - 7.54 = log(conc. of base)/( conc. of acid)

0.12 = log(conc. of base)/( conc. of acid)

(conc. of base)/(conc. of acid) = 10⁻⁰¹² = 0.76









Related Questions

What is the smallest particle of an element that still retains all the properties of the element? a compound a mineral an atom an isotope

Answers

The atom is the smallest particle of an element that retains it's characteristics. Sub-atomic particles such as protons, neutrons and electrons form the atom and it is the amount of each of these sub-atomic particles that make the element that element.

The basic building block of chemistry is known as the atom. The smallest particle of an element that still retains all the properties of the element is known as the atom. The correct option is C.

What is an atom?

The atom can be considered as the basic building blocks of matter which possess the properties of the chemical element. An atom don't exist independently, instead they form ions and molecules which in turn combine in large numbers to form matter.

An atom is an indivisible particle and it contains the sub-atomic particles like protons, electrons and neutrons. The positively charged particles are called protons, the negatively charged particles are called electrons. The neutrons are chargeless particles.

All atoms of the same element are identical but different elements have different types of atoms. The chemical reactions occur when the atoms are rearranged.

Thus the correct option is C.

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Seafloor spreading provides evidence of which of the following Earth processes?

A.erosion of coastlines
B.weathering of mountains
C.movement of crustal plates
D.formation of sedimentary rocks

Answers

The answer would be C. Movement of crustal plates. 

Seafloor spreading provides evidence for D. formation of sedimentary rocks.

Seafloor spreading occurs when there's volcanic activity that leads to the formation of a new oceanic crust.

Sedimentary rocks refer to the rocks that are formed when there's an accumulation of organic particles or minerals on the surface of the Earth.

It should be noted that sedimentary rocks are deposited in layers that are referred to as strata. Examples of sedimentary rocks include limestones, iron ore, chert, etc.

In conclusion, when seafloor spreading occurs, there are sediments that overtime accumulates and forms sedimentary rock.

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Which is more stable hydroxyl isopropyl or benzhydrol radical?

Answers

the correct answer is Hydroxyl isopropy

The benzhydrol radical is more stable than the hydroxyl isopropyl radical because it can delocalize its unpaired electron through resonance across the aromatic ring, while the hydroxyl isopropyl radical lacks such extensive resonance stabilization.

When considering the stability of hydroxyl isopropyl and benzhydrol radicals, it's important to look at resonance stabilization. Radicals that can delocalize their unpaired electron through resonance are generally more stable. In the case of a benzhydrol radical, also known as a benzylic radical, there is significant stabilization due to the possibility of multiple resonance structures. This is because the unpaired electron in the benzhydrol radical can be delocalized through the aromatic ring's system of conjugated pi bonds.

On the other hand, the hydroxyl isopropyl radical, which is an alkyl radical, lacks the extended conjugated system that allows for such delocalization. While it may have some hyperconjugative stabilization, it does not benefit from the extensive resonance stabilization that the benzhydrol radical enjoys. As such, the benzhydrol radical is more stable than the hydroxyl isopropyl radical due to the resonance effects and the subsequent delocalization of the unpaired electron across the aromatic ring.

Scientists often investigate alternative explanations for the data and observations presented, even once a hypothesis has been tested and supported through an experiment. This investigation of alternative explanations ...

Answers

strengthens the evidence and support for a scientific theory

This is your answer

Answer:

Strengthens the evidence and support for a scientific theory.

Explanation:

Hello,

Scientific method provides a compelling tool scientists use to both develop and demonstrate new theories. As it involves both the observation and experimentation towards a specific subject of matter, it turns out convenient to consider alternative explanations substantiating such subject of matter in light of obtaining a more precise explanation for it. In such a way, this investigation of alternative explanations strengthens the evidence and support for a scientific theory.

Best regards.

Use the periodic table in the tools bar to complete the electron configurations for the following elements: Lithium (Li): 1sA2sB

Answers

Answer: Value of A is 2 and value of B is 1.

Explanation:

Lithium is the third element of the periodic table. It belongs to the Period 2 and Group 1 and is considered as an alkali metals.

To write the electronic configuration, we need to find the number of electrons this element contain, which is equal to the atomic number.

Number of electrons = Atomic number = 3

So, the electronic configuration will be: [tex]1s^22s^1[/tex]

The s-orbital in total can contain only 2 electrons.

Hence, the value of A is 2 and value of B is 1.

The periodic table showcases the table of the chemical elements listed in order of atomic number, usually in rows(period) from the left to the right, in such a way that elements with similar atomic structures as well as similar chemical properties can be located in vertical columns (groups).

Lithium is the third chemical element on the periodic table. It can be located on group 1 element also known as the alkali metals. It is soft in nature and has a whitish color.

The electronic configuration explains how electrons are distributed in their atomic orbitals.

The electronic configuration for Lithium can be expressed as:

Li: 1s² 2s¹

Therefore, from the given information, we can conclude that the value for the electronic configuration of A and B  in the Lithium sample given is 2 and 1 respectively

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dentify the molecule with the highest boiling point.

CHCl3
OF2
NH3
C6H6

Answers

CHCI3, ion-ion attractions

Answer: Option (c) is the correct answer.

Explanation:

A molecule which has hydrogen bonding will have the highest boiling point. So, out of the given options only [tex]NH_{3}[/tex] will have hydrogen bonding.

Whereas in [tex]CHCl_{3}[/tex] there will be dipole-dipole interactions and no hydrogen bonding within the molecule.

In [tex]OF_{2}[/tex] and [tex]C_{6}H_{6}[/tex], there will be dipole-dipole interaction in both the molecules.

Thus, we can conclude that [tex]NH_{3}[/tex] will have the highest boiling point.

If a propane heater burns 38.95 g C3H8, it consumes 38.95 mol C3H8. 0.8830 mol C3H8. 1 mol C3H8. 44.10 mol C3H8.

Answers

The answer is 0.8830 mol C3H8.

Here's how the answer was generated:

We do know that all the choices are in moles, in that case, we divide the 38.95 g of propane (C3H8) by the molar mass which is:

C = 12.01
H = 1.01

C3H8 = 3 * 12.01 + 8 * 1.01 = 44.11
Divide 38.95 g by 44.11 g/mol and the answer will be 0.8830 mol C3H8. 

Answer:


               Option-2 (0.8830 mol C₃H₈) is the correct answer.


Solution:

                 In statement we are given with the amount of propane gas and are asked to find out the moles for given mass.


As we know mass is related to moles as follow,


                                      Moles = Mass / M.mass ----- (1)


Data Given:


                Moles = ??


                Mass = 38.95 g


                M.mass = (C)3 + (H)8 = (12)3 + (1)8 = 36 + 8 = 44 g/mol


Putting values in equation 1,


                                    Moles = 38.95 g / 44 g/mol


                                    Moles = 0.8854 Moles

Which of the following is a part of a land based carbon cycle ?coral reefs
Crab shells
Trees
Whales

Answers

The appropriate answer is C. Trees. Trees remove carbon dioxide from the atmosphere through the process of photosynthesis. The carbon dioxide is used along with water and energy from the sun to make food for plants.
Corals extract dissolved carbon dioxide from the ocean to secrete their hard rocky structures.
Crab shells and other marine animals with shells have their bodies incorporated into the seafloor when they die. The sea floor eventually gets subducted where it melts. The carbon present here gets back into the atmosphere via volcanic eruptions.

Answer:

c

Explanation:

Which of the following could be classified as matter? Check all of the boxes that apply. desk water idea cloud helium dream

Answers

desk, water, helium and coulds

Examples of matter include;

DeskWaterCloudHeliumFurther ExplanationMatter  Matter is anything that has weight and occupies space. Matter exists in three states, liquid, gases, and solids.For example, from the examples above; helium is matter in a gaseous state, water in liquid state and desk in solid-state.Matter is made up of small particles that are in continuous random movement.Particles  A particle refers to a single atom or a group of atoms that are bonded together and functions as a single unit.  Therefore, matter is made up of particles that can either be single atoms or chemically bonded atoms to make a molecule. Hence, a molecule is also a particle of matter.An atom  An atom is the smallest particle of an element that can take part in a chemical reaction.Atoms are made up of sub-atomic particles which include; protons, neutrons, and electrons. When two or more atoms are bonded together they form a molecule.Molecule  A molecule is the smallest particle of an element or a compound that has similar properties of that particular compound or element.Molecules could be made up of atoms that are similar such as oxygen molecules or atoms that different from different elements, such as water molecules.The bonding of atoms to form molecules occurs as a result of the sharing or transfer of electrons between atoms.  

Keywords: Matter, states of matter, particles, atoms, molecules, elements, compounds  

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Level: High school  

Subject: Chemistry  

Topic: Matter and particles of matter  

Sub-topic: Classification of matter

Match the each term with its definition. 1) reaction coordinate a) the higher point on the energy curve 2) δg° b) the plot of the reaction progress as a function of time 3) δg‡ c) the free energy of the reaction

Answers

The correct answer is:
1) reaction coordinate will match with
B)the plot of the reaction progress as a function of time.

as the reaction coordinate is the progress of a reaction from the reactants to products with different transition states in between. The X-axis: which has the reaction progress reflects the progressive chemical changes and the formation of bond and the bond breakage as S (the energy associated with the reactant) is changing and converting to P ( the energy that associated with the product).Actually, it has no relation to time.Rather partially formation of bonds and breaking of bond reaction steps.

2)ΔG° will match with  
c) the free energy of the reaction.

As it is simply defined as the Gibbs free energy and is also known as a free enthalpy, it is used to calculate the maximum of reversible work performed by the thermodynamic system when the temperature and the pressure are constant.

3)ΔG will match with
A) the higher point of the energy curve.

when ΔG = ΔGproduct - ΔGreactant
and It is simply defined as the change in free energy. It reflects nothing about the speed of the reaction. ΔG+ indicates that the reaction is endergonic and energy goes from reactants to products.and ΔG- become negative when the reaction goes to a lower energy state and it indicates then that the reaction is exergonic.

You are given a crushed sample that is a mixture of limestone (caco3), lime (cao), and sand. the calcium carbonate, limestone, is the only material present in the material that will decompose when heated. you subject a 6.4734 g sample of the mixture to strong heating and after the sample reaches a constant mass (no more mass is lost with additional heating), the sample has a final weight of 4.3385 g. what is the percentage of calcium carbonate present in the original mixture? (f.wt. caco3 = 100.1)

Answers

Answer is: percentage of calcium carbonate is 75%.
Chemical reaction: CaCO₃ → CaO + CO₂.
m₁(sample) = 6,4734 g.
m₂(sample) = 4,3385 g.
m(CO₂) = m₁(sample) - m₂(sample).
m(CO₂) = 6,4734 g - 4,3385 g.
m(CO₂) = 2,1349 g.
n(CO₂) = m(CO₂) ÷ M(CO₂).
n(CO₂) = 2,1349 g ÷ 44 g/mol.
n(CO₂) = 0,0485 mol.
From chemical reaction: n(CO₂) : n(CaCO₃) = 1 : 1.
n(CaCO₃) = 0,0485 mol.
m(CaCO₃) = 0,0485 mol · 100,1 g/mol.
m(CaCO₃) = 4,854 g.
percentage of calcium carbonate = 4,854 g ÷ 6,4734 g · 100%.
percentage of calcium carbonate = 75%.

Write the chemical reaction that is responsible for the ph of a buffer which contains nh3 and nh4cl. write the reaction in such a way that is appropriate for a ka.

Answers

Final answer:

The pH of a buffer containing NH3 and NH4Cl is determined by the equilibrium between NH4+ and NH3 in water, with the reaction NH4+ (aq) + H2O(l) → H3O+ (aq) + NH3(aq). The reaction demonstrates the action of the ammonium ion as a weak acid, and its Ka is calculated using the Ka = Kw/Kb relationship. The chloride ion does not undergo significant hydrolysis, so it does not affect the pH of the buffer.

Explanation:

The chemical reaction responsible for the pH of a buffer containing NH3 (ammonia) and NH4Cl (ammonium chloride) involves the equilibrium between NH4+ and NH3 in water:

NH4+ (aq) + H2O(l) ⇒ H3O+ (aq) + NH3(aq)

This represents the dissociation of the ammonium ion, which is a weak acid, in water to produce hydronium ions (H3O+) and ammonia. Since ammonia is a weak base, the corresponding acid dissociation constant (Ka) can be calculated using the relation Ka = Kw/Kb, where Kw is the ion product of water and Kb is the base dissociation constant of ammonia.

The chloride ion, being the conjugate base of the strong acid hydrochloric acid (HCl), does not undergo significant hydrolysis in water:

Cl-(aq) + H2O(l) → HCl(aq) + OH−(aq)

Since HCl is a strong acid, the equilibrium constant (Ka) for its conjugate base, Cl-, is essentially zero, which means Cl- does not affect the buffer solution's pH appreciably.

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How many neutrons are found in Cr-54

Answers

Number of neutrons found=Mass number-No. of protons
=54-24
=30
So the answer is 30 neutrons

Answer:

30

Explanation:

To find out the neutron number of an element we must first know what the mass value of that element is and the value of the atom number of that element. To find out these values, just look for the element in the periodic table. Once discovered simply subtract the values using the formula:

No. of neutrons = mass - atom number.

In the case of Cr, the mass is 54, while the atom number is 24. So we can find the number of neutrons.

Cr Neutrons = 54-24 = 30

Draw the acetal produced when ethanol adds to ethanal.

Answers

Structure of acetal is in Word document below.
Acetal is produced when one molecule of aldehyde (in this reaction ethanal) and two molecules of alcohols (in this reaction ethanol) react. Hemiacetal is produced when one molecule of aldehyde and one molecule of alcohol react. Acetals are stable compared to hemiacetals.

Explanation:

Acetals are geminal diethers derivatives of aldehyde formed by the addition to equivalent molecules of an alcohol and removal of water.

When ethanol is added to the ethanal in acidic medium:

Ethanal + Ethanol → Hemiacetal

Hemiacetal + Ethanol → Acetal

Acetal produced when ethanol is added to ethanal are given in the image attached.

In a molecule of methane (ch4), what type of bond joins the carbon atom to each of the hydrogen atoms?

Answers

a polar covalent bond, the electronegativity of carbon is 2.6, and for hydrogen it's 2.1, therefore their bond is polar, but the molecule itself is not, because of its 3D structure

The reaction of 0.779 g K with O2 forms 1.417 g potassium superoxide, a substance used in self-contained breathing devices. Determine the formula for potassium superoxide.

Answers

First we need to find the number of moles of both K and O reacted
K - 0.779 g / 39 g/mol
  = 0.02 mol
the mass of O₂ reacted = 1.417 g - 0.779 g = 0.638 g
O₂ moles = 0.638 g / 32 g/mol
               = 0.02 mol 
the number of both K and O₂ moles reacted are equal 
therefore stoichiometry of K to O₂ reacted are 1:1 
then the formula of potassium superoxide is KO₂

Final answer:

The correct formula for potassium superoxide formed when 0.779 g of potassium reacts with an excess of oxygen to form 1.417 g of the compound is[tex]KO_{2}[/tex]

Explanation:

The formula for potassium superoxide can be determined by considering the mass of potassium reacted and the mass of the resultant compound formed. In this case, 0.779 grams of potassium reacts with oxygen to form 1.417 grams of potassium superoxide. Knowing that the potassium has fully reacted and become part of the potassium superoxide, we can deduce that the difference in mass (1.417 g - 0.779 g = 0.638 g) must be due to the oxygen present in the compound.

The simplest ratio between potassium (K) and oxygen (O) that could form a compound would be a 1:1 ratio, which gives us KO. However, based on the provided information, potassium superoxide has a different stoichiometry where 1 mol of potassium reacts with oxygen to form a compound with the formula [tex]KO_{2}[/tex], which is a superoxide. This means there are two oxygen atoms for every potassium atom in the compound.

Therefore, the correct formula for potassium superoxide, as formed in the reaction with an excess of oxygen, is [tex]KO_{2}[/tex].

H2+I2= 2HI+3 kcal Based on the reaction given above, as the temperature decreases, the formation of the reactants will: A. decrease B. increase C. remained consistent D. indeterminate

Answers

Answer:
Decrease

Explanation:
The reaction given is an exothermic reaction. This means that the heat is a product.
At equilibrium, the rate of forward reaction is equal to the rate of backward reaction.
Now, decreasing the temperature means that the concentration of the products will decrease. 
As a result, the equilibrium will shift to the right leading to the formation of more products in order to reach equilibrium again.
This means that the formation of the reactants will decrease.

Hope this helps :)

the answer is A: decrease

What is the acid-base equilibrium reaction between ClO– and H2O.

Answers

Chemical reaction: ClO⁻ + H₂O → HClO + OH⁻.
ClO⁻ is base in this chemical reaction and water is acid. According Brønsted–Lowry acid–base theory base is compound that attracts protons (H⁺) and acid (in this chemical reaction water) gives protons.
Ke = [OH⁻] · [HClO] / [ClO⁻].
[OH⁻] - equilibrium concentration.

In an experiment, you combine 83.77 g of iron with an excess of sulfur and then heat the mixture to obtain iron(III) sulfide. 2Fe(s) + 3S(s) → Fe2S3(s) What is the theoretical yield, in grams, of iron(III) sulfide?

Answers

Start by looking up the molar mass of each thing in the reaction.

Fe = 55.845  g/mol
S = 32.065 g/mol
Fe2S3 = 207.9 g/mol

Next, convert Fe mas to moles.

83.77 g /  55.845  g/mol = 1.5 mol Fe

Us the stoichiometry (mole ratio) to get to moles product.

2 Fe reactants makes 1 Fe2S3 product

1.5 mol Fe * (1 Fe2S3 / 2 Fe) = 0.75 mol Fe2S3

Now multiply buy the Fe2S3 molar mass to get its weight in grams.

0.75 mol Fe2S3 * 207.9 g/mol = 155.925 g

This is the amount you should theoretically obtain using that much iron.









The theoretical yield of iron (II) sulfide would be 155.92 g

Theoretical yield

It is the total stoichiometric product from a reaction.

From the equation of the reaction:

2Fe(s) + 3S(s) → Fe2S3(s)

The mole ratio of Fe to Fe2S3 is 2:1

Mole of 83.77 g Fe = 83.77/55.85

                               = 1.4999 moles

Equivalent mole of Fe2S3 = 1.4999/2

                                            = 0.75 moles

Mass of 0.75 mole Fe2S3 = 0.75 x 207.9

                                             = 155.92 g

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Experimental data have shown that the rate law for the reaction 2 hgcl2(aq) + c2o4 2 -(aq) → 2 cl-(aq) + 2 co2 (g) + hg2cl2 (s) is: rate = k[hgcl2][c2o4 2 -]2 how will the rate of reaction change if the concentration of c2o4 2 - is tripled and the concentration of hgcl2 is doubled?

Answers

Answer:

The rate will be doubled by a Factor of 18

Explanation:

Good luck to everyone doing this!! you got this

Final answer:

The rate of the reaction will increase by a factor of 18 if the concentration of C2O42- is tripled and the concentration of HgCl2 is doubled.

Explanation:

The question asks how the rate of the reaction 2 HgCl2(aq) + C2O42-(aq) → 2 Cl-(aq) + 2 CO2 (g) + Hg2Cl2 (s) will change if the concentration of C2O42- is tripled and the concentration of HgCl2 is doubled. Given the rate law rate = k[HgCl2][C2O42-]2, we can predict the effect on the rate. If the rate law is followed, tripling [C2O42-] will increase the rate by a factor of 32 or 9 because the concentration of C2O42- is squared in the rate law. Doubling [HgCl2] will double the rate of reaction. Therefore, tripling [C2O42-] and doubling [HgCl2] together will increase the reaction rate by a factor of 2 * 9 = 18.

Approximately how many moles of boron make up 1.20 × 10^24 atoms of boron?

A. 7.22 × 10^47 moles

B. 6.02 × 10^23 moles

C. 5.00 moles

D. 1.99 moles

Answers

1 mol of anything is 6.02 * 10^23 of that substance
x mol = 1.2 * 10^24

x = 1.2 * 10^24/6.02 * 10^23
x = 1.993 mol.

Answer: D <<<<<======

If kc = 7.04 × 10-2 for the reaction: 2 hbr(g) ⇌h2(g) + br2(g), what is the value of kc for the reaction: 1/2 h2(g) + 1/2 br2 ⇌hbr(g)

Answers

at the first reaction when 2HBr(g) ⇄ H2(g) + Br2(g)
So Kc = [H2] [Br2] / [HBr]^2
7.04X10^-2 = [H2][Br] / [HBr]^2

at the second reaction when 1/2 H2(g) + 1/2 Br2 (g) ⇄ HBr
Its Kc value will = [HBr] / [H2]^1/2*[Br2]^1/2
we will make the first formula of Kc upside down:
1/7.04X10^-2 = [HBr]^2/[H2][Br2]
and by taking the square root: 
∴ √(1/7.04X10^-2)= [HBr] / [H2]^1/2*[Br]^1/2
∴ Kc for the second reaction = √(1/7.04X10^-2) = 3.769 

The value of Kc for the second reaction is mathematically given as

Kc' = 3.769  

What isthe value of Kc for the second reaction?

Question Parameters:

kc = 7.04 × 10-2 for the reaction

2 hbr(g) ⇌h2(g) + br2(g)

1/2 h2(g) + 1/2 br2 ⇌hbr(g)

Generally, the equation for the reaction  is mathematically given as

2HBr(g) ⇄ H2(g) + Br2(g)

Therefore

Kc = [H2] [Br2] / [HBr]^2

7.04X10^-2 = [H2][Br] / [HBr]^2

Upon final reaction

Kc' = [HBr] / [H2]^1/2*[Br2]^1/2

Hence

[tex]\sqrt{(1/7.04X10^-2)}= [HBr] / [H2]^1/2*[Br]^1/2}\\\\Kc' = \sqrt{(1/7.04X10^-2)[/tex]

Kc' = 3.769  

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You used both HNO3 and H2SO4 solutions in this experiment. briefly answer the following question.
why couldn't you substitute 3M H2SO4 for concentrated HNO3 in Part 1?

Answers

Final answer:

You couldn't substitute 3M H2SO4 for concentrated HNO3 in Part 1 of the experiment due to the significant differences in their reactivity and properties. HNO3 is a powerful oxidizing agent and provides specific reactions, while H2SO4 is a strong acid but not as strong an oxidizing agent.

Explanation:

The reason you couldn't substitute 3M H2SO4 for concentrated HNO3 in Part 1 of the experiment is due to the difference in their reactivity and properties. Nitric Acid (HNO3) is a powerful oxidizing agent. This means it has the ability to oxidize other substances, bringing about specific chemical reactions. On the other hand, Sulfuric Acid (H2SO4), while still a strong acid, is not as strong an oxidizing agent and would not yield the same results if used as a substitute for HNO3 in this experiment.

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Explain why c6h5ch2ch2br is not formed during the radical bromination of c6h5ch2ch3. select the single best answer.

Answers

Hi!

The radical bromination reaction of C₆H₅CH₂CH₃ is performed through a mechanism in which radical reactions are involved. This compound is an alkylbenzene compound, and the carbon that is more reactive towards radical bromination is the carbon bonded to the aromatic ring because in the reaction mechanism the intermediaries are stabilized by resonance in the aromatic ring. 

A terminal substitution will not occur because substitution there will not be stabilized by resonance. The compound that will be formed in this reaction would be:

C₆H₅CH₂CH₃ + Br₂ → C₆H₅CH₂(Br)CH₃ + HBr

Final answer:

C6H5CH2CH2Br is not formed during the radical bromination of C6H5CH2CH3 because the intermediate benzyl radical, formed at the carbon adjacent to the aromatic ring, is much more stable than the primary radical needed for the other product. Selectivity is due to bromine's preference for stable radicals, supported by Hammond's postulate.

Explanation:

The reason why C6H5CH2CH2Br is not formed during the radical bromination of C6H5CH2CH3 involves the relative stability of the radical intermediate. Radical bromination tends to occur at the position that forms the most stable radical, which for a benzyl compound is the carbon atom directly adjacent to the aromatic ring. The radical formed at this position, a benzyl radical, is highly stabilized by resonance. In contrast, the radical that would be required to form C6H5CH2CH2Br is a primary radical, which is less stable and thus less likely to form. This selectivity is due to the fact that bromine radicals are relatively selective and prefer to abstract hydrogen atoms from positions that lead to more stable radical intermediates. Moreover, Hammond's postulate suggests that since the radical formation with bromine is endothermic, the transition state will more closely resemble the stable radical intermediate, leading to more selective radical formation.

For a particular first-order reaction, it takes 3.0 minutes for the concentration of the reactant to decrease to 25% of its initial value. what is the value for rate constant (in s-1) for the reaction?

Answers

Final answer:

For a first-order reaction, the rate constant can be determined using the concentration of the reactant at a given time. In this case, the rate constant is 0.25 s^-1.

Explanation:

A first-order reaction is one in which the rate of reaction is directly proportional to the concentration of the reactant. The rate law expression for a first-order reaction is given by rate = k[A], where [A] is the concentration of the reactant and k is the rate constant.

In this case, the concentration of the reactant decreases to 25% of its initial value in 3.0 minutes. We can use this information to determine the rate constant (k).

25% of the initial concentration corresponds to 0.25 times the initial concentration, so the concentration at that time is 0.25[A]. We can substitute this value into the rate law expression and solve for k:

0.25[A] = k[A]

0.25 = k

Therefore, the value for the rate constant (k) for the reaction is 0.25 s-1.

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Final answer:

To find the rate constant (k) for a first-order reaction, we can use the half-life formula. The given information states that it takes 3.0 minutes for the concentration of the reactant to decrease to 25% of its initial value. By substituting these values into the equation, we can find the rate constant.

Explanation:

To determine the rate constant (k) for the first-order reaction, we can use the formula for the half-life of a first-order reaction. The half-life is the amount of time it takes for the concentration of the reactant to decrease to half of its initial value. In this case, it takes 3.0 minutes for the concentration to decrease to 25% of its initial value, which is equivalent to one half-life.

The formula for the first-order half-life is: t1/2 = ln(2)/k
Since the concentration decreases to 25% of its initial value after one half-life, we can use this information to solve for k:

25% = (1/2) * 100% = e-kt1/2
ln(1/2) = -k * t1/2
k = -ln(1/2) / t1/2

Substituting the given values, we have:
k = -ln(1/2) / 3.0 minutes

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How many grams nano3 add to 500g of h20 prepare solution .5 molal nano3?

Answers

Answer is: mass of sodium nitrate is 21,25 g.
m(H₂O) = 500 g · 1 kg/1000 g = 0,5 kg.
b(solution) = 0,500 m = 0,500 mol/kg.
m(NaNO₃) = ?
b(solution) = n(NaNO₃) ÷ m(H₂O).
n(NaNO₃) = 0,500 mol/kg · 0,5 kg.
n(NaNO₃) = 0,25 mol.
m(NaNO₃) = n(NaNO₃) · M(NaNO₃).
m(NaNO₃) = 0,25 mol · 85 g/mol.
m(NaNO₃) = 21,25 g.

Water is a polar molecule, meaning it carries partial charges (δ or δ–) on opposite sides of the molecule. for two formula units of kbr, drag two potassium ions and two bromide ions to where they would most likely appear based on the grouping of the water molecules in the area provided.

Answers

The side of each water molecule with the oxygen atom uncovered will be marginally negative. 
The side of each water molecule with the hydrogen atoms uncovered will be marginally positive. 
So the two Cl{-} particles will be pulled in to the biggest number of positive charges, which happen in the boxes on the upper right and lower left. 
The two Na{+} particles will be pulled in to the biggest number of negative charges, which happen in the boxes on the upper left and lower right.

[tex]{{\mathbf{K}}^{\mathbf{+}}}[/tex] will be dragged towards the side of [tex]{\mathbf{O}}{{\mathbf{H}}^{\mathbf{-}}}[/tex] while [tex]{\mathbf{B}}{{\mathbf{r}}^{\mathbf{-}}}[/tex] will be dragged towards the side of [tex]{{\mathbf{H}}^{\mathbf{+}}}[/tex]. (Refer to the attached image)

Further explanation:

Electronegativity:

It is defined as the tendency of an atom to attract the shared electrons in the bond towards itself is known as electronegativity. The more electronegative atom will more attract the bonding electrons towards itself than the less electronegative one. Therefore the electrons will spend more time with the more electronegative atom than an electropositive atom. The electronegative atom will acquire the partial negative charge, and the electropositive atom will acquire a partial positive charge.

The polarity of the bond can be estimated by the electronegativity difference [tex]\left({\Delta {\text{EN}}}\right)[/tex]. [tex]\Delta{\text{EN}}[/tex]is the electronegativity difference between the two atoms that are bonded to each other. The formula to calculate [tex]\Delta{\text{EN}}[/tex]in XY bond is as follows:

[tex]{\mathbf{\Delta EN=}}\left({{\mathbf{electronegativity of Y}}} \right){\mathbf{-}}\left({{\mathbf{electronegativity of X}}}\right)[/tex]

Here, X is the electropositive atom and Y is the electronegative atom.

Higher the electronegativity difference between the two atoms, more will be the polarity of the bond and vice-versa.

Water is a polar molecule. Hydrogen atom acquires partial positive charge while oxygen atom is partially negatively charged. So the end of the water molecule with hydrogen is positively charged, and that with oxygen is negatively charged.

In the case of a potassium-bromine bond, bromine is more electronegative than potassium. So the electrons will be more attracted towards bromine due to which it develops a partial negative charge. Potassium, being less electronegative than bromine, in turn, acquires a partial positive charge. This separation of charge results in the formation of a polar bond between potassium and bromine.

So [tex]{{\text{K}}^+}[/tex] will be dragged towards the side of [tex]{\text{O}}{{\text{H}}^-}[/tex] while [tex]{\text{B}}{{\text{r}}^-}[/tex] will be dragged towards the side of [tex]{{\text{H}}^+}[/tex].

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Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Covalent bonding and molecular structure

Keywords: electronegativity difference, electropositive, electronegative, electrons, polar, KBr, K, Br, K+, Br-, H+, OH-, potassium, bromine, hydrogen, oxygen.

Consider the reaction a + b c +
d. at biochemical equilibrium (25°c, ph of 7), the concentration of a is 0.2 m, the concentration of b is 0.2 m, the concentration of c is 0.8 m, and the concentration of d is 0.8 m. calculate δg and δg° ′ under these conditions.

Answers

when the reaction is at  equilibrium  ∴ΔG = Zero 
now we need to get Δ G°, we can get it from this formula:
ΔG° = - RT㏑K(eq)
when we have R = 8.315 J/mol°K and T in Kelvin = 25+273 = 298
so we need to get the K(eq) from this formula:
K(eq) = concentration of products / concentration of reactants
          = [ C] [ D] / [A] [B]
          = (0.8*0.8) / (0.2*0.2) = 16
by substitution in ΔG° formula:
∴ ΔG° = - 8.315 * 298 *㏑(16) = -6870 Jmol^-1 /1000 = - 6.87 KJ mol^-1

pls help me!!

Which of the following is a large body in space that orbits a star and does not produce its own light?

Moon
Planet
Sun
Universe

Answers

The planet because the sun reflects off the planet which creates the light.
Planet is the answer and moon is orbit the planet and that doesn't produce light either 

What products are formed from monochlorination of (2r)−2−bromobutane at c1 and c4? draw the products using skeletal structures?

Answers

From monochlorination of (2R)−2−bromobutane at C1 is formed (2S)-2-bromo-1-chlorobutane.

From monochlorination of (2R)−2−bromobutane at C4 is formed (2R)-3-bromo-1-chlorobutane.

According to Cahn-Ingold-Prelog rules, the priority of halogen substituents decreases in the following sequence:

-I > -Br > -Cl > -F

According to the rule, chlorine has priority over bromine, so the configuration changes at C1 substitution.


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