A variation of the acetamidomalonate synthesis can be used to synthesize serine. The process involves the following steps: Ethoxide ion deprotonates diethyl acetamidomalonate, forming enolate anion 1; Enolate anion 1 makes a nucleophilic attack on formaldehyde, forming tetrahedral intermediate 2; Protonation of the oxyanion forms alcohol 3; Acid hydrolysis yields dicarboxyamino alcohol 4; Decarboxylation leads to the final amino acid. Write out the mechanism on a separate sheet of paper, and then draw the structure of dicarboxyamino alcohol 4.

Answers

Answer 1

Answer:

See detailed mechanism in the image attached

Explanation:

The mechanism shown in detail below is the synthesis of serine in steps.

The first step is the attack of the ethoxide ion base on the diethyl acetamidomalonate substrate giving the enolate and formaldehyde.

The second step is the protonation of the oxyanion from (1) above to form an alcohol as shown.

Acid hydrolysis of the alcohol formed in (3) above yields a tetrahedral intermediate, a dicarboxyamino alcohol.

Decarboxylation of this dicarboxyamino alcohol yields serine, the final product as shown in the image attached.

A Variation Of The Acetamidomalonate Synthesis Can Be Used To Synthesize Serine. The Process Involves

Related Questions

Consider the volumes of benzaldehyde and acetone that you used for your scaled-down version of the lab (as described on the Aldol Condensation page and in the Aldol Lab quiz), and consider how these reactants are added to the reaction mixture. There is a potential problem associated with the preparation and addition of the benzaldehyde/acetone mixture, which would be exacerbated by the scaling down of the reaction. What is this problem, and why would this become a bigger problem at smaller scale

Answers

Answer:

Aldol condensation is possible only when their is alpha Hydrogen atom is present. It ia present only in the acetophenone and not in benzaldehyde.

Explanation:

Problem PageQuestion The airbags that protect people in car crashes are inflated by the extremely rapid decomposition of sodium azide, which produces large volumes of nitrogen gas. 1. Write a balanced chemical equation, including physical state symbols, for the decomposition of solid sodium azide () into solid sodium and gaseous dinitrogen. 2. Suppose of dinitrogen gas are produced by this reaction, at a temperature of and pressure of exactly . Calculate the mass of sodium azide that must have reacted. Round your answer to significant digits.

Answers

Answer:

1. 2NaN₃(s) → 2Na(s) + 3N₂(g)

2. 14.5 g NaN₃

Explanation:

The answer is incomplete, as it is missing the required values to solve the problem. An internet search shows me these values for this question. Keep in mind that if your values are different your result will be different as well, but the solving methodology won't change.

" The airbags that protect people in car crashes are inflated by the extremely rapid decomposition of sodium azide, which produces large volumes of nitrogen gas. 1. Write a balanced chemical equation, including physical state symbols, for the decomposition of solid sodium azide (NaN₃) into solid sodium and gaseous dinitrogen. 2. Suppose 71.0 L of dinitrogen gas are produced by this reaction, at a temperature of 16.0 °C and pressure of exactly 1 atm. Calculate the mass of sodium azide that must have reacted. Round your answer to 3 significant digits. "

1. The reaction that takes place is:

2NaN₃(s) → 2Na(s) + 3N₂(g)

2. We use PV=nRT to calculate the moles of N₂ that were produced.

P = 1 atm

V = 71.0 L

n = ?

T = 16.0 °C ⇒ 16.0 + 273.16 = 289.16 K

1 atm * 71.0 L = n * 0.082 atm·L·mol⁻¹·K⁻¹ * 289.16 Kn = 0.334 mol

Now we convert N₂ moles to NaN₃ moles:

0.334 mol N₂ * [tex]\frac{2molNaN_{3}}{3molN_2}[/tex] = 0.223 mol NaN₃

Finally we convert NaN₃ moles to grams, using its molar mass:

0.223 mol NaN₃ * 65 g/mol = 14.5 g NaN₃

what are the three laws of motion​

Answers

Answer:

Newton's three laws of motion may be stated as follows:

Every object in a state of uniform motion will remain in that state of motion unless an external force acts on it.

Force equals mass times acceleration

For every action there is an equal and opposite reaction

Explanation:

pls mark brainliest

What is the scaling factor of the molar mass of
this compound, having an empirical formula of
CH20, is 150 g/mol?

Answers

Final answer:

The scaling factor is determined by dividing the compound's actual molar mass (150 g/mol) by the molar mass of its empirical formula CH2O (30 g/mol), which results in a factor of 5. The molecular formula of the compound is C5H10O5.

Explanation:

The student's question is asking about the scaling factor of a compound's molar mass based on its empirical formula. The empirical formula is CH2O, which has a molar mass of 30 g/mol (C = 12, H = 1 x 2 = 2, O = 16). If the compound's actual molar mass is 150 g/mol, we divide the actual molar mass by the empirical formula's molar mass to find the scaling factor.

Scaling factor = Actual molar mass / Empirical formula molar mass

= 150 g/mol / 30 g/mol

= 5

Thus, the actual compound's formula is obtained by multiplying each subscript in the empirical formula by the scaling factor of 5. Therefore, the molecular formula of the compound is C5H10O5.

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Write a balanced half-reaction for the oxidation of gaseous arsine AsH3 to aqueous arsenic acid H3AsO4 in acidic aqueous solution. Be sure to add physical state symbols where appropriate.

Answers

Answer:

AsH3(g) + 4H2O(l)------> H3AsO4(aq) +8H^+(aq) + 8e-

Explanation:

Now we need to work through the problem in steps.

Step1: reaction of arsine with water

AsH3(g) + 4H2O(l) -----> H3AsO4(aq) this is the molecular reaction

Step II: oxygen is balanced using hydrogen ions

AsH3(g) + 4H2O(l)------> H3AsO4(aq) +8H^+(aq)

Step III: We specify the number of electrons transferred in the redox reaction

AsH3(g) + 4H2O(l)------> H3AsO4(aq) +8H^+(aq) + 8e-

The balanced half-reaction for the oxidation of gaseous arsine AsH₃ to

aqueous arsenic acid H₃AsO₄ in acidic aqueous solution is

AsH₃(g) + 4H₂O(l)------> H₃AsO₄(aq) +8H+(aq) + 8e-

The first step involves reaction of arsine with water

AsH₃(g) + 4H₂O(l) -----> H₃AsO₄(aq)

The second step involves balancing oxygen using hydrogen ions

AsH₃(g) + 4H₂O(l)------> H₃AsO₄(aq) +8H⁺(aq)

The third and final step involves noting the the number of electrons transferred in the redox reaction

AsH₃(g) + 4H₂O(l)------> H₃AsO4(aq) +8H⁺(aq) + 8e⁻

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A mixture of He
, N2
, and Ar
has a pressure of 13.6
atm at 28.0
°C. If the partial pressure of He
is 1831
torr and that of Ar
is 997
mm Hg, what is the partial pressure of N2
?

Answers

Answer : The partial pressure of nitrogen gas in the mixture is, 9.88 atm

Explanation :

According to the Dalton's Law, the total pressure of the gas is equal to the sum of the partial pressure of individual gases.

Formula used :

[tex]p_T=p_{He}+p_{Ar}+p_{N_2}[/tex]

where,

[tex]p_T[/tex] = total pressure of gas  = 13.6 atm

[tex]p_{He}[/tex] = partial pressure of helium gas  = 1831 torr =  2.41 atm

[tex]p_{Ar}[/tex] = partial pressure of argon gas  = 997 torr =  1.31 atm

Conversion used: (1 atm = 760 torr)

[tex]p_{N_2}[/tex] = partial pressure of nitrogen gas  = ?

Now put all the given values in the above formula, we get:

[tex]13.6=2.41+1.31+p_{N_2}[/tex]

[tex]p_{N_2}=9.88atm[/tex]

Thus, the partial pressure of nitrogen gas in the mixture is, 9.88 atm

What is the name of this compound?
CH3CH2OCH2CH2CH3

Answers

Answer:

(B) ethyl-propyl-ether

Explanation:

ethyl-propyl-ether

a step by step explanation

As the compound has ether as functional group the name of the compound is ethyl propyl ether.

Functional group is defined as a substituent or group of toms or an atom which causes chemical reactions.Each functional group will react similarly regardless to the parent carbon chain to which it is attached.This helps in prediction of chemical reactions.

The reactivity of functional group can be enhanced by making modifications in the functional group .Atoms present in functional groups are linked to each other by means of covalent bonds.They are named along with organic compounds according to IUPAC nomenclature.

The compound has ether as functional group,thus  the name of the compound is ethyl propyl ether.

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Which of the following is/are a true statement about 1 mole samples of oxygen,
hydrogen, and nitrogen gas at STP?

I. Only oxygen and hydrogen are diatomic molecules.
II. All 3 samples occupy the same volume.
III. All 3 samples have the same mass.

A) I only
B) II only
C) I and II only
D) II and III only
E) I, II and III

Answers

i think it could possibly could be D

A simple equation relates the standard free‑energy change, ΔG∘′, to the change in reduction potential. ΔE0′. ΔG∘′ = −nFΔE0′ The n represents the number of transferred electrons, and F is the Faraday constant with a value of 96.48 kJ⋅mol^(−1)⋅V^(−1). Use the standard reduction potentials provided to determine the standard free energy released by reducing O2 with FADH2. FADH2 + 1/2O2 → FAD + H2O
given that the standard reduction potential for the reduction of oxygen to water is +0.82 V and for the reduction of FAD to FADH2 is +0.03 V.

Answers

Answer :  The value of standard free energy is, -152.4 kJ/mol

Explanation :

The given balanced cell reaction is:

[tex]FADH_2+\frac{1}{2}O_2\rightarrow FAD+H_2O[/tex]

The half reaction will be:

Reaction at anode (oxidation) : [tex]FADH_2\rightarrow FAD+2H^++2e^-[/tex]     [tex]E^0_{Anode}=+0.03V[/tex]

Reaction at cathode (reduction) : [tex]\frac{1}{2}O_2+2H^++2e^-\rightarrow H_2O[/tex]     [tex]E^0_{Cathode}=+0.82V[/tex]

First we have to calculate the standard electrode potential of the cell.

[tex]E^o=E^o_{cathode}-E^o_{anode}[/tex]

[tex]E^o=(+0.82V)-(+0.03V)=+0.79V[/tex]

Relationship between standard Gibbs free energy and standard electrode potential follows:

[tex]\Delta G^o=-nFE^o_{cell}[/tex]

where,

[tex]\Delta G^o[/tex] = standard free energy = ?

n = number of electrons transferred = 2

F = Faraday constant = [tex]96.48kJ.mol^{-1}V^{-1}[/tex]

[tex]E^o_{cell}[/tex]  = standard electrode potential of the cell = 0.79 V

Now put all the given values in the above formula, we get:

[tex]\Delta G^o=-(2)\times (96.48kJ.mol^{-1}V^{-1})\times (0.79V)[/tex]

[tex]\Delta G^o=-152.4kJ/mol[/tex]

Therefore, the value of standard free energy is, -152.4 kJ/mol

Final answer:

To calculate the standard free energy change for the reduction of O2 with FADH2, we first calculate the difference in reduction potentials to find ΔE0′. We then substitute the values into the relation ΔG∘′ = −nFΔE0′, with n=2 and Faraday constant F=96.48 kJ⋅mol‾¹⋅V‾¹. The calculated ΔG∘′ is -152.4384 kJmol‾¹.

Explanation:

The standard free energy change, ΔG∘′, is related to the change in reduction potential, ΔE0′, by the equation ΔG∘′ = −nFΔE0′. To find the standard free energy released by the reduction of O2 with FADH2, we first need to find ΔE0′.

ΔE0′ is given by the difference in reduction potentials of the two half reactions involved. In this case, the reduction of O2 to H2O (+0.82 V) and the reduction of FAD to FADH2 (+0.03 V). Therefore, ΔE0′ = E(O2/H2O) - E(FAD/FADH2) = +0.82 V - (+0.03 V) = +0.79 V.

Inserting the values into the equation, and knowing that the number of transferred electrons (n) is 2 and the Faraday constant (F) is 96.48 kJ⋅mol‾¹⋅V‾¹, we get ΔG∘′ = −2 * 96.48 kJ⋅mol‾¹⋅V‾¹ * (+0.79 V) = -152.4384 kJmol‾¹. Thus, the standard free energy released by reducing O2 with FADH2 is -152.4384 kJmol‾¹.

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An unknown liquid has a pH lower than 7, conducts electricity poorly, and tastes sour, what kind of solution is the unknown?

Answers

Answer:

Weak Acid solution

Explanation:

Acidic substances usually have a pH of 0.1-6.9 or it is usually less than 7. Acidic substances too have a very unique sour taste.

However it is understood that it conducts electricity poorly which means the acid doesn’t readily dissociate in water. This makes it a weak acid and an example is Acetic acid.

Copper was the first metal to be produced from its ore because it is the easiest to smelt, that is, to refine by heating in the presence of carbon. The ore was likely malachite (Cu2(OH)2CO3). What is the mass percent of copper in malachite?

Answers

Answer:

57.5%

Explanation:

The mass percent of copper in malachite (Cu2(OH)2CO3) can be determined as follow:

Molar Mass of malachite (Cu2(OH)2CO3) = (2x63.5) + 2(16 +1) + 12 + (16x3) = 127 + 2(17) + 12 + 48 = 127 + 34 + 12 + 48 = 221g/mol

Mass of Cu in Cu2(OH)2CO3 = 2 x 63.5 = 127g

The percentage by mass of Cu in Cu2(OH)2CO3 is given by:

Mass of Cu/Molar Mass of Cu2(OH)2CO3 x 100

=> 127/221 x 100

=> 57.5%

Therefore, 57.5% by mass of Cu is contained in malachite Cu2(OH)2CO3

What is the pH of an aqueous solution at 25.0°C in which [H+] is 0.0025 M?
A) 5.99 B) 2.60 C) -2.60 D) -5.99 E) none of the above

Answers

Final answer:

The pH of an aqueous solution at 25.0°C with [H+] = 0.0025 M is calculated using the pH formula and results in a pH of 2.60, which is answer option B.

Explanation:

The pH of an aqueous solution at 25.0°C with a hydrogen ion concentration [H+] of 0.0025 M can be found using the pH formula:

pH = -log [H3O+]

By substituting the given concentration into the formula, the calculation would be:

pH = -log(0.0025) = -log(2.5 x 10-3)

Using a scientific calculator:

pH = 2.60

Therefore, the correct answer is B) 2.60.

The 1H NMR spectrum of an unknown acid has the following peaks: δ (ppm) = 12.71 (1H, s), 8.04 (2H, d), 7.30 (2H, d), 2.41 (3H, s) Which structure best fits this spectral information?

Answers

Answer:

The most appropriate structure given the sparse spectral data is 4-acetyl benzoic acid (see attached).

Explanation:

It is difficult to accurately elucidate the structure of this compound without its chemical formula. But from the 1H NMR spectral data shows a total of 8 hydrogen atoms:

12.71 (1H. s) -  confirms presence of carboxylic acid proton, C=O-OH8.04 (2H, d) - confirms aromatic hydrogen7.30 (2H, d) - confirms aromatic hydrogen2.41 (3H,s) - confirms C=C hydrogen or ketone O=C-RCH3

The attached files show the structure and the neighboring hydrogen atoms.

The most likely structure i 4-acetyl benzoic acid

A student measures the S2- concentration in a saturated aqueous solution of iron(II) sulfide to be 2.29×10-9 M. Based on her data, the solubility product constant for iron(II) sulfide is

Answers

Answer:

Ksp FeS = 5.2441 E-18

Explanation:

FeS ↔ Fe2+  + S2-

         S          S           S

∴ Ksp = [Fe2+]*[S2-].....solubility product constant

∴ [S2-] = 2.29 E-9 M = S

⇒ Ksp = (S)(S) = S²

⇒ Ksp = (2.29 E-9)²

⇒ Ksp = 5.2441 E-18

For the reaction ? NO + ? O2 → ? NO2 , what is the maximum amount of NO2 which could be formed from 16.42 mol of NO and 14.47 mol of O2? Answer in units of g. 003 1.0 points For the reaction ? C6H6 + ? O2 → ? CO2 + ? H2O 37.3 grams of C6H6 are allowed to react with 126.1 grams of O2. How much CO2 will be produced by this reaction? Answer in units of gram

Answers

Final answer:

The maximum possible mass of NO2 that could be formed from the given amounts of reactants is 755.20 grams, and the amount of CO2 that would be produced from the combustion of 37.3 grams of C6H6 is 126.10 grams.

Explanation:

Calculating the Maximum Amount of NO2 Formed

For the balanced reaction 2 NO + O2 → 2 NO2, the stoichiometry shows a 1:1 ratio between NO and NO2. With 16.42 mol of NO, if O2 is in excess, 16.42 mol of NO2 could theoretically be formed. The molar mass of NO2 is 46.0055 g/mol, so the maximum mass of NO2 would be 16.42 mol × 46.0055 g/mol = 755.20 grams of NO2.

Amount of CO2 Produced from C6H6 Combustion

The balanced reaction for the combustion of benzene (C6H6) is 2 C6H6 + 15 O2 → 12 CO2 + 6 H2O. One mole of C6H6 (78.1134 g/mol) produces 6 moles of CO2. With 37.3 grams of C6H6, there would be 37.3 g / 78.1134 g/mol = 0.4775 mol C6H6 which would yield 0.4775 mol C6H6 × 6 mol CO2/mol C6H6 = 2.865 mol CO2.

The molar mass of CO2 is 44.0095 g/mol, so the mass of CO2 would be 2.865 mol × 44.0095 g/mol = 126.10 grams of CO2.

Final answer:

The maximum amount of NO2 that can be formed from 16.42 mol of NO and 14.47 mol of O2 is 755.1 grams. When reacting 37.3 grams of C6H6 with 126.1 grams of O2, the amount of CO2 produced is 125.96 grams.

Explanation:

Reaction Stoichiometry and Limiting Reactants:

To determine the maximum amount of NO2 that can be formed from 16.42 mol of NO and 14.47 mol of O2, we use the balanced chemical equation 2 NO + O2 → 2 NO2. This equation shows that 2 moles of NO react with 1 mole of O2 to produce 2 moles of NO2. We can see that NO will be the limiting reactant because 14.47 mol of O2 would theoretically react with only 28.94 mol of NO, which is more than the 16.42 mol of NO present.

Since NO is the limiting reactant, we can form a maximum of 16.42 mol of NO2. Using the molar mass of NO2 (46.01 g/mol), this is equivalent to 755.1 grams of NO2. For the reaction C6H6 + O2 → CO2 + H2O, first, we would calculate the moles of C6H6 and O2, then use stoichiometry to determine the moles of CO2 produced. The molar mass of C6H6 (78.11 g/mol) means we start with 0.477 moles of C6H6.

From the balanced equation, we can see that for every 2 moles of NO, we need 1 mole of O2 to produce 2 moles of NO2. This gives us the mole ratio of NO to O2 as 2:1.

To find the limiting reagent (the reactant that is completely consumed and determines the maximum amount of product formed), we compare the number of moles of each reactant to the mole ratio.

For NO:

16.42 mol NO * (1 mol O2 / 2 mol NO) = 8.21 mol O2

For O2:

14.47 mol O2 * (2 mol NO / 1 mol O2) = 28.94 mol NO

Since the calculated amount of O2 (28.94 mol) is greater than the actual amount of O2 (14.47 mol), O2 is in excess and NO is the limiting reagent.

Now, we need to calculate the maximum amount of NO2 produced from the limiting reagent, which is NO.

From the balanced equation, we know that 2 moles of NO react to form 2 moles of NO2. Therefore, the mole ratio of NO to NO2 is 2:2.

Using the moles of NO (8.21 mol), we can calculate the moles of NO2:

8.21 mol NO * (2 mol NO2 / 2 mol NO) = 8.21 mol NO2

To convert moles of NO2 to grams, we need to use the molar mass of NO2, which is 46.01 g/mol.

8.21 mol NO2 * 46.01 g/mol = 377.27 g NO2

Therefore, the maximum amount of NO2 that could be formed from 16.42 mol of NO and 14.47 mol of O2 is 377.27 grams of NO2.

For the second question, we have the balanced chemical equation:

C6H6 + 15O2 → 6CO2 + 3H2O

From the balanced equation, we can see that for every mole of C6H6, we need 15 moles of O2 to produce 6 moles of CO2.

To determine the amount of CO2 produced, we first need to find the limiting reagent.

For C6H6:

37.3 g C6H6 * (1 mol C6H6 / 78.11 g C6H6) = 0.477 mol C6H6

For O2:

126.1 g O2 * (1 mol O2 / 32 g O2) = 3.94 mol O2

Since the calculated amount of C6H6 (0.477 mol) is less than the actual amount of O2 (3.94 mol), C6H6 is the limiting reagent.

Using the mole ratio from the balanced equation, we find that 0.477 mol of C6H6 will produce 6 moles of CO2.

To convert moles of CO2 to grams, we need to use the molar mass of CO2, which is 44.01 g/mol.

0.477 mol CO2 * 44.01 g/mol = 21.0 g CO2

Therefore, 37.3 grams of C6H6 reacted with 126.1 grams of O2 will produce 21.0 grams of CO2.

The rovibrational transition of 1H 35Cl with v = 0 to 1, J = 11 to 10 occurs at 2757.89 cm-1 , and the transition with v = 0 to 1, J = 10 to 9 occurs at 2779.07 cm-1 . From this information, i) calculate the spring constant of the vibrational potential (assuming the harmonic approximation and rigid rotor approximation) and ii) the equilibrium length of the HCl bond.

Answers

Answer:

Explanation:

find the solution below

Gaseous ammonia (NH3) reacts with gaseous oxygen to form gaseous nitrogen monoxide and gaseous water. Express your answer as a chemical equation. Identify all of the phases in your answer.

Answers

Answer:

The chemical equation is given as:

[tex]4NH_3(g)+5O_2(g)\rightarrow 4NO(g)+6H_2O(g)[/tex]

Explanation:

When gaseous ammonia reacts with gaseous oxygen it gives nitrogen monoxide gas and water vapors as product.

The chemical equation is given as:

[tex]4NH_3(g)+5O_2(g)\rightarrow 4NO(g)+6H_2O(g)[/tex]

According to reaction, 4 moles of ammonia reacts with 5 moles of oxygen gas to give 4 moles of nitrogen monoxide gas and 6 moles of water vapor.

To write the skeletal equation, begin by writing the chemical formula for each reactant and product.

Reactants:

1. Ammonia's chemical formula is given as  NH3.

2. Gaseous oxygen exists as a diatomic molecule with the chemical formula  O2.

Products:

1. Nitrogen monoxide has the chemical formula of  NO.

2. The chemical formula for water is  H2O.

Therefore, the skeletal equation is written as:

NH3(g)+O2(g)→NO(g)+H2O(g)

Now count the number of each atom on each side of the equation to determine if the equation is balanced.

Reactants

1N atom

3H atoms

2O atoms

Products

1N atom

2H atoms

2O atoms

Begin by balancing the number of hydrogen atoms by adding a coefficient of 2 to  NH3 and a coefficient of 3 to  H2O. Next, balance the number of nitrogen atoms by adding a coefficient of 2 to  NO. Now there are two oxygen atoms on the reactant's side and five oxygen atoms on the product's side of the reaction. Since only whole number coefficients should be used, all coefficients need to be increased by a factor of two to balance the oxygen atoms. Thus the coefficient for  NH3 is 4, the coefficient for  H2O is 6, and the coefficient for  NO is 4. Finally, balance the oxygen atoms by adding a coefficient of 5 to  O2. The balanced equation is:

4NH3(g)+5O2(g)→4NO(g)+6H2O(g)

The price of gold on April 15,2000 was $282/t.oz. How much did 100.0cm^3 of gold cost that day if 1.00 t.oz=28.4 grams?

Answers

Answer:

price ($) Au = $ 19183.94

Explanation:

april 15,2000:

∴ price Au = $ 282/t.oz

∴ 1.00 t.oz = 28.4 g

∴ V Au = 100.0 cm³  ⇒  price ($) = ?

∴ δ Au = 19.32 g/cm³

⇒ mass Au = (100.0 cm³)*(19.32 g/cm³)

⇒ m Au = 1932 g

⇒ price ($) = (1932 g Au)*(1.00 t.oz/28.4 g Au)*( $ 282/t.oz)

⇒ price ($) = $ 19183.94

Final answer:

To calculate the cost of 100.0cm3 of gold on April 15, 2000, convert the volume to grams, then to troy ounces, and multiply by the price per troy ounce.

Explanation:

To calculate the cost of 100.0cm3 of gold on April 15, 2000, we need to convert the volume of gold to grams and then to troy ounces. First, convert 100.0cm3 to grams by multiplying it by the density of gold (19.3 g/cm3). This gives us 1930 grams. Next, convert grams to troy ounces by dividing by the conversion factor of 28.4 grams per troy ounce. This gives us approximately 67.96 troy ounces. Finally, multiply the number of troy ounces by the price per troy ounce to find the cost. Therefore, 100.0cm3 of gold on April 15, 2000 would have cost $19,191.12.

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Select all the correct locations on the image. The model shows global atmospheric circulation. Identify the wind directions that are correct.

Answers

Answer:1 2 4

Explanation:

Answer: 1.3.5.6.

Explanation:

The pressure of a balloon made of a stretchy material is held constant at
2 atm. If the initial volume is 250 mL at room temperature (25 ˚C), what
would be the final volume at 50 ˚C?

Answers

Answer:

New volume is 271 mL

Explanation:

To determine the volume for a gas, when the pressure remains constant we follow this ratio:

V₁ / T₁ = V₂ / T₂

Remember the Ideal Gases Law → P . V = n . R . T

That's why we propose V / T

We need to determine the Absolute T°

25°C + 273 = 298 K

50°C + 273 = 323 K

We convert the volume from mL to L → 250 mL . 1L / 1000 mL = 0.250L

Now we replace: 0.250L / 298K = V₂ / 323K

V₂ = (0.250L / 298K) . 323K  → 0.271 L

In conclussion volume of a gas will be increased, while the temperature is also increased and the pressure remains constant.

Answer:

The final volume is 271 mL

Explanation:

Step 1: Data given

The initial pressure = 2 atm

The pressure will be kept constant

The initial volume = 250 mL = 0.250 L

The initial temperature = 25°C = 298 K

The final temperature = 50 °C = 323 K

Step 2: Calculate the final volume

V1/T1 = V2/T2

⇒with V1 = the initial volume = 0.250 L

⇒with T1 = the initial temperature = 25 °C = 298 K

⇒with V2 = the final volume = TO BE DETERMINED

⇒with T2 = the final temperature = 50 °C = 323 K

0.250 L / 298 K = V2 / 323 K

V2 = (0.250 /298) *323

V2 = 0.271 L = 271 mL

The final volume is 271 mL

What is the heat energy released?

Estimate the heat energy released when one mole of the of the fuel molecule acetylene C2H2 undergoes complete combustion with oxygen to form carbon dioxide and water.

Answers

Thermal energy (also called heat energy) is produced when a rise in temperature causes atoms and molecules to move faster and collide with each other. The energy that comes from the temperature of the heated substance is called thermal energy.

The Ph scale is logarithmic; how many times stronger is a Ph of 4 versus a Ph of 2?

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Answer:

A pH greater than 7 is basic. The pH scale is logarithmic and as a result, each whole pH value below 7 is ten times more acidic than the next higher value. For example, pH 4 is ten times more acidic than pH 5 and 100 times (10 times 10) more acidic than pH 6.

At 330 K the vapor pressure of pure n-pentane is 1.92 atm and the vapor pressure of pure n-octane is 0.07 atm. If 330K is the normal boiling point for a solution of these two substances, what will the mole fractions of each substance be in that solution

Answers

Answer: mole fractions are

For n-pentane = 0.965

For n-octane = 0.035

Explanation: pressure exerted by each gas is,

n-pentane = 1.92atm

n-octane = 0.07atm

Total pressure exerted = 1.92 + 0.07

= 1.99atm.

Recall that the partial pressure exerted by each gas is the product of its mole fraction and the total pressure, that is,

Pres. n-pentane = n x pressure(total)

1.92 = n x 1.99

n = 1.92/1.99 = 0.965 for n-pentane

For n-octane,

n = 1 - 0.965 = 0.035 for n-octane.

Enter your answer in the provided box. Calculate the pH of 1.00 L of a buffer that is 1.00 M in acetic acid and 1.00 M in sodium acetate after the addition of 0.450 mole of NaOH.

Answers

Answer : The  pH of buffer is, 5.17

Explanation : Given,

[tex]pK_a=4.75[/tex]

Concentration of acetic acid = 1.00 M

Concentration of sodium acetate = 1.00 M

Volume of solution = 1.00 L

As, [tex]Moles=Concentration\times Volume[/tex]

So,

Moles of acetic acid = 1.00 mol

Moles of sodium acetate = 1.00 mol

Moles of NaOH added = 0.450 mol

The balanced chemical equilibrium reaction is:

                      [tex]CH_3COO+NaOH\rightleftharpoons CH_3COONa+H_2O[/tex]

Initial mole        1                0.450              1

At eqm.         (1-0.450)            0            (1+0.450)

                       = 0.55                                =1.450

Now we have to calculate the pH of buffer.

Using Henderson Hesselbach equation :

[tex]pH=pK_a+\log \frac{[Salt]}{[Acid]}[/tex]

[tex]pH=pK_a+\log \frac{[CH_3COONa]}{[CH_3COOH]}[/tex]

Now put all the given values in this expression, we get:

[tex]pH=4.75+\log (\frac{1.450}{0.55})[/tex]

[tex]pH=5.17[/tex]

Therefore, the pH of buffer is, 5.17

What is the partial pressure of carbon dioxide in a container that contains 3.63 mol of oxygen, 1.49 mol of nitrogen, and 4.49 mol of carbon dioxide when the total pressure is 871 mmHg?

Answers

Answer:

Partial pressure of CO₂ is 406.9 mmHg

Explanation:

To solve the question we should apply the concept of the mole fraction.

Mole fraction = Moles of gas / Total moles

We have the total moles of the mixture, if we have the moles for each gas inside. (3.63 moles of O₂, 1.49 moles of N₂ and 4.49 moles of CO₂)

Total moles = 3.63 mol O₂ + 1.49 mol N₂ + 4.49 mol CO₂ = 9.61 moles

To determiine the partial pressure of CO₂ we apply

Mole fraction of CO₂ → mol of CO₂ / Total moles = P. pressure CO₂ / Total P

Partial pressure of CO₂ = (mol of CO₂ / Total moles) . Total pressure

We replace values: (4.49 moles / 9.61 moles) . 871 mmHg = 406.9 mmHg

Answer:

Partial pressure O2 = 329 mmHg

Partial pressure N2 = 135 mmHg

Partial pressure CO2 = 407 mmHg

Explanation:

Step 1: Data given

Number of moles oxygen (O2) = 3.63 moles

Number of moles nitrogen (N2) = 1.49 moles

Number of moles carbon dioxide (CO2) = 4.49 moles

Total pressure = 871 mmHg

Step 2: Calculate total number of moles

Total moles = moles O2 + moles N2 + moles CO2

Total moles = 3.63 + 1.49 + 4.49

Total moles =  9.61 moles

Step 3: Calculate the mol ratio

Mol ratio number of moles compound / total moles

Mol ratio O2 = 3.63 moles / 9.61 moles

Mol ratio O2 = 0.378

Mol ratio N2 = 1.49 moles / 9.61 moles

Mol ratio N2 = 0.155

Mol ratio CO2 = 4.49 moles / 9.61 moles

Mol ratio CO2 = 0.467

Step 4: Calculate partial pressure

Partial pressure = mol ratio * total pressure

Partial pressure O2 = 0.378 * 871 mmHg

Partial pressure O2 = 329 mmHg

Partial pressure N2 = 0.155 * 871mmHg

Partial pressure N2 = 135 mmHg

Partial pressure CO2 = 0.467 * 871 mmHg

Partial pressure CO2 = 407 mmHg

Ethers react with HI to form two cleavage products. One of the products might react further with HI. In the first box below draw the two major products that could be recovered after treatment with one equivalent of HI. In the second box draw the two major products that could be recovered after treatment with excess HI. (If a product of the first step does not undergo additional reaction with excess HI, repeat its structure in the second box.)

Answers

Answer:

Explanation:

the solution is solved below

When ethers react with HI, treatment with one equivalent of HI produces an alcohol and an alkyl iodide as major products. Treatment with excess HI yields both alkyl iodides as major products.

Ethers react with HI to form two cleavage products. When treated with one equivalent of HI, the major products that could be recovered are an alcohol and an alkyl iodide. The alcohol is formed by the substitution of the ether oxygen with a hydrogen atom from HI, and the alkyl iodide is formed by the substitution of one of the alkyl groups of the ether with iodine.

When treated with excess HI, the major products that could be recovered are both alkyl iodides. The initial products from the first step do not further react but are still recovered.

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Drag each title to the correct location identify each process as carbon source or carbon sink

Answers

Answer:

PLATO Answer

Explanation:

Underneath Photosynthesis Is Carbon Sink

Underneath Animals Is Carbon Sink

Underneath Combustion Is Carbon Source

Final answer:

Among the given options, only the title 'a' correctly identifies the processes as carbon sources and sinks. Burning fossil fuels is a carbon source, while oceans are a carbon sink. The other titles misinterpret the roles of various processes in the carbon cycle.

Explanation:

The correct title to location identifications for each process as carbon source or sink are as follows:

a. Carbon sources, such as burning fossil fuels, produce carbon while carbon sinks, such as oceans, absorb carbon.b. Incorrect, as carbon sources like volcanic activity produce carbon, they don't absorb it. And carbon sinks such as vegetation absorb carbon, they don't produce it.c. Incorrect, as carbon sources like vegetation produce carbon, they do not absorb it. Carbon sinks, like volcanic activity, in reality, does not absorb carbon, they produce it.d. Incorrect, because carbon sources (for example, volcanic activity) produce carbon and don't absorb it, and carbon sinks (for example, burning fossil fuels) actually absorb carbon, rather than producing it.

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Thermal decomposition of 5.0 metric tons of limestone to lime and carbon dioxide requires 9.0 x 106 kJ of heat. Convert this energy to joules A. 9.0 x 108 J B. 9.0 x 104 J C. 9.0 x 103 J D. 9.0 x 109 J E. None of these is within 5% of the correct answer

Answers

Answer : The correct option is, (D) [tex]9.0\times 10^9J[/tex]

Explanation :

As we are given that the energy require for decomposition is, [tex]9.0\times 10^6kJ[/tex].

Now we have to calculate the energy in joules.

Conversion used :

1 kJ = 1000 J

As, 1 kJ of energy = 1000 J

So, [tex]9.0\times 10^6kJ[/tex] of energy = [tex]\frac{9.0\times 10^6kJ}{1kJ}\times 1000J[/tex]

                                          = [tex]9.0\times 10^9J[/tex]

Therefore, the energy in joules is, [tex]9.0\times 10^9J[/tex]

Thermal decomposition of 5.0 metric tons of limestone to lime and carbon dioxide requires 9.0 × 10⁹ Joules of heat.

What is energy?

Enegy is the quantitative property which is used by any system to perform any work.

Chemical reactions generally involves energy in the form of heat energy and given amount of energy is 9.0 × 10⁶ kJ.

We know that:

1 kJ = 1000 J

So, 9.0 × 10⁶ kJ = 9.0 × 10⁶ kJ  × 1000

9.0 × 10⁶ kJ = 9.0 × 10⁹ J

Hence, option (D) is correct i.e. 9.0 × 10⁹ J.

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2. Incoming wastewater, with BOD5 equal to 200 mg/L, is treated in a well-run secondary treatment plant that removes 90 percent of the BOD. You are to run a five-day BOD test with a standard 300-mL bottle, using a mixture of treated sewage and dilution water (no seed). Assume the initial DO is 9.2 mg/L. a. Roughly what maximum volume of treated wastewater should you put in the bottle if you want to have at least 2.0 mg/L of DO at the end of the test (filling the rest of the bottle with water). (answer in mL)

Answers

Answer:

10.8 ml

Explanation:

The BOD is an empirical test to determine the molecular oxygen used during a specified incubation period (usually five days), for the biochemical degradation of organic matter (carbonaceous demand) and the oxygen used to oxidise inorganic matter.

See attached file

The maximum volume of treated wastewater that will be in the bottle is 10.8 mL.

The given parameters;

wastewater density = 200 mg/Lstandard volume = 300 mLinitial DO = 9.2 mg/L

The dilution factor (P) is calculated as follows;

[tex]200 \ mg/L= \frac{9.2 \ mg/L \ - \ 2\ mg/L}{P} \\\\P = \frac{7.2 \ mg/L}{200 \ mg/L} \\\\P = 0.036[/tex]

The maximum  volume of treated wastewater that will be in the bottle to have at least 2.0 mg/L DO;

[tex]0.036 = \frac{V_w}{300 \ mL} \\\\V_w = 0.036 \times 300 \ mL\\\\V_w = 10.8 \ mL[/tex]

Thus, the maximum volume of treated wastewater that will be in the bottle is 10.8 mL.

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Calculate the final concentration of ONPG (in mM) if you add 1.42 mL of 3.3 mM ONPG and dilute to a final volume of 10 mL with PBS buffer. Report your final answer to two places after the decimal.

Answers

Answer : The final concentration of ONGP is, 0.47 mM

Explanation :

Formula used :

[tex]M_1V_1=M_2V_2[/tex]

where,

[tex]M_1\text{ and }V_1[/tex] are the initial molarity and volume

[tex]M_2\text{ and }V_2[/tex] are the final molarity and volume

We are given:

[tex]M_1=3.3mM\\V_1=1.42mL\\M_2=?\\V_2=10mL[/tex]

Now put all the given values in above equation, we get:

[tex]3.3mM\times 1.42mL=M_2\times 10mL\\\\M_2=0.47mM[/tex]

Hence, the final concentration of ONGP is, 0.47 mM

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