How does heat transfer takes place between any two systems?

Answers

Answer 1

Explanation:

For transfer of heat between any two substances or matter can be occurred by conduction or convection process.

Conduction is a process in which two objects of different temperature are placed in contact with each other. Therefore, heat transfers from hotter object to colder object until the temperature of both objects becomes equal.

For example, a metal spoon placed in a hot cup of tea.

Convection is a process in which a fluid generally liquid or gas is heated and denser material (colder) sinks at the bottom whereas less denser material (hotter) rises at the top. This causes conventional currents in the fluid.

For example, heating rice in a pot full of water.


Related Questions

The depletion of ozone (O3) in the stratosphere has been a matter of great concern among scientists in recent years. It is believed that ozone can react with nitric oxide (NO) that is discharged from the high-altitude jet plane, the SST. The reaction is O3 + NO longrightarrow O2 + NO2 If 0.781 g of O3 reacts with 0.589 g of NO, how many grams of NO2 will be produced?

Answers

Answer: 0.736 g

Explanation:

[tex]O_3+NO\rightarrow O_2+NO2[/tex]

To calculate the moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

[tex]\text{Number of moles of}O_3=\frac{0.781g}{48g/mol}=0.016moles[/tex]

[tex]\text{Number of moles of}NO=\frac{0.589g}{30g/mol}=0.019moles[/tex]

By Stoichiometry:

1 mole of ozone [tex]O_3[/tex] reacts with 1 mole of nitric oxide [tex]NO[/tex] to form 1 mole of nitrogen dioxide [tex]NO_2[/tex]

0.016 moles of ozone reacts with=[tex]\frac{1}{1}\times 0.016=0.016moles[/tex] of nitric oxide to form 0.016 mole of [tex]NO_2[/tex]

Thus ozone is the limiting reagent as it limits the formation of products and nitric oxide is the excess reagent as (0.019-0.016) g= 0.003 g remains as such.

Mass of [tex]NO_2=moles\times {\text{Molar mass}}=0.016\times 46=0.736g[/tex]

0.736 g of [tex]NO_2[/tex] will be produced.

0.748 grams of [tex]\( \text{NO}_2 \)[/tex] will be produced when 0.781 grams of [tex]\( \text{O}_3 \)[/tex] reacts with 0.589 grams of NO, as [tex]\( \text{O}_3 \)[/tex] is the limiting reactant.

To determine how many grams of [tex]\( \text{NO}_2 \)[/tex] will be produced from the reaction of [tex]\( \text{O}_3 \)[/tex] with NO, we need to follow these steps:

1. Write the balanced chemical equation:

[tex]\text{O}_3 + \text{NO} \longrightarrow \text{O}_2 + \text{NO}_2[/tex]

2. Calculate the moles of reactants:

Moles of [tex]\( \text{O}_3 \)[/tex]:

[tex]\text{Molar mass of } \text{O}_3 = 3 \times 16.00 \, \text{g/mol} = 48.00 \, \text{g/mol}[/tex]

[tex]\text{Moles of } \text{O}_3 = \frac{0.781 \, \text{g}}{48.00 \, \text{g/mol}} = 0.01627 \, \text{mol}[/tex]

Moles of NO:

[tex]\text{Molar mass of } \text{NO} = 14.01 \, \text{g/mol} + 16.00 \, \text{g/mol} = 30.01 \, \text{g/mol}[/tex]

[tex]\text{Moles of } \text{NO} = \frac{0.589 \, \text{g}}{30.01 \, \text{g/mol}} = 0.01963 \, \text{mol}[/tex]

3. Determine the limiting reactant:

The balanced equation shows that 1 mole of [tex]\( \text{O}_3 \)[/tex] reacts with 1 mole of NO.

Compare the moles of each reactant:

[tex]0.01627 \, \text{mol} \, \text{O}_3 \quad \text{and} \quad 0.01963 \, \text{mol} \, \text{NO}[/tex]

Since [tex]\( \text{O}_3 \)[/tex] has fewer moles, it is the limiting reactant.

4. Calculate the moles of [tex]\( \text{NO}_2 \)[/tex] produced:

From the balanced equation, 1 mole of [tex]\( \text{O}_3 \)[/tex] produces 1 mole of [tex]\( \text{NO}_2 \)[/tex].

Therefore, moles of [tex]\( \text{NO}_2 \)[/tex] produced = moles of [tex]\( \text{O}_3 \)[/tex] reacted:

[tex]\text{Moles of } \text{NO}_2 = 0.01627 \, \text{mol}[/tex]

5. Convert moles of [tex]\( \text{NO}_2 \)[/tex] to grams:

Molar mass of [tex]\( \text{NO}_2 \)[/tex]:

[tex]\text{Molar mass of } \text{NO}_2 = 14.01 \, \text{g/mol} + 2 \times 16.00 \, \text{g/mol} = 46.01 \, \text{g/mol}[/tex]

Grams of [tex]\( \text{NO}_2 \)[/tex]:

[tex]\text{Mass of } \text{NO}_2 = 0.01627 \, \text{mol} \times 46.01 \, \text{g/mol} = 0.748 \, \text{g}[/tex]

Antacids, such as Alka-Seltzer, use the reaction of sodium bicarbonate with citric acid in water solution to produce a fizz as follows: 3NaHCO3 + C6H8O7 → 3CO2 + 3H2O + Na3C6H5O7 If 4.11 g of the citric acid (C6H8O7, MW = 192 g/mol) react with excess sodium bicarbonate (NaHCO3), how many grams of carbon dioxide (CO2, MW = 44 g/mol) are formed as the solution fizzes?

Answers

Final answer:

When 4.11 g of citric acid reacts with sodium bicarbonate, 2.82 g of carbon dioxide gas is produced according to the provided chemical reaction.

Explanation:

In the given chemical reaction, 3NaHCO3 + C6H8O7 → 3CO2 + 3H2O + Na3C6H5O7, specifically between sodium bicarbonate and citric acid, it's clear that for every one molecule of citric acid, three molecules of carbon dioxide are formed. Given that you have 4.11 g of citric acid, and knowing that the molecular weight of citric acid is 192 g/mol, first we calculate the number of moles of citric acid by dividing the mass by the molecular weight: 4.11 g/192 g/mol = 0.0214 moles. Since each mole of citric acid react to produce 3 moles of carbon dioxide, then 0.0214 moles of citric acid would produce 0.0214 moles x 3 = 0.0642 moles of CO2. To find the mass of CO2 formed (since its molar mass is 44 g/mol), multiply the resulting moles of CO2 by its molar mass: 0.0642 moles x 44 g/mol = 2.82 g. Therefore, when 4.11 g of citric acid reacts with sodium bicarbonate, 2.82 g of carbon dioxide will form.

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What are the resulting coefficients when you balance the chemical equation for the combustion of ethane, C2H6? In this reaction, ethane is burned in the presence of oxygen (O2) to form carbon dioxide (CO2) and water (H2O). ____C2H6(g)+____O2(g)→____CO2(g)+____H2O(g) Recall that the coefficients of the final balanced equation should be whole numbers. Thus, you might need to multiply through the equation by a factor of two to obtain whole numbers in your last step. If you have trouble balancing the equation below, use the first hint to view a video of a similar equation being balanced. Then, use the rest of the hints to help you balance the equation, step-by-step. Express the coefficients as integers separated by commas. View Available Hint(s)

Answers

Answer: The coefficients are 2, 7, 4 and 6.

Explanation:

Every balanced chemical equation follows Law of conservation of mass.

This law states that mass can neither be created nor be destroyed but it can only be transformed from one form to another form. This means that total mass on the reactant side is equal to the total mass on the product side.

This also means that the total number of individual atoms on the reactant side will be equal to the total number of individual atoms on the product side.

For the given chemical reaction, the balanced equation follows:

[tex]2C_2H_6(g)+7O_2(g)\rightarrow 4CO2(g)+6H_2O(g)[/tex]

On reactant side:

Number of carbon atoms = 4

Number of hydrogen atoms = 12

Number of oxygen atoms = 14

On product side:

Number of carbon atoms = 4

Number of hydrogen atoms = 12

Number of oxygen atoms = 14

Hence, the coefficients are 2, 7, 4 and 6.

Final answer:

To balance the combustion of ethane (C2H6), the correct coefficients are 2 for C2H6, 7 for O2, 4 for CO2, and 6 for H2O resulting in the equation 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O.

Explanation:

The chemical equation for the combustion of ethane to form carbon dioxide and water is C₂H₆ + O₂ → CO₂ + H₂O. After balancing the number of atoms of each element on both sides of the equation, we arrive at the balanced chemical equation: 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O. Thus, the resulting coefficients are 2, 7, 4, and 6.

Firstly, the carbon (C) atoms are balanced. As we have 2 carbon atoms on the left side, we can put the coefficient 2 in front of CO₂ on the right side.Next, we balance the hydrogen (H) atoms. Since we have 6 hydrogen atoms on the left side, we put the coefficient 3 in front of H₂O on the right side.Finally, we balance the oxygen (O) atoms. Counting the oxygen atoms on both sides, we see that we have 7 oxygen atoms on the right (4 from CO₂ and 3 from H₂O), meaning we need 7 O₂ molecules on the left side.

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A 60.0 mL60.0 mL aliquot of a 1.80 M1.80 M solution is diluted to a total volume of 218 mL.218 mL. A 109 mL109 mL portion of that solution is diluted by adding 107 mL107 mL of water. What is the final concentration? Assume the volumes are additive

Answers

Answer:

The final concentration is 0.2497 M.

Explanation:

1. Molarity of the starting solution = [tex]M_1=1.80 M[/tex]

Volume of the starting solution = [tex]V_1=60.0 mL[/tex]

After dilution of the solution to 219 mL.

Molarity of solution after dilution = [tex]M_2[/tex]

Volume of the new solution = [tex]V_2=218 mL[/tex]

[tex]M_1\times V_1=M_2\times V_2[/tex] (Dilution law)

[tex]M_2=\frac{1.80 M\times 60.0 mL}{218 mL}=0.495 M[/tex]

2. Now,109 mL of 0.495 M solution was diluted by 107 mL

Molarity of the solution = [tex]M_1=0.495 M[/tex]

Volume of the solution = [tex]V_1=109 mL[/tex]

Molarity of solution after dilution = [tex]M_2[/tex]

Volume of the new solution(107 mL of water is added)  = [tex]V_2=109 mL+107 mL = 216 mL[/tex]

[tex]M_1\times V_1=M_2\times V_2[/tex] (Dilution law)

[tex]M_2=\frac{0.495 M\times 109 mL}{216 mL}=0.2497 M[/tex]

The final concentration is 0.2497 M.

Final answer:

To calculate the final concentration after multiple dilutions, use the dilution formula (M1V1 = M2V2) for each dilution step. The first dilution involves diluting a 60.0 mL sample of a 1.80 M solution to 218 mL. The second dilution involves diluting a 109 mL sample of this diluted solution by adding 107 mL of water.

Explanation:

The calculation involved here relies on the formula used for dilution which states that M1V1 = M2V2, where M represents molarity and V represents volume. Initially, we have a 1.80 M solution and we take a 60.0 mL aliquot. After dilution, this becomes a 218 mL solution. Hence, the new molarity (M2) can be calculated as (1.80 M * 60.0 mL) / 218 mL.

From that diluted solution, we take a 109 mL sample and add 107mL of water to it, again diluting this solution further. This process is again similar to the first step of dilution. To find the final concentration, use the dilution formula again with the newly calculated molarity as M1 and 109 mL as V1. The final volume (V2) would be 109 mL + 107 mL. So the final concentration will be given by: (M1 * 109 mL) / (109 mL + 107 mL).

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2Al(s)+Fe2O3(s)−→−heatAl2O3(s)+2Fe(l) 2Al(s)+Fe2O3(s)→heatAl2O3(s)+2Fe(l) If 26.1 kg Al26.1 kg Al reacts with an excess of Fe2O3,Fe2O3, how many kilograms of Al2O3Al2O3 will be produced?

Answers

Answer : The mass of [tex]Al_2O_3[/tex] produced will be, 49.32 Kg

Explanation : Given,

Mass of [tex]Al[/tex] = 26.1 Kg  = 26100 g

Molar mass of [tex]Al[/tex] = 26.98 g/mole

Molar mass of [tex]Al_2O_3[/tex] = 32 g/mole

First we have to calculate the moles of [tex]Al[/tex].

[tex]\text{Moles of }Al=\frac{\text{Mass of }Al}{\text{Molar mass of }Al}=\frac{26100g}{26.98g/mole}=967.38moles[/tex]

Now we have to calculate the moles of [tex]Al_2O_3[/tex].

The balanced chemical reaction is,

[tex]2Al+Fe_2O_3\rightarrow Heat+Al_2O_3+2Fe[/tex]

From the balanced reaction we conclude that

As, 2 moles of [tex]Al[/tex] react to give 1 mole of [tex]Al_2O_3[/tex]

So, 967.38 moles of [tex]Al[/tex] react to give [tex]\frac{967.38}{2}=483.69[/tex] moles of [tex]Al_2O_3[/tex]

Now we have to calculate the mass of [tex]Al_2O_3[/tex].

[tex]\text{Mass of }Al_2O_3=\text{Moles of }Al_2O_3\times \text{Molar mass of }Al_2O_3[/tex]

[tex]\text{Mass of }Al_2O_3=(483.69mole)\times (101.96g/mole)=49317.0324g=49.32Kg[/tex]

Therefore, the mass of [tex]Al_2O_3[/tex] produced will be, 49.32 Kg

In the reaction of 26.1 kg of Al with an excess of Fe₂O₃, whose equation is 2Al(s) + Fe₂O₃(s) → heat + Al₂O₃(s) + 2Fe(l), will be produced 49.31 kilograms of Al₂O₃.

The reaction is:

2Al(s) + Fe₂O₃(s) → heat + Al₂O₃(s) + 2Fe(l)  (1)

To find the mass of Al₂O₃ produced, we need to find the number of moles of Al since it is the limiting reactant (Fe₂O₃ is in excess).

[tex] n_{Al} = \frac{m_{Al}}{A_{Al}} [/tex]   (2)

Where:

[tex]m_{Al}[/tex]: is the mass of Al = 26.1 kg = 26100 g

[tex]A_{Al}[/tex]: is the atomic mass of Al = 26.982 g/mol

The number of moles of Al is (eq 2):

[tex]n_{Al} = \frac{m_{Al}}{A_{Al}} = \frac{26100 g}{26.982 g/mol} = 967.31 \:moles[/tex]

From equation (1) we have that 2 moles of Al react with 1 mol of Fe₂O₃ to form 1 mol of Al₂O₃(s), so the number of moles of Al₂O₃ produced is:

[tex]n_{Al_{2}O_{3}} = \frac{1 \:mol \:Al_{2}O_{3}}{2 \:moles \:Al}*967.31 \:moles \:Al = 483.66 \:moles[/tex]

Finally, the mass of Al₂O₃ in kilograms is:

[tex]m = n_{Al_{2}O_{3}}*MM = 483.66 \:moles*101.96 \:g/mol = 49313.5 g = 49.31 kg[/tex]

Therefore, will be produced 49.31 kilograms of Al₂O₃.

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Which of the following statements is true? A) If Q < K, it means the forward reaction will proceed to form more products. B) If Q > K, it means the forward reaction will proceed to form more products. C) If Q = K, it means the reaction is not at equilibrium. D) All of the above are true. E) None of the above are true.

Answers

Hey there!:

If Q = K, it means the reaction is at equilibrium.

The correct statments are as follows:

A. If Q < K, it means the forward reaction will proceed to form more products.

B. If Q > K, it means the backward reaction will proceed to form more reactants.

The statement C is true.

Hope this helps!

The correct statement is " If Q < K, it means the forward reaction will proceed to form more products."

What is the forward reaction?

Any chemical change has been considered a forward reaction if the reactants reacted to produce the product on the opposite side of the arrow.

What are products?

The species that result from chemical reactions have always been called products. In a chemical reaction, reactants undergo a slightly elevated transition state before becoming products.

Therefore, the correct statement is " If Q < K, it means the forward reaction will proceed to form more products."

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Which of the following statements are true with respect to enzyme activity? Check all that apply. View Available Hint(s) Check all that apply. Enzymes speed up the reaction rate. The activation energy of a reaction increases when an enzyme is used to catalyze the reaction. Enzyme reactivity is not affected by change in pH and temperature. Enzymes are regenerated when the reaction is completed. Enzymes affect the reaction pathway by forming an enzyme-substrate complex.

Answers

Final answer:

Enzymes speed up reactions, are regenerated after the reaction, and form enzyme-substrate complexes. They do not increase activation energy or remain unaffected by pH and temperature changes.

Explanation:

The following statements are true regarding enzyme activity:

Enzymes speed up the reaction rate. They do this by providing an alternative pathway for a reaction with a lower activation energy.Enzymes are regenerated when the reaction is completed. After an enzyme has bound to its substrate and completed its catalytic function, it's released intact and can participate in future reactions.Enzymes affect the reaction pathway by forming an enzyme-substrate complex. The active site of an enzyme accommodates the substrate molecule, leading to a temporary enzyme-substrate complex that allows the reaction to proceed more easily.

However, the statement that "The activation energy of a reaction increases when an enzyme is used to catalyze the reaction" is incorrect. Enzymes lower the activation energy of a reaction rather than increasing it. Also false is "Enzyme reactivity is not affected by change in pH and temperature." Enzyme activity is very sensitive to changes in pH and temperature.

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hotosynthesis can be represented by 6CO2(g)+6H2O(l)⇌C6H12O6(s)+6O2(g) Which of the following will be false when the photosynthesis reaction reaches equilibrium?
a.The rate of formation of O2 is equal to the rate of formation of CO2.
b.The concentration of O2 will begin decreasing.
c.The concentrations of CO2 and O2 will not change.
d.The concentrations of CO2 and O2 will be equal.

Answers

Answer: Option (b) and (d) are correct.

Explanation:

An equilibrium reaction is defined as the reaction in which rate of forward reaction equals rate of backward reaction.

A photosynthesis reaction is the reaction in which plants in the presence of sunlight, water, and carbon dioxide make their own food.  

The amount of carbon dioxide consumed will be equal to the rate of formation of oxygen into the atmosphere.

Hence, the statement rate of formation of [tex]O_{2}[/tex] is equal to the rate of formation of [tex]CO_{2}[/tex] is true.

Concentration of oxygen may remain constant but it will not decrease. Hence, the statement concentration of [tex]O_{2}[/tex] will begin decreasing, is false.As both oxygen and carbon dioxide are present in an equilibrium reaction, So, their concentration will not change.

        Hence, the statement concentrations of [tex]CO_{2}[/tex] and [tex]O_{2}[/tex] will not change, is true.

Concentration of carbon dioxide and oxygen will also depend on the limiting reagent. So, it is not necessary that the concentrations of [tex]CO_{2}[/tex] and [tex]O_{2}[/tex] will be equal.

Some amount of carbon dioxide might escape out into the air.

Hence, the statement concentrations of [tex]CO_{2}[/tex] and [tex]O_{2}[/tex] will be equal, is false.

The Heat transferred through wave energy (electromagnetic waves) is: A. Sublimation B. Conduction C. Radiation D. Nuclear Fusion

Answers

Answer:

C. Radiation

Explanation:

The Heat transferred through wave energy (electromagnetic waves) is Radiation.

The Heat transferred through wave energy (electromagnetic waves) is Radiation.

What mass of Cu(s) would be produced if 0.40 mol of Cu2O(s) was reduced completely with excess H2(g) ?

Answers

Answer:

50.8g

Explanation:

Given parameters:

Nubmer of mole of Cu₂O = 0.4mol

Unknown:

Mass of Cu produced = ?

Solution:

The balanced reaction equation:

           Cu₂O  +  H₂   ⇄ 2Cu + H₂O

From the reaction, we know that:

            1 mole of Cu₂O produced 2 moles of Cu

             0.4 mol of Cu₂O would give 0.8mol of Cu

Now we know the number of moles of Cu produced because the limiting reactant here is Cu₂O. It was used up in the reaction in which the hydrogen gas was in excess.

To find the mass of Cu produced, we use the equation below :

              Mass of Cu = Number of moles of Cu x molar mass of Cu

Molar mass of Cu = 63.5gmol⁻¹

              Mass of Cu = 0.8 x 63.5 = 50.8g

If [tex]0.40[/tex] mol of [tex]Cu_2O(s)[/tex] is reduced completely with excess [tex]H_2(g)[/tex], approximately [tex]50.84[/tex] grams of [tex]Cu(s)[/tex] would be produced.

The balanced chemical equation for the reduction of [tex]Cu_2O(s)[/tex] with [tex]H_2(g)[/tex] is:

[tex]\[ \text{Cu}_2\text{O}(s) + \text{H}_2(g) \rightarrow \text{Cu}(s) + \text{H}_2\text{O}(l) \][/tex]

From the balanced equation, we can see that [tex]1[/tex] mole of [tex]Cu_2O[/tex] produces [tex]2[/tex] moles of [tex]Cu[/tex].

Given that we have [tex]0.40[/tex] mol of [tex]Cu_2O[/tex], we can use the stoichiometry of the reaction to find the amount of [tex]Cu[/tex] produced:

[tex]\[ \text{mol of Cu} = 0.40 \, \text{mol Cu}_2\text{O} \times \frac{2 \, \text{mol Cu}}{1 \, \text{mol Cu}_2\text{O}} \][/tex]

[tex]\[ \text{mol of Cu} = 0.40 \times 2 \][/tex]

[tex]\[ \text{mol of Cu} = 0.80 \, \text{mol} \][/tex]

Now, we need to convert the moles of [tex]Cu[/tex] to grams using the molar mass of copper ([tex]Cu[/tex]), which is approximately [tex]63.55 g/mol[/tex]

[tex]\[ \text{mass of Cu} = \text{mol of Cu} \times \text{molar mass of Cu} \][/tex]

[tex]\[ \text{mass of Cu} = 0.80 \, \text{mol} \times 63.55 \, \text{g/mol} \][/tex]

[tex]\[ \text{mass of Cu} = 50.84 \, \text{g} \][/tex]

The four bonds of carbon tetrachloride (CCl4) are polar, but the molecule is nonpolar because the bond polarity is canceled by the symmetric tetrahedral shape. When other atoms substitute for some of the Cl atoms, the symmetry is broken and the molecule becomes polar. Rank the following molecules from the least polar to the most polar: CH2Br2, CF2Cl2, CH2F2, CH2Cl2, CBr4, CF2Br2.

Answers

Answer:The following would be the polarity order CH₂F₂>CF₂Br₂>CF₂Cl₂>CH₂Cl₂>CH₂Br₂>CBr₄.

Explanation:

The polarity of any bond is associated with its dipole moment.

Dipole moment is created when two charges having equal magnitude but opposite signs are separated by a distance. Dipole moment is a vector quantity and it has a direction.

Mathematically:

Dipole moment=Magnitude of charge×distance between the charges

The charge separation only occurs in a bond when the two atoms forming bond have different electronegativities .The atom having more electroegativity pulls the shared electron density between the bonds  towards itself thereby generating partial charges on individual atoms .

The atom which pulls the shared electron density between the bonds (more electronegative atom) towards itself develops a partial negative charge and the atom (less electronegative atom) from  which the  electrondensity is pulled generates a partial positive charge.

This leads to the  development of a dipole as partial charges with opposite signs  on individual atoms   are separated by the bond length and the direction of the dipole is towards the electron which withdraws the electron density.

So we can say that the molecules will only have polarity or the molecule would be polar when they have a net dipole moment.

Net dipole moment of molecule is the vector sum of individual dipole moments of individual  bonds.

It is possible that individual bonds may create dipole moments but due to the overall symmetrical nature of molecule these individual bonds cancel each other and hence the net dipole moment of molecule is zero which means the molecule is non-polar.

The net dipole moment in case of CCl₄ is zero because the vector some of dipole moments created by individual bonds is zero which means the individual dipoles cancel each other leading to a net zero dipole moment.

This happens as CCl₄ has a tetrahedral structure which is very symmetric and hence the individual bonds in CCl₄ are polar on account of electronegativity difference between carbon and chlorine which leads to creation of individual dipoles but overall the net dipole moment of molecule is zero as these individual dipoles cancel each other and hence the molecular is  non-polar.

So we can say that molecules would have high polarity if they have high dipole moment.

A molecule will only have high dipole moment when the charge separtion is more and magnitude of partial charges developed is also more. This would happen when there is greater electronegativity difference between the two bond forming atoms

So the following would be the polarity order of the given molecules:

CH₂F₂>CF₂Br₂>CF₂Cl₂>CH₂Cl₂>CH₂Br₂>CBr₄

CH₂F₂ has the highest electronegativity difference  in between bonds(C-H&C-F) so they will generate more dipole moment and hence it would be most polar.

CF₂Br₂ has the 2nd highest electronegativity difference  in between bonds(C-F&C-Br) so they will generate  dipole moment and hence it would be  polar but less than CH₂F₂ .

CF₂Cl₂ has the 3rd highest electronegativity difference  in between bonds(C-F&C-Cl) so they will generate  dipole moment and hence it would also be  polar but less than CH₂F₂ &CF₂Br₂ .

CH₂Cl₂ has the 4th highest electronegativity difference  in between bonds(C-H&C-Cl) so they will generate dipole moment and hence it would be  polar but less than other 3 molecules .

CH₂Br₂ has the 5th highest electronegativity difference  in between bonds(C-H&C-Br) so they will generate dipole moment and hence it would be the least polar of all.

CBr₄ would be non-polar in nature as the net dipole moment would be Zero.

The answer is CH₂F₂> CF₂Br₂> CF₂Cl₂> CH₂Cl₂> CH₂Br₂> CBr₄

Further Explanation

In chemistry, polarity (or polarity) is the separation of electrical charges that leads to molecules or chemical groups that have dipole or multipole electric moments. Polar molecules must contain polar chemical bonds due to electronegativity differences between bonding atoms. Polar molecules with two or more polar bonds must have asymmetrical geometry so that the bonding moments do not cancel out. Polar molecules interact through the dipole-dipole intermolecular forces and hydrogen bonds. Polarity underlies several physical properties including surface tension, solubility, and melting and boiling points.

Polarity Classification

Bonds can be categorized as extreme - very nonpolar or very polar. Completely nonpolar bonds occur when electronegativity is identical and therefore has a zero difference. Fully polar bonds are more accurately called ionic bonds, and occur when the difference between electronegativity is large enough that one atom takes electrons from another. The terms "polar" and "nonpolar" are usually applied to covalent bonds, which are bonds where the polarity is incomplete. To determine the polarity of covalent bonds using numerical tools, the difference between atomic electronegativity is used.

The bond polarity is usually divided into three groups based on the difference in electronegativity between the two bonding atoms. According to the Pauling scale:

Nonpolar bonds generally occur when the electronegativity difference between the two atoms is less than 0.5 Polar bonds generally occur when the electronegativity difference between the two atoms is approximately between 0.5 and 2.0 Ionic bonding generally occurs when the electronegativity difference between two atoms is greater than 2.0

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Grade: College

Subject: Chemistry

keywords: Polarity

A mixture of helium and nitrogen gases at a total pressure of 641 mm mm Hg. If the gas mixture contains 0.399 grams of helium, how many grams of nitrogen are present? Hg contains helium at a partial pressure of 231 g

Answers

Answer : The mass of nitrogen present are, 4.965 grams.

Explanation :

According to the Raoult's law,

[tex]p_{He}=X_{He}\times p_T[/tex]

where,

[tex]p_{He}[/tex] = partial pressure of gas = 231 mmHg

[tex]p_T[/tex] = total pressure of gas = 641 mmHg

[tex]X_{He}[/tex] = mole fraction of helium gas = ?

Now put all the given values in this formula, we get the mole fraction of helium gas.

[tex]231mmHg=X_{He}\times 641mmHg[/tex]

[tex]X_{He}=0.36[/tex]

Now we have to calculate the mole fraction of nitrogen gas.

[tex]X_{He}+X_{N_2}=1[/tex]

[tex]X_{N_2}=1=0.36=0.64[/tex]

Now we have to calculate the mass nitrogen gas.

[tex]\frac{X_{He}}{X_{N_2}}=\frac{n_{He}}{n_{N_2}}[/tex]

[tex]\frac{X_{He}}{X_{N_2}}=\frac{\frac{w_{He}}{M_{He}}}{\frac{w_{N_2}}{M_{N_2}}}[/tex]

where,

n = moles, w = mass, M = molar mass

Now put all the given values in this expression, we get:

[tex]\frac{0.36}{0.64}=\frac{\frac{0.399}{4}}{\frac{w_{N_2}}{28}}[/tex]

[tex]w_{N_2}=4.965g[/tex]

Therefore, the mass of nitrogen present are, 4.965 grams.

The atomic mass of silicon is approximately 28.055. Which of the following would indicate the number closest to 28.055?
1. atomic number

2. mass number

3. number of electrons + neutrons

4. number of protons + electrons

Answers

Answer:

2. mass number

Explanation:

Mass number is equal to the sum of protons + neutrons in an element. For silicon is 14 + 14 = 28 (for the silicon 14 isotope).

Answer:

2. mass number

Explanation:

The atomic mass is concentrated in the tiny nucleus which contains protons and neutrons. These particles are called the nucleons. Nucleons dictate the mass of an atom.

The number of protons and neutrons in a nucleus is the atomic mass. Also, when we add the protons and neutrons together, we are calculating the mass number. The mass number also gives the atomic mass.

Atomic number on the other hand is the number of electrons or protons in a neutral atom.

You can identify a metal by carefully determining its density. A 8.44 g piece of an unknown metal is 1.25 cm long, 2.50 cm wide, and 1.00 cm thick. What is a possible identity of the element?Aluminum, 2.70 g/cm3Titanium, 4.54 g/cm3Zirconium, 6.51 g/cm3Chromium, 7.20 g/cm3Nickel, 8.90 g/cm3

Answers

Answer: Aluminum, [tex]2.70 g/cm^3[/tex]

Explanation:

Density is defined as the mass contained per unit volume.  It is characteristic of a substance.

[tex]Density=\frac{mass}{Volume}[/tex]

Given : Mass of object = 8.44 grams

Volume of object=[tex]length\times breadth\times height=1.25cm\times 2.50cm\times 1.0cm=3.125cm^3[/tex]

Putting in the values we get:

[tex]Density=\frac{8.44g}{3.125cm^3}=2.70g/cm^3[/tex]

Thus density of the object will be [tex]2.70 g/cm^3[/tex]  which matches that of aluminium.

Answer: Nickel

Explanation:

They have the same density as each other

The density of water at 4ºC is 1.00 x 103 kg/m3. What is water's density at 82ºC? Assume that the water's coefficient of volume expansion is constant. Enter your answer in kg/m3, without units, to the nearest whole number.

Answers

Answer:

Density of water at [tex] T = 82^0 C , \rho = 983.308 kg/m^3 [/tex]

Explanation:

The relationship between density and temperature is shown below:

[tex] \rho_1 = \rho_0 [ 1- \beta \Delta T ][/tex]

Where,

[tex] \rho_1[/tex]  is the density at temperature [tex]T_1[/tex]

[tex] \rho_0[/tex]  is the density at temperature [tex]T_0[/tex]

[tex] \beta [/tex] is the coefficient of volume expansion

[tex] \Delta T [/tex] is the change in temperature which is:

[tex] \Delta T = {T_1} -{T_0} [/tex]

Given,

[tex]T_0 = 4^0 C [/tex]

[tex] \rho_0 = 1.00\times 10^3 kg/m^3 [/tex]

[tex]T_1 = 82^0 C [/tex]

[tex] \Delta T = (82 -4) ^0 C =78 ^0 C [/tex]

[tex] \rho_1 = ? [/tex]

Also,

[tex] \beta for water = 0.000214 ^0C^{-1} [/tex]

So,

[tex] \rho_1 is: [/tex]

[tex] \rho_1 = 1.00\times 10^3 kg/m^3[1 - 0.000214 ^0C^{-1} \times 78^0 C ][/tex]

[tex] \rho_1 = 983.308 kg/m^3 [/tex]

A scientist wants to make a solution of tribasic sodium phosphate, Na3PO4, for a laboratory experiment. How many grams of Na3PO4 will be needed to produce 375 mL of a solution that has a concentration of Na+ ions of 1.50 M ?

Answers

The mass of sodium phosphate needed to make 375 mL of a solution with a molarity of sodium ions of 0.900 M is indeed 18.45 grams.

Given:

Volume of solution (V) = 375 mL = 0.375 L

Molarity of sodium ions (c) = 0.900 M

Using the formula for molarity: c = n/V

Since each mole of sodium phosphate produces 3 moles of sodium ions:

Effective molarity of sodium phosphate solution = c / 3 = 0.300 M

Number of moles of sodium phosphate (n) = c * V = 0.300 M * 0.375 L = 0.1125 mol

Molar mass of sodium phosphate (M) = 164 g/mol

Mass of sodium phosphate (m) = n * M = 0.1125 mol * 164 g/mol = 18.45 g

Therefore, the mass of sodium phosphate needed to make 375 mL of a solution with a molarity of sodium ions of 0.900 M is indeed 18.45 grams.

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Final answer:

To make a solution of tribasic sodium phosphate with a concentration of 1.50 M Na+ ions in 375 mL, you will need 276.38 grams of Na3PO4.

Explanation:

To calculate the grams of Na3PO4 needed, we need to use the equation relating moles, volume, and concentration:

Moles of Na+ ions = Molarity of Na+ ions x Volume of solution (in L)

Moles of Na3PO4 = 3 x Moles of Na+ ions

First, convert the volume in mL to L (375 mL = 0.375 L). Then, substitute the values into the equation:

Moles of Na+ ions = 1.50 M x 0.375 L = 0.5625 mol

Moles of Na3PO4 = 3 x 0.5625 mol = 1.6875 mol

Finally, convert moles to grams using the molar mass of Na3PO4 (163.94 g/mol):

Mass of Na3PO4 = 1.6875 mol x 163.94 g/mol = 276.38 g

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Lithium hydrogen carbonate, LiHCO3, decomposes when heated to form Li2O, CO2, and H2O. How many moles of H2O are formed when 0.50 mol LiHCO3 decomposes?

Answers

Answer:

0.25 mol of water

Explanation:

The starting point is writing out a balanced chemical equation

[tex]2LiHCO_{3} --->Li_{2}O +2CO_{2} +H_{2}O[/tex]

From here we can see that 2 moles of Lithium hydrogen carbonate produce 1 mole of water. It follows that 0.5 moles of Lithium hydrogen carbonate will produce half of that too, which is 0.25 moles. The ratio is always mantained.

Final answer:

When 0.50 mol of lithium hydrogen carbonate (LiHCO3) decomposes, it produces 0.25 mol of water (H2O).

Explanation:

You asked how many moles of H2O are formed when 0.50 mol LiHCO3 decomposes. The decomposition reaction for LiHCO3 to produce Li2O, CO2, and H2O is:

2 LiHCO3(s) → Li2O(s) + 2 CO2(g) + H2O(g)

According to the balanced equation, 2 moles of LiHCO3 produce 1 mole of H2O. Therefore, when 0.50 mole of LiHCO3 decomposes, you would get half of that ratio in moles of water:

(0.50 mol LiHCO3) / (2 mol LiHCO3) = 0.25 mol H2O

Therefore, the decomposition of 0.50 mol of LiHCO3 will produce 0.25 mol of H2O.

(C6H6) can be biodegraded by microorganism. if 30 mg of benzene is present, what amount of oxygen required for biodegradation, no new cells are formed?

Answers

Answer:

36.92 mg of oxygen required for bio-degradation.

Explanation:

[tex]5C_6H_6+15O_2\rightarrow 12CO_2+15H_2O[/tex]

Mass of benzene = 30 mg = 0.03 g (1000 mg = 1 g )

Moles benzene =[tex]\frac{0.03 g}{78 g/mol}=0.0003846 mol[/tex]

According to reaction 5 moles of benzene reacts with 15 moles of oxygen gas.

Then 0.0003846 mol of benzene will react with:

[tex]\frac{15}{5}\times 0.0003846 mol=0.0011538 mol[/tex] of oxygen gas

Mass of 0.0011538 moles of oxygen gas:

0.0011538 mol × 32 g/mol = 0.03692 g = 36.92 mg

36.92 mg of oxygen required for bio-degradation.

Excess Ca(OH)2 is shaken with water to produce a saturated solution. The solution is filtered, and a 50.00 mL sample titrated with HCl requires 11.22 mL of 0.0983 M HCl to reach the end point. Part A Calculate Ksp for Ca(OH)2.

Answers

Answer: The [tex]K_{sp}[/tex] for calcium hydroxide is [tex]5.324\times 10^{-6}[/tex]

Explanation:

To calculate the concentration of acid, we use the equation given by neutralization reaction:

[tex]n_1M_1V_1=n_2M_2V_2[/tex]

where,

[tex]n_1,M_1\text{ and }V_1[/tex] are the n-factor, molarity and volume of acid which is [tex]HCl[/tex]

[tex]n_2,M_2\text{ and }V_2[/tex] are the n-factor, molarity and volume of base which is [tex]Ca(OH)_2[/tex]

We are given:

[tex]n_1=1\\M_1=0.0983M\\V_1=11.22mL\\n_2=2\\M_2=?M\\V_2=50mL[/tex]

Putting values in above equation, we get:

[tex]1\times 0.0983\times 11.22=2\times M_2\times 50\\\\M_2=0.011M[/tex]

The concentration of [tex]Ca(OH)_2[/tex] comes out to be 0.011 M.

The balanced equilibrium reaction for the ionization of calcium hydroxide follows:

[tex]Ca(OH)_2\rightleftharpoons Ca^{2+}+2OH^-[/tex]

The expression for solubility constant for this reaction follows:

[tex]K_{sp}=[Ca^{2+}][OH^-]^2[/tex]

Putting the values in above equation, we get:

[tex]K_{sp}=(0.011)\times (2\times 0.11)^2[/tex]

[tex]K_{sp}=5.324\times 10^{-6}[/tex]

Hence, the [tex]K_{sp}[/tex] for calcium hydroxide is [tex]5.324\times 10^{-6}[/tex]

Answer:

[tex]5.2*10^{-6}[/tex]

Explanation:

The balanced chemical equation of the reaction is :

Ca(OH)2 + 2HCl → CaCl2 + 2 H20.

Ksp can be calculated by the following formula:

Ksp =  [Ca^{2+} ]+ [OH^{2-}].

Moles of HCl = Molarity × Volume of solution ( liters).

Moles of HCl can be calculated by multiplying 0.01122 (liters) ×0.0983

Moles of HCl = 0.0011 or  [tex]1.0*10^{-3}[/tex]

The calculation of the concentration of Calcium hydroxide ( as starting with 50 ml) is :

[tex]Ca(OH)_2 = \frac{1/2 * 0.0011}{0.05 (liters)}[/tex]

[tex]Ca(OH)_2 =0.011[/tex].

[tex]Ca(OH)_2 = 1.1 \times 10^{-2}[/tex].

Ksp =  [Ca^{2+} ]+ [2OH^{2-}].

Ksp = [tex]1.1 \times 10^{-2}* (2.2 \times 10^{-2})^2[/tex]

Ksp = [tex]5.2*10^{-6}[/tex]

Hence, the Ksp of calcium hydroxide is [tex]5.2*10^{-6}[/tex]

The following reaction was carried out in a 2.00 L reaction vessel at 1100 K: C(s)+H2O(g)⇌CO(g)+H2(g) If during the course of the reaction, the vessel is found to contain 8.75 mol of C, 12.9 mol of H2O, 4.00 mol of CO, and 7.20 mol of H2, what is the reaction quotient Q?

Answers

The ratio of products to reactants in a process at a particular time is measured by the reaction quotient Q. The reaction quotient Q is 0.2552.

What is the reaction quotient ?

The reactivity factor Q measures the proportional amounts of reactants and products present in a reaction at a specific time. A reaction's direction of shift toward equilibrium can be predicted using Q.

A reaction will go forward and change reactants into products if K > Q. The reaction will go in the opposite direction, turning reactants into products, if K Q. The system is already in equilibrium if Q = K.

Volume of container = 2 L

Concentration = mass / volume

Moles of carbon = 8.75 mol

Concentration of carbon = 8.75 / 2

= 4.375 mol

Moles of H₂O = 12.9 mol

Concentration of water = 12.9 /2

= 6.45 mol

Moles of CO = 4

Concentration of CO = 4 / 2

= 2

Moles of Hydrogen = 7.20 mol

Concentration of Hydrogen is 7.20 / 2

= 3.6 mol

Q is given as

Q = ( H₂ ) ( O₂ ) / ( C ) ( H₂O )

= 7.20 / 28.21

= 0.2552

Thus, The reaction quotient Q is 0.2552.

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Final answer:

The reaction quotient Q for C(s) + H2O(g) ⇌ CO(g) + H2(g), given the amounts of reactants and products and the volume of the container, is calculated to be 1.12.

Explanation:

The reaction quotient, Q, expresses the relative amounts of reactants and products during the progress of a reaction at a particular moment in time. It is calculated using the same expression as the equilibrium constant, Kc, but with the concentrations (or in the case of gases, the partial pressures) that are currently present, rather than at equilibrium. For the reaction given:

C(s) + H₂O(g) ⇌ CO(g) + H₂(g)

The reaction quotient, Q, can be expressed as:

Q = ([CO][H₂]) / [H₂O]

The concentrations can be found by dividing the number of moles of each gas by the volume of the container. Since carbon is a solid, its amount does not factor into the expression for Q. In a 2.00 L container:

[H₂O] = 12.9 mol / 2.00 L = 6.45 M

[CO] = 4.00 mol / 2.00 L = 2.00 M

[H₂] = 7.20 mol / 2.00 L = 3.60 M

To calculate Q:

Q = (2.00 M × 3.60 M) / 6.45 M

Q = 7.20 M2 / 6.45 M

Q = 1.12

Thus, the reaction quotient Q for the given reaction under the specified conditions is 1.12.

Sodium nitrite (NaNO2) reacted with 2−iodooctane to give a mixture of two constitutionally isomeric compounds of molecular formula C8H17NO2 in a combined yield of 88%. Draw reasonable structures for these two isomers. Click the "draw structure" button to launch the drawing utility. Place the two compounds in the appropriate boxes below.

Answers

Hey there!:

the chemical reaction between 2-iodoctane and sodium nitrite is as follows:

Answer:

On the attached picture.

Explanation:

Hello,

In the case, the reaction between 2-iodooctane and sodium nitrite, leads to the formation of an alkyl nitrite and a nitro alkane as shown on the attached picture. Once the reaction began, the salt breaks and the sodium bonds with the iodine from the 2-iodooctane to form sodium iodide, in such a way, a free radical in the second carbon is formed so the NO₂ could bond both as a nitrite and as a nitro radical; therefore, the formed species are octyl 2-nitrite and 2-nitrooctane.

Best regards.

A more experienced colleague mentions to you that you should aim for a dissolved oxygen concentration around 1.0 mg/L at day 5 of the experiment. They show you data from a similar wastewater spill that happened last year, in which the BOD5 of the stream water was 60 mg/L. From your previous experiment, you found that the dissolved oxygen concentration at day 0 was 10 mg/L. Based on this information, what dilution factor, P, should you try in your reactor?

Answers

Answer:

3

Explanation:

Lt= Loe^(-kt)

Data:

Lo = 10 mg/mL

Assume k = 0.23/da

1. Calculate L5

L5 = 10e^(-5×0.23) = 10e^-1.15 = 10 × 0.317 = 3.17 mg/mL

2. Calculate the dilution factor

You expect to find L5 to be about 3

You want L5 to be about 1.

You should use a dilute your sample by a factor of 3.

P = 3

The normal boiling point of a certain liquid X is 120.7°C , but when 58.66g of urea NH22CO are dissolved in 950.g of X , it is found that the solution boils at 123.0°C instead. Use this information to calculate the molal boiling point elevation constant Kb of X .

Answers

Final answer:

The molal boiling point elevation constant, Kb, of the liquid X in the presence of the given amount of urea is calculated to be approximately 2.239 °C kg/mol.

Explanation:

The question requires us to calculate the molal boiling point elevation constant, Kb, of a fluid X. The molal boiling point elevation constant is a measure of how much the boiling point of a solution increases when a solute is added. This is represented by the formula: ∆TB = Kb*m, where ∆TB is the change in boiling point and m is the molal concentration of the solute. Given that

∆TB = TB(solution) - TB(pure solvent) = 123.0°C - 120.7°C = 2.3°C,

and the molality m = moles of solute/kg of solvent = (58.66g urea / 60.056 g/mol urea) / (950g solvent / 1000g/kg) = 1.027 mol/kg,

The molal boiling point elevation constant, Kb, can be calculated by rearranging ∆TB = Kb*m to Kb = ∆TB / m = 2.3°C / 1.027 mol/kg = 2.239 °C kg/mol.

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Based on boiling point elevation, mole number, and molality, the molal boiling point elevation constant (Kb) of a liquid X containing 58.66g of urea is computed as 2.23 °C/m.

Step-by-Step Solution:

Determine the boiling point elevation (∆Tb):

[tex]\Delta T_b = 123.0\textdegree C - 120.7\textdegree C = 2.3\textdegree C[/tex]

Calculate the number of moles of urea (NH₂₂CO):

[tex]Molar\ mass\ of\ urea\ = 14 + 1\times 4 + 12 + 16 = 60\ g/mol[/tex]

Urea moles are equal to 58.66 g / 60 g/mol, or 0.978 moles.

Calculate the molality (m) of the solution:

Molality (m) is calculated as solute moles per kilogram of solvent.

[tex]m = 0.978\ moles / 0.950\ kg = 1.03\ m[/tex]

Use the boiling point elevation formula to calculate Kb:

[tex]\Delta T_b = K_b \times m[/tex]

[tex]K_b = \Delta T_b / m = 2.3\textdegree C / 1.03\ m = 2.23 \textdegree C/m[/tex]

As a result, liquid X's molal boiling point elevation constant, or Kb, is 2.23 °C/m.

In the activity, click on the E∘cell and Keq quantities to observe how they are related. Use this relation to calculate Keq for the following redox reaction that occurs in an electrochemical cell having two electrodes: a cathode and an anode. The two half-reactions that occur in the cell are Cu2 (aq) 2e−→Cu(s) and Co(s)→Co2 (aq) 2e− The net reaction is Cu2 (aq) Co(s)→Cu(s) Co2 (aq) Use the given standard reduction potentials in your calculation as appropriate.

Answers

Final answer:

Determine the standard cell potential for the reaction from given standard reduction potentials. Use this in the Nernst equation to calculate the equilibrium constant (Keq). From Keq, interpret the system at equilibrium.

Explanation:

The calculation involved in this chemistry question is related to electrochemistry, specifically determining the equilibrium constant (Keq) for a redox reaction involving copper and cobalt in an electrochemical cell. This calculation can be performed using standard reduction potentials and the Nernst equation.

Based on the given half-reactions, the net reaction is Cu2+ (aq) + Co(s) → Cu(s) + Co2+ (aq). You would first determine the E°cell (standard cell potential) for the reaction by subtracting the standard reduction potential for the oxidation half-reaction (occurring at the anode) from that for the reduction half-reaction (at the cathode).

Assuming we have the standard reduction potential values for the cathode and anode processes, E.cell can be calculated. Note that at equilibrium, E.cell equals to 0, so from the Nernst equation we derive the formula for Keq. Remember that n is the number of moles of electrons transferred in the reaction, which is equivalent to 2 in this reaction. From this calculated Keq value, you will be able to infer changes in the system at equilibrium.

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4.2 g of 1,4-di-t-butyl-2,5-dimethoxybenzene (250.37 g/mol) were synthesized by reacting 10.4 mL of t-butyl alcohol (MW 74.12 g/mol, D 0.79 g/mL), 25 mL of concentrated sulfuric acid (MW 98.08 g/mol, D 1.84 g/mL), and 5.6 g of 1,4-dimethoxybenzene (MW 138.17 g/mol) together. Calculate the percent yield of this reaction.

Answers

Answer:

Percentage yield of 1,4-di-t-butyl-2,5-dimethoxybenzene is 41.40%.

Explanation:

Here, in the reaction sulfuric acid is playing the role of catalyst by donating its proton in initial stage of the reaction and in the end of the reaction the proton is returned back to sulfuric acid.

Mass = Density × Volume

Mass of t-butyl alcohol = [tex]0.79 g/mL\times 10.4 mL=8.219 g[/tex]

Moles of t-butyl alcohol  =[tex]\frac{8.219 g}{74.12 g/mol}=0.11084 mol[/tex]

Moles of 1,4-dimethoxybenzene = [tex]\frac{5.6 g}{138.17 g/mol}=0.04052 mol[/tex]

According to reaction 2 mol of  t-butyl alcohol reacts  with 1 mol of 1,4-dimethoxybenzene.

Then 0.11084 moles of t-butyl alcohol will react with :

[tex]\frac{1}{2}\times 0.11084 mole=0.05542 mol[/tex] of 1,4-dimethoxybenzene.

This means that moles of 1,4-dimethoxybenzene are limited and moles of t-butyl alcohol are in excess.So, the moles of product will depend upon the moles of 1,4-dimethoxybenzene.

According top reaction 1 mol of 1,4-dimethoxybenzene gives 1 mol of  1,4-di-t-butyl-2,5-dimethoxybenzene.

Then 0.04052 moles of 1,4-di-t-butyl-2,5-dimethoxybenzene will give:

[tex]\frac{1}{1}\times 0.04052 mol= 0.04052 mol[/tex] of 1,4-di-t-butyl-2,5-dimethoxybenzene.

Mass of 0.04052 moles of 1,4-di-t-butyl-2,5-dimethoxybenzene:

0.04052 mol × 250.37 g/mol = 10.144 g

Percentage yield:

[tex]\frac{Experimental}{Theoretical}\times 100[/tex]

Percentage yield of 1,4-di-t-butyl-2,5-dimethoxybenzene:

Experimental yield = 4.2 g

Theoretical yield = 10.144 g

[tex]\frac{4.2 g}{10.144 g}\times 100=41.40\%[/tex]

The percent yield of the reaction is approximately 41.52%.

The correct format for the answer is as follows:

First, we need to calculate the moles of the limiting reactant to determine the theoretical yield. The balanced chemical equation for the synthesis of 1,4-di-t-butyl-2,5-dimethoxybenzene is not provided, but we can assume that one mole of 1,4-dimethoxybenzene reacts with two moles of t-butyl alcohol to produce one mole of the product.

Let's calculate the moles of each reactant:

For t-butyl alcohol:

[tex]\[ \text{Moles of t-butyl alcohol} = \frac{\text{Volume (mL)} \times \text{Density (g/mL)}}{\text{Molecular Weight (g/mol)}} \] \[ \text{Moles of t-butyl alcohol} = \frac{10.4 \text{ mL} \times 0.79 \text{ g/mL}}{74.12 \text{ g/mol}} \] \[ \text{Moles of t-butyl alcohol} = \frac{8.216 \text{ g}}{74.12 \text{ g/mol}} \] \[ \text{Moles of t-butyl alcohol} \approx 0.1108 \text{ mol} \][/tex]

For 1,4-dimethoxybenzene:

[tex]\[ \text{Moles of 1,4-dimethoxybenzene} = \frac{\text{Mass (g)}}{\text{Molecular Weight (g/mol)}} \] \[ \text{Moles of 1,4-dimethoxybenzene} = \frac{5.6 \text{ g}}{138.17 \text{ g/mol}} \] \[ \text{Moles of 1,4-dimethoxybenzene} \approx 0.0405 \text{ mol} \][/tex]

Since the reaction requires two moles of t-butyl alcohol for every mole of 1,4-dimethoxybenzene, t-butyl alcohol is in excess, and 1,4-dimethoxybenzene is the limiting reactant.

Now, we calculate the theoretical yield of 1,4-di-t-butyl-2,5-dimethoxybenzene:

[tex]\[ \text{Theoretical yield (g)} = \text{Moles of limiting reactant} \times \text{Molecular Weight of product} \] \[ \text{Theoretical yield (g)} = 0.0405 \text{ mol} \times 250.37 \text{ g/mol} \] \[ \text{Theoretical yield (g)} \approx 10.11955 \text{ g} \]The actual yield is given as 4.2 g.[/tex]

Finally, we calculate the percent yield:

[tex]\[ \text{Percent Yield} = \left( \frac{\text{Actual Yield (g)}}{\text{Theoretical Yield (g)}} \right) \times 100\% \] \[ \text{Percent Yield} = \left( \frac{4.2 \text{ g}}{10.11955 \text{ g}} \right) \times 100\% \] \[ \text{Percent Yield} \approx 41.52\% \][/tex]

What volume (in liters) of carbon monoxide gas, measured at a temperature of 212 K and a pressure of 676 mm Hg, is required to synthesize 19.3 g of methanol. How many liters of oxygen (at STP) are required to form 12.5 g of H2O ? Show your work

Answers

Answer:

For 1: The volume of carbon monoxide required to produce given amount of methanol is 11.9 L.

For 2: The volume of oxygen required to form given amount of water is 7.77 L.

Explanation:

For 1:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]     ......(1)

For methanol:

Given mass of methanol = 19.3 g

Molar mass of methanol = 32 g/mol

Putting values in above equation, we get:

[tex]\text{Moles of methanol}=\frac{19.3g}{32g/mol}=0.603mol[/tex]

The chemical reaction of formation of methanol from carbon monoxide follows:

[tex]CO+2H_2\rightarrow CH_3OH[/tex]

By Stoichiometry of the reaction:

1 mole of methanol is produced from 1 mole of carbon monoxide.

so, 0.603 moles of methanol will be produced from = [tex]\frac{1}{1}\times 0.603=0.603mol[/tex] of carbon monoxide.

To calculate the volume of carbon monoxide, we use the equation given by ideal gas:

PV = nRT

where,

P = Pressure of carbon monoxide = 676 mmHg

V = Volume of carbon monoxide = ? L

n = Number of moles of carbon monoxide = 0.603 mol

R = Gas constant = [tex]62.3637\text{ L.mmHg }mol^{-1}K^{-1}[/tex]

T = Temperature of carbon monoxide = 212 K

Putting values in above equation, we get:

[tex]676mmHg\times V=\frac{19.3}{32g/mol}\times 62.3637\text{ L.mmHg }mol^{-1}K^{-1}\times 212K\\\\V=11.79L[/tex]

Hence, the volume of carbon monoxide required to produce given amount of methanol is 11.9 L.

For 2:

Calculating the moles of water by using equation 1, we get:

Given mass of water = 12.5 g

Molar mass of water = 18 g/mol

Putting values in equation 1, we get:

[tex]\text{Moles of water}=\frac{12.5g}{18g/mol}=0.694mol[/tex]

The chemical reaction of formation of water from oxygen and hydrogen follows:

[tex]O_2+2H_2\rightarrow 2H_2O[/tex]

By Stoichiometry of the reaction:

2 moles of water is produced from 1 mole of oxygen gas.

so, 0.694 moles of water will be produced from = [tex]\frac{1}{2}\times 0.694=0.347mol[/tex] of oxygen gas.

At STP:

1 mole of a gas occupies 22.4 L of volume.

So, 0.347 moles of oxygen gas will occupy = [tex]\frac{22.4L}{1mol}\times 0.347mol=7.77L[/tex]

Hence, the volume of oxygen required to form given amount of water is 7.77 L.

Which of the following assumptions appears reasonable for the isothermal process? H20 (liq, 1 bar) → H2O (liq, 1300 bar), T = 20°C. A. AU = 0, AH 0 B. AU = 0, AH 0 C. AU #0, AH = 0 D. None of the above Hinn nf diethyl ether using the Chen's rule is

Answers

Answer : The assumptions appears reasonable for the isothermal process is, [tex]\Delta U=0[/tex] and [tex]\Delta H=0[/tex]

Explanation :

First law of thermodynamic : It states that the energy can not be created or destroyed, it can only change or transfer from one state to another state.

As per first law of thermodynamic,

[tex]\Delta U=q+w[/tex]

The expression for internal energy is:

[tex]\Delta U=nC_vdt[/tex]

The expression for enthalpy is:

[tex]\Delta H=nC_pdt[/tex]

where,

[tex]\Delta U[/tex] = internal energy

q = heat

w = work done

n = number of moles

[tex]C_v[/tex] = specific heat capacity at constant volume

[tex]C_p[/tex] = specific heat capacity at constant pressure

[tex]dt[/tex] = change in temperature

As we know that, the term internal energy and enthalpy is the depend on the temperature and the process is isothermal that means at constant temperature.

T = constant

[tex]\dt[/tex] = 0

So, at constant temperature the internal energy and enthalpy is equal to zero. That means,

[tex]\Delta U=0[/tex] and [tex]\Delta H=0[/tex]

Final answer:

For an isothermal process in which the pressure changes significantly (as in the one outlined in the question, from 1 bar to 1300), the change in internal energy (ΔU) will be zero but a change in enthalpy (ΔH) will be non-zero, since the work done on the system is not constant. This corresponds to option B in the question.

Explanation:

In order to understand the question, it's crucial to define two key terms: isothermal and internal energy. An isothermal process is a change of a system, in which the temperature remains constant: ΔT = 0. For an ideal gas, the internal energy is a function of temperature only. Hence, in an isothermal process, the change in internal energy ΔU = 0. The enthalpy H of a system is defined as H = U + PV where U is the internal energy of the system, P is the pressure, and V is the volume.

Given that the process we're examining here involves a change in pressure, there is work done on the system (from 1 bar to 1300 bar), so the enthalpy H = U + PV will not be zero as P and V do not remain constant. Therefore, the most reasonable assumption for this process is ΔU = 0 and ΔH ≠ 0, which would correspond to option B.

Learn more about the Isothermal Process here:

https://brainly.com/question/29209594

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Ethanol has a Kb of 1.22 Degrees C/m and usually boils at 78.4 Degrees Celcius. How many mol of an nonionizing solute would need to be added to 47.84 g ethanol in order to raise the boiling point to 86.30?

Answers

Answer:

0.3097 moles of an nonionizing solute would need to be added.

Explanation:

Molal elevation constant = [tex]k_b=1.22^oC/m[/tex]

Normal boiling point of ethanol = [tex]T_o=78.4^oC[/tex]

Boiling of solution =[tex]T_b=86.30^oC[/tex]

Moles of nonionizing solute = n

Mass of ethanol (solvent) = 47.84 g

Elevation boiling point:

[tex]\Delta T_b=T_b-T_o[/tex]

[tex]\Delta T_b=86.30^oC-78.4^oC=7.9^oC[/tex]

[tex]\Delta T_b=K_b\times  m[/tex]

[tex]m=\frac{\text{Moloes of solute}}{\text{Mass of solvent(kg)}}[/tex]

[tex]7.9^oC=1.22^oC/m\times \frac{n}{0.04784 kg}[/tex]

n = 0.3097 mol

0.3097 moles of an nonionizing solute would need to be added.

Final answer:

To raise the boiling point of ethanol to 86.30°C, 0.310 moles of a nonionizing solute need to be added to 47.84 g of ethanol, using the boiling point elevation formula and the given Kb of ethanol.

Explanation:

To calculate the number of moles of a nonionizing solute needed to raise the boiling point of ethanol to 86.30°C, we use the boiling point elevation formula: ΔT = Kb × m, where ΔT is the change in boiling point, Kb is the ebullioscopic constant of ethanol, and m is the molality of the solution.

First, determine the change in boiling point (ΔT): ΔT = final boiling point - initial boiling point = 86.30°C - 78.4°C = 7.9°C.

Use the given Kb for ethanol, 1.22°C/m, and solve for molality (m): m = ΔT / Kb = 7.9°C / 1.22°C/m = 6.48 m.

To find the number of moles of solute, relate molality to the mass of solvent in kilograms: molality (m) = moles of solute/kg of solvent. Therefore, moles of solute = m × kg of solvent. The mass of ethanol is 47.84 g or 0.04784 kg, thus moles of solute = 6.48 × 0.04784 kg = 0.310 moles.

Which statements are true? The oxidation number for Cu(s) is +2. An oxidizing agent gains electrons. Na+ is formed from the reduction of Na(s) . The oxidation number for Hg(????) is 0. A reducing agent gains electrons. Zn2+ is formed from the oxidation of Zn(s) .

Answers

Final answer:

The true statements are: an oxidizing agent gains electrons, a reducing agent loses electrons, and Zn2+ is formed from the oxidation of Zn(s).

Explanation:

Let's address each statement in the question about oxidation numbers and redox reactions:The oxidation number for Cu(s) is 0, not +2, because the oxidation number of a free element is always 0.An oxidizing agent gains electrons during a redox reaction.Na+ is formed from the oxidation of Na(s), not reduction, because sodium loses an electron to form Na+.The oxidation number for elemental Hg(l) is 0 since the oxidation state of a free element is 0.A reducing agent loses electrons in a redox reaction.Zn2+ is formed from the oxidation of Zn(s) since zinc loses electrons in the process.

An enzyme that follows Michaelis-Menten kinetics has a KM value of 15.0 μM and a kcat value of 221 s−1. At an initial enzyme concentration of 0.0100 μM, the initial reaction velocity was found to be 1.07×10−6 μM/s. What was the initial concentration of the substrate, [S], used in the reaction ?

Answers

The initial substrate concentration was approximately 7.29 μM.

To determine the initial substrate concentration, we use the Michaelis-Menten equation along with the provided data to calculate that the initial substrate concentration was approximately 7.29 μM.

To determine the initial concentration of the substrate, [S], used in the reaction, we can use the Michaelis-Menten equation, which is:

[tex]vo=\frac{V(max)[S]}{Km+[S]}[/tex]

Given the following data:

Initial reaction velocity (v0) = 1.07×10⁻⁶ μM/sMichaelis constant (KM) = 15.0 μMTurnover number (kcat) = 221 s⁻¹Initial enzyme concentration ([E]₀) = 0.0100 μM

First, we need to calculate Vmax using the formula:

Vmax = kcat [E]₀

Substituting the given values:

Vmax = 221 s⁻¹ x 0.0100 μM = 2.21 μM/s

Next, substitute Vmax and the given values into the Michaelis-Menten equation to solve for [S]:

1.07×10⁻⁶ = (2.21 [S]) / (15.0 + [S])

Rearranging to solve for [S] gives:

[S] = (1.07×10⁻⁶ * (15.0 + [S])) / 2.21

Solving this equation numerically, we find:

[S] ≈ 7.29×10⁻³ μM

Thus, the initial concentration of the substrate, [S], used in the reaction was approximately 7.29 μM.

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